General Information
Version
7.6
Revision date
2025-03-11
Product name
Bromomethane-d2
CAS No.
4960-89-8
REACH No
A
Emergency telephone
+49 (0)696 43508409
Icons in SDS
Company Information
company name
Sigma-Aldrich Chemie GmbH
e-mail address of the competent person responsible for the Safety Data Sheet
technischerservice@merckgroup.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H280, H301, H310, H310+H330, H315, H319, H330, H335, H341, H373, H400, H410, H411, H420
Hazard statements
Code
Statements
H280
Contains gas under pressure; may explode if heated
Section 2
SECTION 2: Hazards identification
Regulation (EC) No. 1272/2008 Classification of the substance or mixture Gases under pressure, (Liquefied H280: Contains gas under pressure; may gas) explode if heated Acute toxicity, (Category 3) H301: Toxic if swallowed Acute toxicity, (Category 2) H330: Fatal if inhaled Acute toxicity, (Category 2) H310: Fatal in contact with skin Skin irritation, (Category 2) H315: Causes skin irritation Eye irritation, (Category 2) H319: Causes serious eye irritation Germ cell mutagenicity, H341: Suspected of causing genetic Category 2) defects Specific target organ toxicity - H335: May cause respiratory irritation single exposure, (Category 3), Respiratory system Specific target organ toxicity - H373: May cause damage to organs repeated exposure, (Category 2), through prolonged or repeated exposure Central nervous system Short-term (acute) aquatic H400: Very toxic to aquatic life hazard, (Category 1) Long-term (chronic) aquatic H411: Toxic to aquatic life with long lasting hazard, (Category 2) effects Hazardous to the ozone layer, H420: Harms public health and the Category 1) environment by destroying ozone in the upper atmosphere
Signal word
Danger Danger
Hazard statements
H280 Contains gas under pressure; may explode if heated. H301 Toxic if swallowed. H310 + H330 Fatal in contact with skin or if inhaled. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H341 Suspected of causing genetic defects. H373 May cause damage to organs (Central nervous system) through prolonged or repeated exposure. H410 Very toxic to aquatic life with long lasting effects. H420 Harms public health and the environment by destroying ozone in the upper atmosphere. Reduced Labeling (<= 125 ml) H301 Toxic if swallowed. H341 Suspected of causing genetic defects. H420 Harms public health and the environment by destroying ozone in the upper atmosphere. H310 + H330 Fatal in contact with skin or if inhaled.
Precautionary statements
P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P302 + P352 + P310 IF ON SKIN: Wash with plenty of water. Immediately call a POISON CENTER/ doctor. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P410 + P403 Protect from sunlight. Store in a well-ventilated place. P502 Refer to manufacturer or supplier for information on recovery or recycling. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P302 + P352 + P310 IF ON SKIN: Wash with plenty of water. Immediately call a POISON CENTER/ doctor. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P502 Refer to manufacturer or supplier for information on recovery or recycling.
Supplemental label elements
none none
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
ECOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
TOXICOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
2.1 Classification of the substance or mixture
Gases under pressure, (Liquefied H280: Contains gas under pressure; may gas) explode if heated. Acute toxicity, (Category 3) H301: Toxic if swallowed. Acute toxicity, (Category 2) H330: Fatal if inhaled. Acute toxicity, (Category 2) H310: Fatal in contact with skin. Skin irritation, (Category 2) H315: Causes skin irritation. Eye irritation, (Category 2) H319: Causes serious eye irritation. Germ cell mutagenicity, H341: Suspected of causing genetic (Category 2) defects. Specific target organ toxicity - H335: May cause respiratory irritation. single exposure, (Category 3), Respiratory system Specific target organ toxicity - H373: May cause damage to organs repeated exposure, (Category 2), through prolonged or repeated exposure. Central nervous system Short-term (acute) aquatic H400: Very toxic to aquatic life. hazard, (Category 1) Long-term (chronic) aquatic H411: Toxic to aquatic life with long lasting hazard, (Category 2) effects. Hazardous to the ozone layer, H420: Harms public health and the (Category 1) environment by destroying ozone in the upper atmosphere.