Ethynylmagnesium chloride solution

Sigma-Aldrich Canada Co

Revision date : 2015-11-06

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GHS02 GHS07 GHS08
Health risk rating 4
Safety risk rating 3
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

109-99-9

Name of the chemical

Tetrahydrofuran (618/2012)

Concentration

N/A

EC/CAS

203-726-8

Name of the chemical

Tetrahydrofuran (618/2012)

Concentration

N/A

General Information

Revision date

2015-11-06

Product name

Ethynylmagnesium chloride solution

supplier name

Sigma-Aldrich Canada Co

Manufacturer Name

Sigma-Aldrich Corporation

Emergency telephone

Americas Region

Icons in SDS

Company Information

company name

Sigma-Aldrich Canada Co

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H261, H302, H316, H319, H335, H351

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

GHS Classification Emergency Overview Target Organs Central nervous system, Liver, Kidney

WHMIS Classification

B2 Flammable liquid D2B Toxic Material Causing Other Toxic Effects Moderate respiratory irritant Moderate eye irritant

2.1 Classification of the substance or mixture

Flammable liquids (Category 2) Substances and mixtures, which in contact with water, emit flammable gases (Category 2) Acute toxicity, Oral (Category 4) Skin corrosion/irritation (Category 3) Serious eye damage/eye irritation (Category 2A) Carcinogenicity (Category 2) Specific target organ toxicity - single exposure (Category 3), Respiratory system

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapour. H261 In contact with water releases flammable gases. H302 Harmful if swallowed. H316 Causes mild skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H351 Suspected of causing cancer.

Precautionary statements

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P223 Do not allow contact with water. P231 + P232 Handle and store contents under inert gas. Protect from moisture. P233 Keep container tightly closed. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. Rinse mouth. P302 + P335 + P334 IF ON SKIN: Brush off loose particles from skin. Immerse in cool water. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P332 + P313 If skin irritation occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ attention. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P402 + P404 Store in a dry place. Store in a closed container. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P501 Dispose of contents/ container to an approved waste disposal plant.

Health hazards

1 * Flammability: 3

Physical hazards

1

Potential health effects

Inhalation May be harmful if inhaled. May cause respiratory tract irritation. Skin May be harmful if absorbed through skin. May cause skin irritation. Eyes May cause eye irritation. Ingestion May be harmful if swallowed.

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