General Information
Revision date
2016-05-27
Product name
Bromomethane-d2
CAS No.
4960-89-8
Emergency telephone
+1-703-527-3887 (CHEMTREC
Icons in SDS
Company Information
company name
Sigma-Aldrich
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H220, H301, H301+H331, H315, H319, H331, H335, H341, H400, H410, H420
Hazard statements
Code
Statements
H220
Extremely flammable gas
Section 2
OSHA HCS Classification
Flammable gases (Category 1), H220 Acute toxicity, Oral (Category 3), H301 Acute toxicity, Inhalation (Category 3), H331 Skin irritation (Category 2), H315 Eye irritation (Category 2A), H319 Germ cell mutagenicity (Category 2), H341 Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335 Acute aquatic toxicity (Category 1), H400 Chronic aquatic toxicity (Category 1), H410 Hazardous to the ozone layer (Category 1), H420 For the full text of the H-Statements mentioned in this Section, see Section 16.
Signal word
Danger
Hazard statements
H220 Extremely flammable gas. H301 + H331 Toxic if swallowed or if inhaled H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H341 Suspected of causing genetic defects. H410 Very toxic to aquatic life with long lasting effects. H420 Harms public health and the environment by destroying ozone in the upper atmosphere.
Precautionary statements
P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/doctor. Rinse mouth. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P332 + P313 If skin irritation occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ attention. P362 Take off contaminated clothing and wash before reuse. P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely. P381 Eliminate all ignition sources if safe to do so. P391 Collect spillage. P403 Store in a well-ventilated place. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of contents/ container to an approved waste disposal plant. P502 Refer to manufacturer/ supplier for information on recovery/ recycling.
2.3 Other hazards
Hazardous to the ozone layer.