Hydrazine solution

Sigma-Aldrich Brasil Ltda

Revision date : 2024-03-01

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GHS02 GHS06 GHS08 GHS09
Health risk rating 5
Safety risk rating 3
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

200-835-2/75-05-8

Name of the chemical

Acetonitrile

Concentration

>=90-< 100%

Listed in

EC/CAS

206-114-9/302-01-2

Name of the chemical

Hydrazine

Concentration

>=3-<5%

General Information

Version

7.6

Revision date

2024-03-01

Product name

Hydrazine solution

REACH No

This

Emergency telephone

Chemtrec(Intl.): +(55)-21 3958-1449 / +55 11 4349-1359 Chemtrec (Brazil

Icons in SDS

GHS02 GHS06 GHS08 GHS09

Company Information

company name

Sigma-Aldrich Brasil Ltda

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H302, H302+H312, H312, H315, H317, H319, H331, H350, H411

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Flammable liquids, (Category 2) H225: Highly flammable liquid and vapor. Acute toxicity, (Category 4) H302: Harmful if swallowed. Acute toxicity, (Category 3) H331: Toxic if inhaled. Acute toxicity, (Category 4) H312: Harmful in contact with skin. Skin irritation, (Category 2) H315: Causes skin irritation. Eye irritation, (Category 2) H319: Causes serious eye irritation. Skin sensitization, (Category 1) H317: May cause an allergic skin reaction. Carcinogenicity, (Category 1B) H350: May cause cancer. Long-term (chronic) aquatic H411: Toxic to aquatic life with long lasting hazard, (Category 2) effects.

2.2 Label elements

Labelling

Signal word

Danger Danger

Hazard statements

H225 Highly flammable liquid and vapor. H302 + H312 Harmful if swallowed or in contact with skin. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H331 Toxic if inhaled. H350 May cause cancer. H411 Toxic to aquatic life with long lasting effects. Restricted to professional users. Reduced Labeling (<= 125 ml) H331 Toxic if inhaled. H317 May cause an allergic skin reaction. H350 May cause cancer.

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor. P308 + P313 IF exposed or concerned: Get medical advice/ attention.

Supplemental label elements

none none

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

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