Formaldehyde Solution GR ACS

Sigma-Aldrich Brasil Ltda

Revision date : 2024-11-09

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GHS06 GHS02 GHS08
Health risk rating 5
Safety risk rating 2
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

200-001-8/50-00-0

Name of the chemical

Formaldehyde

Concentration

>=30-<50

EC/CAS

200-659-6/67-56-1

Name of the chemical

Methanol

Concentration

>=10-<20 603-001-

General Information

Version

10.1

Revision date

2024-11-09

Product name

Formaldehyde Solution GR ACS

REACH No

This

1.2.1 Relevant identified uses

Reagent for analysis

Emergency telephone

55 0800 707 7022, 55 0800 117 2020, 55 11 4349 1359

Icons in SDS

GHS02 GHS06 GHS08

Company Information

company name

Sigma-Aldrich Brasil Ltda

e-mail address of the competent person responsible for the Safety Data Sheet

suporte-cientifico@merckgroup.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H226, H301, H301+H311+H331, H311, H314, H317, H318, H331, H335, H341, H350, H370

Hazard statements

Code

Statements

H226

Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture Flammable liquids, (Category 3) H226: Flammable liquid and vapor Acute toxicity, (Category 3) H301: Toxic if swallowed Acute toxicity, (Category 3) H331: Toxic if inhaled Acute toxicity, (Category 3) H311: Toxic in contact with skin Skin corrosion, (Sub-category H314: Causes severe skin burns and eye 1B) damage Serious eye damage, (Category H318: Causes serious eye damage Skin sensitization, (Category 1) H317: May cause an allergic skin reaction Germ cell mutagenicity, H341: Suspected of causing genetic Category 2) defects Carcinogenicity, (Category 1B) H350: May cause cancer Specific target organ toxicity - H370: Causes damage to organs single exposure, (Category 1), Eyes, Central nervous system Specific target organ toxicity - H335: May cause respiratory irritation single exposure, (Category 3), Respiratory system Label elements

Signal word

Danger Danger

Hazard statements

H226 Flammable liquid and vapor. H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H341 Suspected of causing genetic defects. H350 May cause cancer. H370 Causes damage to organs (Eyes, Central nervous system). Restricted to professional users. Reduced Labeling (<= 125 ml) H317 May cause an allergic skin reaction. H341 Suspected of causing genetic defects. H350 May cause cancer. H370 Causes damage to organs. H314 Causes severe skin burns and eye damage. H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled.

Precautionary statements

P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P202 Do not handle until all safety precautions have been read and understood. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Supplemental label elements

none none

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

2.1 Classification of the substance or mixture

Flammable liquids, (Category 3) H226: Flammable liquid and vapor. Acute toxicity, (Category 3) H301: Toxic if swallowed. Acute toxicity, (Category 3) H331: Toxic if inhaled. Acute toxicity, (Category 3) H311: Toxic in contact with skin. Skin corrosion, (Sub-category H314: Causes severe skin burns and eye 1B) damage. Serious eye damage, (Category H318: Causes serious eye damage. 1) Skin sensitization, (Category 1) H317: May cause an allergic skin reaction. Germ cell mutagenicity, H341: Suspected of causing genetic (Category 2) defects. Carcinogenicity, (Category 1B) H350: May cause cancer. Specific target organ toxicity - H370: Causes damage to organs. single exposure, (Category 1), Eyes, Central nervous system Specific target organ toxicity - H335: May cause respiratory irritation. single exposure, (Category 3),

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