General Information
Revision date
2018-02-02
Product name
4-tert-Butylphenylmagnesium bromide solution
CAS No.
63488-10-8
Icons in SDS
Company Information
company name
Sigma-Aldrich
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H225, H250, H261, H302, H314, H318, H336
Hazard statements
Code
Statements
H225
Highly Flammable liquid and vapour
Section 2
OSHA HCS Classification
Flammable liquids (Category 2), H225 Pyrophoric liquids (Category 1), H250 Substances and mixtures, which in contact with water, emit flammable gases (Category 2), H261 Acute toxicity, Oral (Category 4), H302 Skin corrosion (Category 1B), H314 Serious eye damage (Category 1), H318 Specific target organ toxicity - single exposure (Category 3), Central nervous system, H336 For the full text of the H-Statements mentioned in this Section, see Section 16.
Signal word
Danger
Hazard statements
H225 Highly flammable liquid and vapour. H250 Catches fire spontaneously if exposed to air. H261 In contact with water releases flammable gases. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H336 May cause drowsiness or dizziness.
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P222 Do not allow contact with air. P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. P231 + P232 Handle under inert gas. Protect from moisture. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P302 + P334 IF ON SKIN: Immerse in cool water/ wrap in wet bandages. P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER/doctor. P321 Specific treatment (see supplemental first aid instructions on this label). P335 + P334 Brush off loose particles from skin. Immerse in cool water/ wrap in wet bandages. P363 Wash contaminated clothing before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. P402 + P404 Store in a dry place. Store in a closed container. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P422 Store contents under inert gas. P501 Dispose of contents/ container to an approved waste disposal plant.
2.3 Other hazards
Reacts violently with water., May form explosive peroxides.