3-Bromothiophene

Sigma-Aldrich

Revision date : 2018-04-12

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GHS02 GHS06 GHS07 GHS09
Health risk rating 5
Safety risk rating 2
Environmental risk rating 4

General Information

Revision date

2018-04-12

Product name

3-Bromothiophene

CAS No.

872-31-1

Icons in SDS

Company Information

company name

Sigma-Aldrich

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H226, H301, H310, H310+H330, H317, H319, H330, H335, H401, H411

Hazard statements

Code

Statements

H226

Flammable liquid and vapour

Section 2

OSHA HCS Classification

Flammable liquids (Category 3), H226 Acute toxicity, Oral (Category 3), H301 Acute toxicity, Inhalation (Category 1), H330 Acute toxicity, Dermal (Category 2), H310 Eye irritation (Category 2A), H319 Skin sensitisation (Category 1), H317 Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335 Acute aquatic toxicity (Category 2), H401 Chronic aquatic toxicity (Category 2), H411 For the full text of the H-Statements mentioned in this Section, see Section 16.

Signal word

Danger

Hazard statements

H226 Flammable liquid and vapour. H301 Toxic if swallowed. H310 + H330 Fatal in contact with skin or if inhaled. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H411 Toxic to aquatic life with long lasting effects.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. P262 Do not get in eyes, on skin, or on clothing. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ eye protection/ face protection. P284 Wear respiratory protection. P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/doctor. Rinse mouth. P302 + P350 + P310 IF ON SKIN: Gently wash with plenty of soap and water. Immediately call a POISON CENTER or doctor/ physician. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ attention. P362 Take off contaminated clothing and wash before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P391 Collect spillage. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P501 Dispose of contents/ container to an approved waste disposal plant.

2.3 Other hazards

Stench.

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