General Information
Revision date
2015-10-16
Product name
1,4-Phenylene diisocyanate
CAS No.
104-49-4
Icons in SDS
Company Information
company name
Sigma-Aldrich
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H302, H302+H312+H332, H312, H315, H318, H332, H334
Hazard statements
Code
Statements
H302
Harmful if swallowed
Section 2
OSHA HCS Classification
Acute toxicity, Oral (Category 4), H302 Acute toxicity, Inhalation (Category 4), H332 Acute toxicity, Dermal (Category 4), H312 Skin irritation (Category 2), H315 Serious eye damage (Category 1), H318 Respiratory sensitisation (Category 1), H334 For the full text of the H-Statements mentioned in this Section, see Section 16.
Signal word
Danger
Hazard statements
H302 + H312 + H332 Harmful if swallowed, in contact with skin or if inhaled H315 Causes skin irritation. H318 Causes serious eye damage. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Precautionary statements
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear eye protection/ face protection. P280 Wear protective gloves/ protective clothing. P285 In case of inadequate ventilation wear respiratory protection. P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. Rinse mouth. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P302 + P352 + P312 IF ON SKIN: Wash with plenty of soap and water. Call a POISON CENTER or doctor/ physician if you feel unwell. P304 + P340 + P312 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. P332 + P313 If skin irritation occurs: Get medical advice/ attention. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/ physician. P362 Take off contaminated clothing and wash before reuse. P501 Dispose of contents/ container to an approved waste disposal plant.
2.3 Other hazards
Lachrymator.