Note: Ingredients listed on restricted chemical lists
EC/CAS
202-966-0/101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
N/A
General Information
Product name
SIGnature PU Next Day Primer
Icons in SDS
Company Information
company name
SIG Roofing Design Technology
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H226, H315, H317, H319, H332, H334, H335, H351, H373
Hazard statements
Code
Statements
H226
Flammable liquid and vapour
Section 2
2.1 Classification of the substance or mixture
EC 67/548 or EC 1999/45
Classifications
R10 Carc. Cat. 3; R40 Xn; R20/21 Xi; R36/37/38 Xn ; R42/43
Health hazards
Acute toxicity, Inhalation - Category 4 - Warning (CLP : Acute Tox. 4) H332 Skin irritation - Category 2 - Warning (CLP : Skin Irrit. 2) H315 Eye irritation - Category 2A - Warning (CLP : Eye Irrit. 2) H319 Respiratory sensitization - Category 1 - Danger (CLP : Resp. Sens. 1) H334 Skin sensitisation - Category 1 - Warning (CLP : Skin Sens. 1) H317 (Continued) Carcinogenicity - Category 2 - Warning (CLP : Carc. 2) H351 Specific Target Organ Toxicity - Single exposure - Respiratory tract irritation - Category 3 - Warning (CLP : STOT SE 3) H335 Specific Target Organ Toxicity - Repeated exposure - Category 2 - Warning (CLP : STOT RE 2) H373
Physical hazards
Flammable liquids - Category 3 - Warning (CLP : Flam. Liq. 3) H226
2.2 Label elements
EC 67/548 or EC 1999/45 Regulation EC 1272/2008 (CLP)
Hazard pictograms
Xn : Harmful
R-phrase(s)
R10 : Flammable. R20/21 : Harmful by inhalation and in contact with skin. R36/37/38 : Irritating to eyes, respiratory system and skin. R40 : Limited evidence of a carcinogenic effect. R42/43 : May cause sensitization by inhalation and skin contact.
S-phrase(s)
S2 : Keep out of the reach of children. S23 : Do not breathe the gas, fumes, vapours, spray. S25 : Avoid contact with eyes. S36/37 : Wear suitable protective clothing and gloves. S40 : To clean the floor and all objects contaminated by this material, use xylene. S45 : In case of accident or if you feel unwell, seek medical advice immediately ( show the label when possible). S51 : Use only in well-ventilated areas. S63 In case of accident by inhalation remove casualty to fresh air and keep at rest
Contains
Xylene - methylenediphenyl diisocyanate isomers and homologues, <<Contains isocyanates. See information supplied by the manufacturer>>. : Xylene - methylenediphenyl diisocyanate isomers and homologues : EUH204: Contains isocyanates. May produce an allergic reaction
Signal word
Danger
Hazard statements
H226 : Flammable liquid and vapour. H351 : Suspected of causing cancer. H319 : Causes serious eye irritation. H315 : Causes skin irritation. H334 : May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 : May cause an allergic skin reaction. H332 : Harmful if inhaled. H335 : May cause respiratory irritation. H373 : May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
General : P101: If medical advice is needed, have product container or label at hand. P102: Keep out of reach of children. P103: Read label before use. P201: Obtain special instructions before use. 2 (Continued)
Prevention
P280: Wear eye protection, face protection. P280: Wear protective gloves, protective clothing, eye protection, face protection. P285: In case of inadequate ventilation wear respiratory protection. P210: Keep away from heat, sparks, open flames or hot surfaces. – No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical, ventilating, lighting, …, equipment. P260: Do not breathe dust, fume, gas, mist, vapours, spray. P264: Wash thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace.
Response
P321: Specific treatment (see on this label). P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses, if present and easy to do. Continue rinsing. P370+P378 In case of fire Use all extinguishing media for extinction P304+P340 IF INHALED Remove to fresh air and keep at rest in a position comfortable for breathing. P302+P352 IF ON SKIN Wash with plenty of soap and water P303+P361+P353 IF ON SKIN (or hair) Remove immediately all contaminated clothing Rinse skin with water/shower. P308+P313 If exposed or concerned get medical advice P312: Call a POISON CENTER or doctor if you feel unwell. P333+P313 If skin irritation or rash occurs Get medical advice P342+P311 If experiencing respiratory symptoms Call a POISON CENTER or doctor P363: Wash contaminated clothing before reuse.
Storage
P403+P235: Store in well-ventilated place. Keep cool. P403+P233: Store in well-ventilated place. Keep container tightly closed. P405: Store locked up. Disposal considerations : P501: Dispose of this material and its container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
2.3 Other hazards
The substance does not fulfil the criteria to be identified as PBT substance or vPvB substance according to Annex XIII of Regulation REACH.