2-methylbutane, isopentane fraction

Hazard statements (CLP)

H224, H304, H336, H411

Code

Statements

H224

Extremely flammable liquid and vapour

2.1 Classification of the substance or mixture

2-methylbutane 2.1.1 Classification and labelling according to DSD / DPD Classification and labelling in Annex I of Directive 67/548/EEC

Other physicochemical hazards

F+; R12 Extremely flammable; Extremely flammable Flam. Liquid 1 (Hazard statement H224 Extremely flammable liquid and vapour)

Health hazards

Xn; R65 Harmful; Harmful: may cause lung damage if swallowed R67 Vapours may cause drowsiness and dizziness R66 Repeated exposure may cause skin dryness or cracking. Asp. Tox. 1 (Hazard statement: H304. May be fatal if swallowed and enters airways.) STOT Single Exp. 3 (Hazard statement: H336. May cause drowsiness or dizziness). Affected organs: Central Nervous System

Environmental hazards

N; R51/53 Dangerous for the environment; Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment 2.1.2 Classification and labelling according to EC/1272/2008 Annex VI (CLP): Aquatic Chronic 2 (Hazard statement H411 Toxic to aquatic life with long lasting effects.) 2.1.3 Additional labelling requirements: EUH066: Repeated exposure may cause skin dryness or cracking.

Principle Routes of Exposure

Inhalation

2.2 Label elements

2.2.1 EU LABELLING:

Hazard pictograms

Xn; F+; N F+ (extremely flammable) N (dangerous for the environment) Xn (harmful) 2.2.2 CLP LABELLING: GHS07: exclamation mark GHS08: health hazard GHS02: flame GHS09: environment

Signal word

Danger

Hazard statements

R-phrases), Hazard statement, Safety Advice (S-phrases) and Precautionary 2.3.1 Risk phrases and Hazard statement: R12 Extremely flammable R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R51/53 Dangerous for the environment; Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. H224: Extremely flammable liquid and vapour. H304: May be fatal if swallowed and enters airways. H336: May cause drowsiness or dizziness. EUH066: Repeated exposure may cause skin dryness or cracking. 2.3.2 Safety phrases and Precautionary statements:

Precautionary statements

S9 - keep container in a well-ventilated place S16 - keep away from sources of ignition - No smoking S29 - do not empty into drains S33 - take precautionary measures against static discharges S61 - avoid release to the environment. Refer to special instructions/safety data sheets S62 - if swallowed, do not induce vomiting: seek medical advice immediately and show this container or label P210: Keep away from heat/sparks/open flames/... /hot surfaces.... No smoking. (Prevention) P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. (Prevention) P241: Use explosion-proof electrical/ventilating/lighting/... / equipment. (Prevention) P242: Use only non-sparking tools. (Prevention) P243: Take precautionary measures against static discharge. (Prevention) P261: Avoid breathing dust/fume/gas/mist/vapours/spray. P271: Use only outdoors or in a well-ventilated area. P273: Avoid release to the environment. P280: Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 IF SWALLOWED Immediately call a POISON CENTER or doctor/physician P303+P361+P353 IF ON SKIN (or hair) Remove/Take off immediately all contaminated clothing Rinse skin with water/shower. P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P331: Do NOT induce vomiting. P370+P378 In case of fire Use... for extinction P391: Collect spillage. P403+P233: Store in a well-ventilated place. Keep container tightly closed. P403+P235: Store in a well-ventilated place. Keep cool. P405: Store locked up. P501: Dispose of contents/container to... (Disposal)

2.3 Other hazards

Assessment PBT / vPvB: According to Annex XIII of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH): - not fulfilling PBT (persistent/bioaccumulative/toxic) criteria; - not fulfilling vPvB (very persistent/very bioaccummulative) criteria.