Methyl acrylate; acrylic acid methyl ester

SIBUR-NEFTEKHIM JSC

Revision date : 2018-11-16

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GHS02 GHS06 GHS07
Health risk rating 4
Safety risk rating 3
Environmental risk rating 3

Note: Ingredients listed on restricted chemical lists

EC/CAS

96-33-3

Name of the chemical

acrylic acid, methyl ester

Concentration

N/A

EC/CAS

79-10-7

Name of the chemical

acrylic acid

Concentration

N/A

EC/CAS

140-88-5

Name of the chemical

acrylic acid, ethyl ester

Concentration

N/A

EC/CAS

123-86-4

Name of the chemical

acetic acid, butyl ester

Concentration

N/A

EC/CAS

106-63-8

Name of the chemical

acrylic acid, isobutyl ester

Concentration

N/A

EC/CAS

71-36-3

Name of the chemical

1-butanol

Concentration

N/A

EC/CAS

150-76-5

Name of the chemical

Mequinol

Concentration

N/A

EC/CAS

200-659-6

Name of the chemical

Methanol

Concentration

N/A

EC/CAS

205-438-8

Name of the chemical

Ethyl acrylate, when used as a fragrance ingredient

Concentration

N/A

EC/CAS

205-769-8

Name of the chemical

Hydroquinone methylether/Mequinol

Concentration

N/A

General Information

Revision date

2018-11-16

Product name

Methyl acrylate; acrylic acid methyl ester

Substance name

Methyl acrylate

Product Synonyms

methyl propenoate; methyl prop-2-enoate; 2-propenoic acid, methyl

CAS No.

96-33-3

REACH No

01-2119459302-44-0011

1.2.1 Relevant identified uses

Most common technical function of substance

supplier name

SIBUR-NEFTEKHIM JSC

Emergency telephone

+7 8313 27-52-98 (office hours only, GMT+3

Icons in SDS

Company Information

company name

SIBUR-NEFTEKHIM JSC

e-mail address of the competent person responsible for the Safety Data Sheet

infosnh@snh.sibur.ru

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H302, H312, H315, H317, H319, H331, H335, H412

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

2.1 Classification and labelling according to EC/1272/2008 Annex VI (CLP (GHS)):

Other physicochemical hazards

Flam. Liquid 2 (Hazard statement H225 Highly flammable liquid and vapour.)

Health hazards

Acute Tox. 4 (Hazard statement H302 Harmful if swallowed) Acute Tox. 4 (Hazard statement H312 Harmful in contact with skin) Acute Tox. 3 (Hazard statement H331 Toxic if inhaled) Skin Irrit. 2 (Hazard statement H315 Causes skin irritation) Eye Irrit. 2 (Hazard statement H319 Causes serious eye irritation) Skin Sens. 1 (Hazard statement H317 May cause an allergic skin reaction) Specific target organ toxicity - single STOT Single Exp. 3

Hazard statements

H335 May cause respiratory irritation).

Principle Routes of Exposure

Inhalation.

Environmental hazards

Aquatic Chronic 3. (H412: Harmful to aquatic life with long lasting effects.) 2.1.1 CLP LABELLING:

Signal word

Danger

Hazard pictograms

GHS02: flame GHS06: skull and crossbones

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking. P271 Use only outdoors or in a well-ventilated area. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P280: Wear protective gloves/protective clothing/eye protection/face protection. P264 Wash hands thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P241 Use explosion-proof electrical/ventilating/lighting/equipment. P233 Keep container tightly closed. P273 Avoid release to the environment. (Disposal) P501 Dispose of contents/container to hazardous or special waste collection point.

Response

P301+P310 IF SWALLOWED Immediately call a POISON CENTER P302+P352 IF ON SKIN: Wash with plenty of soap and water P332+ P313 If skin irritation occurs: Get medical advice/ attention. P303 + P361 + P353 If on skin (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. P337 + P313 If eye irritation persists: Get medical advice/attention. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P370 + P378 In case of fire: Use water spray, dry powder, foam or carbon dioxide for extinction.

Storage

P405 Store locked up. P410+P403: Protect from sunlight. Store in a well-ventilated place. P235 +P410 Keep cool. Protect from sunlight. P403+P233: Store in a well-ventilated place. Keep container tightly closed.

2.3 Other hazards

Assessment PBT / vPvB: According to Annex XIII of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH): - not fulfilling PBT (persistent/bioaccumulative/toxic) criteria; - not fulfilling vPvB (very persistent/very bioaccummulative) criteria.

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