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Hazard statements (CLP)

H225, H226, H315, H317, H319, H332, H336, H351, H361f, H411, H412

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

as spilled μg/l Heteropneustes product. 0,83 mg/m3

2.1 Classification of the substance or mixture

and 62 its ≤ x container 50% is based oxidants,chlorosulphuric 10.6. Sensitising SECTION < 66 - 11. IMDG: on calculation methods Hazardous must not available International for the 2. Hazards be Eye decomposition disposed skin Maritime Irrit. 2 of H319, acid. as per Annex I of CLP, Part 3, unless determined otherwise in Section Irritation Code 75 identification safely. Skin products Caution for dangerous goods Irrit. should 2 H315, be Skin exercised Sens. when 1A H317 handling emptied bw/d EC See Flash 2-Hydroxyethyl containers Section point that 1 for methacrylate have emergency not been contact cleaned information. or rinsed. 37,8 < T < 61 °C Remark:closed cup 2.1. - Environmental CAS See Auto-ignition LC50 Empty Regulation IMO: International Classification Section - containers for Fish (EU) 8 temperature for 2019/1148 hazards: of information or the Maritime containers Redness substance Product - on may Organization the classification is based on calculation methods appropriate or marketing retain mixture some protective and product use not equipment. of available residue. 227000 explosives μg/l Avoid precursors TPO Fish dispersion - Pimephales as per Annex I of CLP, Part 4, unless determined otherwise in and runoff promelas of spilled - Juvenile material (Fledgling, and contact Hatchling, with soil, Wanling) Ingestion: Health Under GERM - Section methacrylic See Decomposition waterways, not applicable INDEX: normal section drains CELL - 12. Derived Identifier No MUTAGENICITY 13 acid, specific conditions for temperature no-effect in Annex and monoester further data. of storage sewers. information VI level of CLP with propane-1,2-diol - DNEL and use, on waste treatment. / DMEL no hazardous decomposition products should be generated. not available N-BUTYL ACETATE - LC50: Lethal Concentration Effects is classified 50% on consumers 12.2. The INDEX Threshold pH Persistence product Limit and Value degradability set forth as hazardous 15 pursuant in (EC) ≤ x < 16,5 to the not provisions Effects on workers 1272/2008 (CLP) (and subsequent available Eye Irrit. 2 H319, Skin Regulation Sens. 1 H317 4.3. Does - LD50: amendments Indication Route not Lethal meet of exposure of dose the any classification supplements). immediate 50% Acute medical criteria for Acute attention this hazard and class special Chronic treatment safety datasheet that complies SECTION 11. Toxicological information EC Kinematic Substances Type Chronic needed viscosity in and Candidate 248-666-3 Acute local Country List (Art. The TWA/8h provisions of (EU) Regulation 59 product Acute REACH) thus requires Chronic not available a STEL/15min Chronic SECTION Remarks 2020/878. - OEL: Occupational CAS Dynamic TPO with / the Observations viscosity 27813-02-1 7. 14. Handling Transport Exposure local and Level information mg/m3 storage systemic ppm 1500 to mg/m3 local 6000 mPa·s ppm systemic local systemic Any Notes CARCINOGENICITY - PBT: 2-Hydroxyethyl Solubility In Titanium the OEL Oral to Persistent, additional absence physician: bioaccumulative dioxide information of methacrylate experimental Treat symptomatically. EU concerning data 241 for the the risks and toxic Contact a poison treatment specialist product for 50 health itself, Non solubile health and/or 723 hazards the in acqua environment 0,0833 immediately if large quantities have been ingested or inhaled. 150 are fredda, evaluated are given according in sections to the 11 properties and 12 of of this 7.1. 14.1. Precautions - PEC: Predicted environmental Concentration UN number for the sheet. substances it or ID safe number handling mg/kg bw/d INDEX Health contains, Degradability: Substances - Derived using subject information the 607-124-00-X no-effect criteria to authorisation not specified level available - DNEL in (Annex 15 the ≤ x / applicable DMEL < XIV 16,5 REACH) non regulation solubile Eye for Irrit. in classification. acqua 2 H319, calda. Skin Irrit. 2 H315, Skin Sens. 1 H317, Classification note Hazard Does - PEL: Partition It None is therefore Inhalation not Predicted classification coefficient: meet the exposure necessary classification SECTION n-octanol/water and indication: Protective ADR / RID, measures: - PMT: to Effects level criteria for this hazard class take into on account Persistent, mobile and toxic IMDG, 5. Firefighting consumers IATA: Wear appropriate the concentration not available measures UN 1993 according personal protective equipment (see Section 8). Persons with a history of skin sensitization problems of the individual 0,145 to Annex hazardous VI to Effects the substances CLP on workers mg/m3 Regulation: indicated D in section 3, to evaluate the 0,822 mg/m3 12.3. EC Vapour toxicological Bioaccumulative Flammable Route pressure of exposure effects liquid, 212-782-2 of potential category exposure Acute 3 to the product. Acute <0.0013kPa Chronic should not be employed in any process in which this product is used. Do not get in eyes, on skin or clothing. Do not swallow. REPRODUCTIVE - PNEC: Skin Predicted TOXICITY H226 Chronic Acute no effect concentration Flammable local liquid Acute and vapour. Chronic Chronic 0,0833 0,233 5.1. CAS 14.2. Avoid UN breathing Density Substances Extinguishing Eye irritation, proper shipping and/or subject relative 868-77-9 vapors or name category media to exportation density 2 local mists. Use only with adequate ventilation. Wear an appropriate respirator when ventilation is inadequate. Do not reporting systemic pursuant 1,12 to Regulation local (EU) H319 systemic 649/2012: Causes serious eye systemic irritation. local systemic 11.1. TPO - REACH: Regulation (EC) 1907/2006 Relative None Information Skin Oral irritation, vapour on density category hazard 2 classes as defined 2 in Regulation not available (EC) No 1272/2008 mg/kg bw/d H315 2 Causes skin irritation. mg/kg enter storage areas and confined spaces unless adequately ventilated. Store in the original container or an approved alternative made of a Does - RID: not Regulation meet the concerning classification the criteria international for this transport hazard class of dangerous goods by train bw/d INDEX Suitable Particle methacrylic compatible ADR / RID: material, kept FLAMMABLE Skin characteristics sensitization, extinguishing acid, 015-203-00-X monoester category media: with Use tightly closed LIQUID, 1A propane-1,2-diol dry 2 ≤ chemicals, when not mg/kg x < 2,5 bw/d CO₂, N.O.S. in use. Store and use away from heat, sparks, open flames or any other sources of ignition. not water applicable Repr. spray 2 or H361f foam. H317 mg/kg bw/d May cause an allergic skin reaction. - TLV: Threshold Limit Value EC Unsuitable Partition Substances Hazardous Inhalation N-BUTYL coefficient: extinguishing subject to 278-355-8 the ACETATE n-octanol/water to aquatic the media: Rotterdam 300 environment, Do not Convention: use 300 chronic water jets. 35,7 0,97 potential: H412 12 low 600 Harmful to aquatic 600 life with long 300 lasting effects. 48 Use IMDG: explosion-proof electrical Legend: STOT - TLV CEILING: - SINGLE Concentration EXPOSURE that should not be exceeded during any time of occupational exposure. FLAMMABLE equipment LIQUID, (ventilation, N.O.S. lighting and material handling). Use only non-sparking tools. Take precautionary CAS None measures IATA: toxicity, Result: against electrostatic category Eyes 75980-60-8 3 - Moderately FLAMMABLE mg/m3 irritating. mg/m3 discharges. LIQUID, Empty Species: Rabbit. mg/m3 N.O.S. containers retain product residue and can be dangerous. Do not reuse the container. Exposure: 100 mg/m3 mg mg/m3 5.2. 9.2. N-BUTYL (C) - TWA: Special Other Skin Specific = CEILING Time-weighted information hazards ACETATE ; INHAL target arising average organ from = Inhalable toxicity exposure the (single substance Fraction 6 limit exposure): ; RESP = Respirable Fraction ; THORA = Thoracic Fraction. or mixture category 3. Target 3,4 organs: Narcotic effects. 11 7 General VND Does - TWA = not STEL: hazard occupational meet Short-term identified the classification hygiene but exposure no advice: DNEL/PNEC criteria limit Eating, for this available drinking hazard and class ; NEA smoking = no are exposure prohibited expected in areas ; where NPI = the no material hazard identified is handled, ; stored LOW or = low hazard 14.3. processed. INDEX Partition Substances Transport coefficient: Workers subject hazard 607-025-00-1 n-octanol/water to the Stockholm 2 Convention: must class(es) wash ≤ mg/kg x < 2,5 bw/d and faces before eating, drinking and smoking. Remove contaminated clothing and protective 2,3 Flam. potential: Liq. low 3 mg/kg H226, bw/d Acute Tox. 4 H332, Eye mg/kg Irrit. 2 H319, STOT SE mg/kg 3 H336, ; - VOC: MED Volatile = medium elements organic hazard Compounds ; HIGH their = hands high hazard. 2.2. Hazards None equipment before entering food and beverage areas. See also Section 8 for further information on hygiene measures. Label Titanium arising from dioxide the substance or mixture: Flammable liquid Aquatic and vapour. Chronic Runoff 3 H412, into EUH066 sewers may create bw/d a fire or explosion hazard. bw/d Target - vPvB: organs EC In 9.2.1. ETHYL the event Information Very persistent and very bioaccumulative Result: ACETATE of a Skin 204-658-1 fire with - or Mild regard overheating, irritant, to physical species: a pressure hazard Human, increase classes exposure: will STA occur 72 hours Inhalation and 300 the container ug gas: I 4500 may ppm burst with the risk of a subsequent explosion. ADR / RID: - vPvM: Exposure Very controls persistent and very mobile Class: 3 Label: 3 8.2. Hazard CAS Hazardous Partition

2.2 Label elements

0444-239569 from of criteria chemicals mg/kg established bw/d by the CLP Regulation, Annex I, Part 2. The mg/kg Flammability Chronic coefficient: Combustion controls 123-86-4 pursuant n-octanol/water Products: to EC Regulation Decomposition

Disposal

Skin Point NOEC methods: for Fish data for The generation 3 - 40 of waste should be not avoided available 75,6 mg/l or minimized Pimephales 2,5 wherever promelas possible. - Waste packaging should be recycled. 4,2 6.4. polyurethane Inhalation: ETHYL RESPIRATORY - evaluation Lower Chronic Incineration IATA DGR: Reference Contained explosive ACETATE NOEC No of International or substance to acrylate chemical-physical specific landfill for other OR SKIN limit Crustacea should sections data. oligomer Air SENSITISATION Transport only be considered when not recycling properties Association are reported Dangerous in section Goods available 2,4 mg/l is not feasible. 9. Regulation mg/kg bw/d bw/d mg/kg Skin - Health INDEX Upper Special IC50: Incompatible Point explosive contact: Immobilization Symptoms

Precautionary statements

with: Product limit This material acids,bases,strong Concentration may classification be as follows and 62 its ≤ x container 50% is based oxidants,chlorosulphuric Sensitising SECTION 66 IMDG on calculation methods Hazardous must not available International for the Hazards be Eye decomposition disposed skin Maritime Irrit. 2 of H319, acid. as per Annex I of CLP, Part 3, unless determined otherwise in Section Irritation Code 75 identification safely. Skin products Caution for dangerous goods Irrit. should H315, be Skin exercised Sens. when 1A H317 handling emptied bw/d EC See Flash 2-Hydroxyethyl containers Section point that 1 for methacrylate have emergency not been contact cleaned information or rinsed 37,8 < T < 61 Remark:closed cup Environmental CAS See Auto-ignition LC50 Empty Regulation IMO: International Classification Section containers for Fish EU) temperature for 2019/1148 hazards of information or the Maritime containers Redness substance Product on may Organization the classification is based on calculation methods appropriate or marketing retain mixture some protective and product use not equipment of available residue 227000 explosives μg/l Avoid precursors TPO Fish dispersion Pimephales as per Annex I of CLP, Part 4, unless determined otherwise in and runoff promelas of spilled Juvenile material Fledgling, and contact Hatchling, with soil, Wanling) Ingestion Health Under GERM Section methacrylic See Decomposition waterways, not applicable INDEX: normal section drains CELL Derived Identifier No MUTAGENICITY acid, specific conditions for temperature no-effect in Annex and monoester further data. of storage sewers information VI level of CLP with propane-1,2-diol DNEL and use, on waste treatment DMEL no hazardous decomposition products should be generated not available N-BUTYL ACETATE LC50: Lethal Concentration Effects is classified 50% on consumers The INDEX Threshold pH Persistence product Limit and Value degradability set forth as hazardous 15 pursuant in (EC) x < 16,5 to the not provisions Effects on workers P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 Wear protective gloves/ protective clothing / eye protection / face protection. P370+P378 In case of fire: use . . . to extinguish. P261 Avoid breathing dust / fume / gas / mist / vapours / spray. P333+P313 If skin irritation or rash occurs: Get medical advice / attention. P337+P313 If eye irritation persists: Get medical advice / attention.

Environmental hazards

0,0833 immediately if large quantities have been ingested or inhaled 150 are fredda, evaluated are given according in sections to the 11 properties and 12 of of this 14.1. Precautions PEC: Predicted environmental Concentration UN number for the sheet substances it or ID safe number handling mg/kg bw/d INDEX Health contains, Degradability Substances Derived using subject information the 607-124-00-X no-effect criteria to authorisation not specified level available DNEL in (Annex the ≤ x / applicable DMEL XIV 16,5 REACH) non regulation solubile Eye for Irrit in classification acqua H319, calda. Skin Irrit. 2 H315, Skin Sens. 1 H317, Classification note Hazard Does PEL Partition It None is therefore Inhalation not Predicted classification coefficient meet the exposure necessary classification SECTION n-octanol/water and indication Protective ADR / RID, measures PMT to Effects level criteria for this hazard class take into on account Persistent, mobile and toxic IMDG, Firefighting consumers IATA Wear appropriate the concentration not available measures UN 1993 according personal protective equipment (see Section 8). Persons with a history of skin sensitization problems of the individual 0,145 to Annex hazardous VI to Effects the substances CLP on workers mg/m3 Regulation indicated D in section 3, to evaluate the 0,822 mg/m3 EC Vapour toxicological Bioaccumulative Flammable Route pressure of exposure effects liquid, 212-782-2 of potential category exposure Acute 3 to the product Acute 0.0013kPa Chronic should not be employed in any process in which this product is used. Do not get in eyes, on skin or clothing. Do not swallow REPRODUCTIVE PNEC Skin Predicted TOXICITY H226 Chronic Acute no effect concentration Flammable local liquid Acute and vapour. Chronic Chronic 0,0833 0,233 CAS Avoid UN breathing Density Substances Extinguishing Eye irritation, proper shipping and/or subject relative 868-77-9 vapors or name category media to exportation density local mists. Use only with adequate ventilation. Wear an appropriate respirator when ventilation is inadequate. Do not reporting systemic pursuant 1,12 to Regulation local EU) H319 systemic 649/2012 Causes serious eye systemic irritation. local systemic TPO

Hazard categories

of dangerous goods by train bw/d INDEX Suitable Particle methacrylic compatible ADR / RID: material, kept FLAMMABLE Skin characteristics sensitization, extinguishing acid, 015-203-00-X monoester category media: with Use tightly closed LIQUID, 1A propane-1,2-diol dry 2 ≤ chemicals, when not mg/kg x < 2,5 bw/d CO₂, N.O.S in use. Store and use away from heat, sparks, open flames or any other sources of ignition not water applicable Repr spray 2 or H361f foam H317 mg/kg bw/d May cause an allergic skin reaction TLV: Threshold Limit Value EC Unsuitable Partition Substances Hazardous Inhalation N-BUTYL coefficient extinguishing subject to 278-355-8 the ACETATE n-octanol/water to aquatic the media Rotterdam 300 environment, Do not Convention use 300 chronic water jets 35,7 0,97 potential: H412 low 600 Harmful to aquatic 600 life with long 300 lasting effects 48 Use IMDG: explosion-proof electrical Legend STOT TLV CEILING SINGLE Concentration EXPOSURE that should not be exceeded during any time of occupational exposure FLAMMABLE equipment LIQUID, ventilation, N.O.S. lighting and material handling). Use only non-sparking tools. Take precautionary CAS None measures IATA toxicity, Result against electrostatic category Eyes 75980-60-8 Moderately FLAMMABLE mg/m3 irritating. mg/m3 discharges LIQUID, Empty Species: Rabbit. mg/m3 N.O.S containers retain product residue and can be dangerous. Do not reuse the container Exposure: 100 mg/m3 mg mg/m3 9.2. N-BUTYL C) TWA Special Other Skin Specific CEILING Time-weighted information hazards ACETATE INHAL target arising average organ from Inhalable toxicity exposure the (single substance Fraction limit exposure) RESP = Respirable Fraction ; THORA = Thoracic Fraction or mixture category 3. Target 3,4 organs: Narcotic effects 11 General VND Does TWA = not STEL hazard occupational meet Short-term identified the classification hygiene but exposure no advice DNEL/PNEC criteria limit Eating, for this available drinking hazard and class NEA smoking no are exposure prohibited expected in areas ; where NPI = the no material hazard identified is handled, ; stored LOW or = low hazard processed INDEX Partition Substances Transport coefficient Workers subject hazard 607-025-00-1 n-octanol/water to the Stockholm 2 Convention must class(es) wash mg/kg x < 2,5 bw/d and faces before eating, drinking and smoking. Remove contaminated clothing and protective 2,3 Flam potential Liq. low 3 mg/kg H226, bw/d Acute Tox. 4 H332, Eye mg/kg Irrit. 2 H319, STOT SE mg/kg H336, VOC MED Volatile medium elements organic hazard Compounds HIGH their = hands high hazard Hazards None equipment before entering food and beverage areas. See also Section 8 for further information on hygiene measures Label Titanium arising from dioxide the substance or mixture: Flammable liquid Aquatic and vapour Chronic Runoff H412, into EUH066 sewers may create bw/d a fire or explosion hazard bw/d Target vPvB: organs EC In ETHYL the event Information Very persistent and very bioaccumulative Result ACETATE of a Skin 204-658-1 fire with or Mild regard overheating, irritant, to physical species a pressure hazard Human, increase classes exposure will STA occur 72 hours Inhalation and 300 the container ug gas 4500 may ppm burst with the risk of a subsequent explosion ADR / RID vPvM Exposure Very controls persistent and very mobile Class: 3 Label: 3 Hazard CAS Hazardous Partition Healthcare

Remarks

/ Observations 15.2. CAS When STOT 1. Regulation phosphorus Partition Chemical - choosing REPEATED coefficient: oxides safety (EC) 13463-67-7 personal

Potential chronic health

of the European isolate from work glove the area Parliament short by and removing material (see standard EN 374): compatibility, degradation, failure time and long-term all exposure people RESP from the area of the accident in case of fire. No Category: permeability. Does 7. Regulation not meet P5c. (EU) 487/2013 (IV criteria Atp. CLP) for of this the hazard European class Parliament The action TLV-ACGIH Notification No Text specific full shall of hazard wording test and (H) data be taken MAPP of hazard indications regarding involving threshold

Hazard statements

mentioned personal reactivity 5000 tonnes. 0,2 is risk is in available given section 2-3 or without in section for of this the product adequate 16 of the sheet: or its ingredients. training. sheet. Move containers RESP from fire area if this can be done without risk. Signal The 8. Regulation Use Information work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on water words: (EU) 944/2013 (V Atp. spray not available to keep containers Warning exposed to fire cool. CLP) of the European Parliament 11.2. 14.4. the Safety ratio threshold: 50000 tonnes 9. Regulation Information Packing duration group and (EU) on type 605/2014 other of use. (VI Atp. CLP) of the European Parliament Special protective equipment for firefighters: Firefighters must wear appropriate protective equipment and self-contained breathing apparatus N-BUTYL Flam. Liq. ACETATE 2 Flammable liquid, category 2 SKIN 10. Regulation (SCBA) Interactive with effects PROTECTION a face shield operating in positive pressure mode. Firefighter clothing (including helmets, protective boots and gloves) compliant (EU) 2015/1221 (VII Atp. CLP) of the European Parliament 7.3. Specific SECTION Wear Based ADR 11. Regulation Decomposes Flam. Liq. / category RID, on statements: the IMDG, end 3 use(s) 4. available (EU) First II professional on contact with: Flammable IATA: 2016/918 aid data, measures the long-sleeved (VIII product water. III Atp. CLP) of the European Parliament does overalls liquid, category 3 not contain and safety substances footwear listed (see in Regulation the main European 2016/425 lists and of standard potential EN or ISO suspected 20344). endocrine Wash body

Results of PBT and vPvB assessment

with the European standard EN 469 will provide a basic level of protection for chemical incidents. ETHYL with disruptors Carc. ACETATE Regulation soap and 2 with water human (EU) 2016/1179 after

Potential health effects

removing (IX Flammable Carcinogenicity, category 2 Atp. protective under CLP) evaluation. liquid and vapour. clothing. 12. H226 Information not available 4.1. Recommendations: Consider Description Decomposes Repr. 2 Regulation the appropriateness of slowly (EU) 2017/776 of (X Causes first Not aid into available. measures acetic Reproductive providing Atp. CLP) serious acid and ethanol antistatic toxicity, under eye clothing irritation. in the case of working environments in which there is a risk of explosion. category the effect 2 of light, air and water. 13. H319 On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%. Specific EYE Acute solutions Regulation PROTECTION Tox. 4 for the industrial Acute (EU) 2018/669 (XI Causes Atp. CLP) sector: toxicity, Not available. category 4 14. H315 ACUTE TOXICITY skin irritation. 10.2. Contact Wear Chemical Eye Irrit. Regulation airtight protective with 2 stability eyes: Immediately Eye flush (EU) 2019/521 (see irritation, standard eyes category with plenty 2 of water, occasionally lifting the upper and lower eyelids. Check and remove any contact 16321). 15. H317 goggles (XII May Atp. cause CLP) an EN allergic ISO skin reaction. lenses. RESPIRATORY Skin Continue Delegated Regulation Irrit. 2 PROTECTION rinsing for at least (UE) 2018/1480 Skin 10 irritation, minutes. category Consult 2 a doctor. 16. H412 ATE (Inhalation - gas) of the mixture: Harmful to (XIII aquatic Atp. life CLP) with long > 20000 lasting mg/l effects. ... / >>

Contains

methacrylic acid, monoester with propane-1,2-diol 2-Hydroxyethyl methacrylate polyurethane acrylate oligomer Identification x = Conc. %

2.3 Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%. The product does not contain substances with endocrine disrupting properties in concentration ≥ 0.1%. 3.2. Mixtures