GLO-NETIC AEROSOL

Hazard statements (CLP)

H220, H304

Code

Statements

H220

Extremely flammable gas

2.1 Classification of the substance or mixture

Classification

2.2 Label elements

Labeling

Signal word

Danger

Hazardous Ingredients

Distillates (petroleum), hydrotreated light Propane Butane ··•·····•···········································································•··································•····• cl\s ··54742 47~3······· ··01sfiflates.(pefroieum),hydr6treatedTight 80-90% ·cfo.s-14-98-6 ____________ -- -- ··--·------........................ --·------------...... - EINECS: 265-149-8 ! .. -----.. ·-·---·--.. ·-- 1-10% ·Most important ingredients cl\s· · 5·474 z 47 3··········r·orsrn1ates(!Jefroieum.),hycfr6treatea119ht EINECS: 265-149-8' -······--·cA·s·-7~fM:S~--- i ProPfin·e··--···-····-- --············-·--------·-·--·---·-··········--·---·--·-·--··--·-----·-· ........... --·-----· CAS 75-28:5 ·Butane .. ----------·---...... _________ .. ________ ..... --- .. I: Eirst ... aid measures _ · 4.1 Description of first aid measures ·After inhalation: Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist In case of unconsciousness place patient stably in side position for transportation. Take affected persons into fresh air and keep quiet · After skin contact: Immediately wash with water and soap and rinse thoroughly. If skin irritation continues, consult a doctor. · After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. ·After swallowing: Do not induce vomiting; immediately call for medical help. A person vomiting while lying on their back should be turned onto their side. (Contd. on page 3) USA r--~r~~e name: GLO-NETIC Aerosol ·~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~---, I {Contd. of page 2) · 4.2 l\ofost important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed L__ No further relevant information available. · 5.1 Extinguishing media · Suitable extinguishing agents: Water haze Foam ABC powder ·For safety reasons unsuitable extinguishing agents: Water spray · 5.2 Special hazards arising from the substance or mixture Carbon monoxide and carbon dioxide · 5.3 Advice for firefighters · Protective equipment: I _ -~-W~e_a_r_se_1_~_co_n_t_a_in_e_d_r_e_sp_i_ra_t_o_ry_p_r_o_te-c-ti-ve~d-e_v_1·c_e_·~~~~~~~~~~~~~~~~~~~~~~~ L Wear fully protective suit. Ji 1\ cciftental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation · 6.2 Environmental precautions: Contain spill and then collect with non-combustible absorbent material. Do not allow to enter sewers/ surface or ground water. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Collect liquid in an appropriate container or absorb with an inert material such as vermiculite, dry sand, or earth; DO NOT use combustible materials. Place in a chemical waste container. · 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. · 7.1 Precautions for safe handling Keep away from sources of ignition .. · Information about protection against explosions and fires: Keep away from sources of ignition. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid contact with skin and eyes. Avoid breathing vapor or mist. Do not swallow. Use only outdoors or in a well-ventilated area. When using do not eat, not drink or smoke. (See section 8) Containers may be hazardous when empty since residue may be present. · 7.2 Conditions for safe storage, including any incompatibilities

Hazard statements

H304 May be fatal if swallowed and enters airways. H220 Flammable aerosol. Contains gas under pressure; may explode if heated.

Precautionary statements

P210 Keep away from heaVsparks/open flames/hot surfaces. - No smoking. P241 Use explosion-proof electrical/ventilating/lighting/equipment. P301+P310 If swallowed: Immediately call a doctor. P331 Do NOT induce vomiting P305+P351 +P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P405 Store locked up. P403+P410 Protect from sunlight. Store in a well-ventilated place. Do not expose to temperatures exceeding 50 °C/122 Of P501 Dispose of contents/container in accordance with local/regional/national/international regulations IContd. on oaae 21 ~de name: GLO-NETIC Aerosol (Contd. of page 1)

Classification system

NFPA ratings (scale 0 - 4) Health= 1 Fire= 4 Reactivity = 0 ·HM IS-ratings (scale 0 - 4) Health= 1 4 Fire= 4 Reactivity = 0

PBT Substances

Not applicable

vPvB Substances

Not applicable · 3.2 Chemical characterization: Mixtures · Description: Mixture of the substances listed below with nonhazardous additions.

Storage

Protect from sunlight. Store in a well-ventilated place. Do not expose to temperatures exceeding 50 °C/122 °F · Requirements to be met by storerooms and receptacles: See above ·Information about storage in one common storage facility: Not required. · Further information about storage conditions: None. {Contd. on page 4) USA ~-de name: GL0-1'\ETIC Aerosol 0 '--- (Contd. of page 3) Specific end use(s) No further relevant information available_ - Additional information about design of technical systems: No further data; see item 7. · 8. l Control parameters · Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.

Additional information

The lists that were valid during the creation were used as basis · 8.2 Exposure controls · Personal protective equipment: · General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes. · Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. Ventilation System: A system of local or general exhaust is recommended to keep employee exposure below the airborne exposure limits. If exposure limit is exceeded use organic vapor respirator (type A), or self contained breathing apparatus. · Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · ;\faterial of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material cannot be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses Tightly sealed goggles ·Body protection: Use suitable protective clothing. USA (Contd. on page 5) r· Trade name: GLO-NETlC Aerosol ·-----------------------~----------, (Contd. of page 4) · 9.l Information on basic physical and chemical properties · General Information ·Appearance: Form: Spray can under pressure. Liquid with brown particles, gas propellant Color: water-white ·Odor: Hydrocarbons ·Odour threshold: Not determined. -------·-----------··------- ·pH-value: Not determined. · Change in condition Melting point/Melting range: Liquid: -22°C. -7°F Boiling point/Boiling range: Liquid: 240 °C (464 °F) ..... ·····--· .. ,,.,,,,,.,, ......... _ .... . · Flammability (solid, gaseous): Not applicable. ·---·-··----·· · Ignition temperature: Liquid: 224 °C (435°F) · Decomposition temperature: Not determined. -··-·-·----··········-·······················-···----------··-------·-········-···------ · Auto igniting: Not determined. · Danger of explosion: Can under pressure with a flammable gas. · Explosion limits: Lower: Liquid: 0.5%(V). Upper: Liquid 7.0%(V). Propellant 'JI..; -_ cq.fON -1l. Nh ·------- ·Vapor pressure: Liquid <0.1 mm Hg @ 20°c, 68°F calculation. · Density at 20 °C (68 °F): Liquid 0.81 g/cm3 (6.7 lbs/gal) (ASTM D-1298) ·Relative density Not applicable --- ·--·-----· ·Vapour density Liquid 6.8. Propellant: 1.766 ··············································· · Evaporation rate Not determined. ·Solubility in I :Vliscibility with Water: Negligible · Partition coefficient (n-octanol/water): Not determined. -------------- -·-·----··-·- · Viscosity: Dynamic: Not determined. Kinematic at 40 °C (I 04 °F): Liquid 2.5 cSts (ASTM D-445) · Solvent content: Organic solvents: 0.0 %

Further information

I 0. I Reactivity · 10.2 Chemical stability · Thermal decomposition I conditions to be avoided: No decomposition if used according to specifications. · I 0.3 Possibility of hazardous reactions No dangerous reactions known. (Contd. on page 6) 11 ~d~-;;·~me GLO-NETIC Aerosol (Contd. of page 5) · I 0.4 Conditions to avoid No further relevant information available. · I 0.5 I neompatible materials: Avoid contact with acetaldehyde, acids, chlorin_e. ethl:'!,ene oxide, is~cyanate anq strong_oxidizing agents Hazardous decomposition products I A'tc• !lc•aS-lf $' ~ ll=ff"rcl' A'tc• OllJl irt · 11.1 Information on toxicological effects · Acute toxicity: Information on hazardous ingredients · Primary irritant effect: ·on the skin: No irritant effect. · on the eye: Strong irritant with the danger of severe eye injury. ·Sensitization: No sensitizing effects known. · Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Irritant · Carcinogenic categories -·-·--·-·:-1ARC.(lnte·~~-~trmm.Agen·cy ro·~-ReSea-rch·--o~~r)CO-Dtains no 1-n-greiliei1"tSiTS!edas·a··camnogen·----.. ----Group 1 Carcinogenic to humans · ··· ... Group 2A Probably carcinogenic to humans Group 28 Possibly carcinogenic to humans Group 3 Not classifiable as to its carcinogenicity to humans Group 4 Probably not carcinogenic to humans --········-····-----------.. ·--- · NTP (National Toxicology Program) ·· ······ None orthe in9redien!Sis nsted. . __ .... _________________________________________________________ _________________ _ __ ·····-···---................................... , , ................ , ·OSHA-Ca (Occupational Safety & Health Administration) · 12. I Toxicity · Aquatic toxicity: Not determined · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Ecotoxical effects: · Remark: No data available ·Additional ecological information: · General notes: Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. (Contd. on page 7) USA L ·------------------------------------------__J Trade name: GLO-NE,TIC. Aerosol (Contd. of page 6) · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. · 13.1 Waste treatment methods · Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Waste/ unused products Collect all waste in suitable and labeled containers and dispose according to local legislation. · Uncleaned packagings: · Recommendation: Waste I used products Waste products and empty packages dispose of in accordance with local regulations. Empty containers may contain residue and vapors. · Recommended cleansing agent: Water, if necessary with cleansing agents. 111 !Ji't ansnort information · 14.l UN-Number ·DOT Consumer commodity ORM-0 · ADR, JMOG, JATA UN 1950 · 14.2 UN proper shipping name ·ooT Consumer commodity ORM-0 · ADR, IMDG, IATA Aerosols, flammable 14.3 Transport hazard class( es) ·DOT ADR, IMDG, IATA Aerosols, flammable, 2.1 · 14.4 Packing group ·DOT Consumer commodity ORM-D · ADR, IMDG, IATA None · 14.5 Environmental hazards: · Marine pollutant: Not applicable · l 4.6 Special precautions for user Not applicable. (Contd. on page 8) USA Trade name: GLO-l\ETIC Aerosol (Contd. of page 7) · --, 4.7 t'rarlsporflnhi.likaccordlngtoAnneX nor .. ·····1 I \"lARPOL73/78 and the IBC Code Not applicable. 1·· -~~:;sport7AddlffonaTlilformation: · Quantity limitations ' (•"-. ···-,,.,// On passenger aircraft/rail: 75kg (165 lbs) /~ '··,,./ On cargo aircraft only: 150kg (330 lbs) ·Remarks: i -----·-1 L ·UN "Model Regulation": ____ ____j . I . 15: Regulator~ information . _ · · 15. I Safety, health and environmental regulations/legislation specific for the substance or mixture ·Sara ·Section 355 (extremely hazardous substances): ----NoneoTtt1eln9feaTenT1ST1Sted._________ ·--------- .Section 313 (Specific toxic chemical listings): ·· · ···· · ·f\fo-n·e--orfhe···1rl'g·recne·n1s·Ts· .. rrstecr ............................... ,. ......... .,.,., .. -... ··--·- -----·----·-··-·--··-··-·---····--··---- Section 311/312 ......... fiTimediaie (acute) health hazard, Fire hazard ·------··----·--····· · TSCA (Toxic Substances Control Act): - -64742-4 7-8 i DistillateS{petroleum-).-h-y-d-ro-tr_e_a-te_d_l_ig_h_t ---- . Proposition 65 known to cause cancer: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for females: ---Hone of the ingredients is listed. ·------·····-·---······--- ·Chemicals known to cause reproductive toxicity for males: ·· ·····Nane·0nhein9redlentsTs.Tisfed: ·Chemicals known to cause developmental toxicity: ----None of thelngrecffen-isis-ffsted:---·----~---------------· · Cancerogenity categories ----------- . EPA (Environmental Protection Agency) ··· None··0rfi1efrigredientsis··11stea:·················--- · TLV (Threshold Limit Value established by ACGIH) (Contd. ori i>a9e 9) USA I Trade name: GL0-1'\ETIC Aerosol I· ...... '>dds H-Ca (Contd. of page 8) (~atfo al institute fo~ Orcui)ation al Safety anCIHealth) JI """l i 1 Noneorthefri9redienfsisiistea. ................................... J .. . . . . ... ....... ... . 1