Pygas (benzene <10%)

Shell Trading Rotterdam B.V

Revision date : 2025-07-11

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GHS02 GHS07 GHS08 GHS09
Health risk rating 5
Safety risk rating 4
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

271-138-9/68516-20-1

Name of the chemical

Naphtha (petroleum), steam-cracked middle arom

Concentration

>=50-<=70

EC/CAS

270-695-5/68476-55-1

Name of the chemical

Hydrocarbons, C5-rich

Concentration

>=30-<=50

EC/CAS

98-83-9

Name of the chemical

alpha-Methylstyrene

Concentration

>=0-<=3

EC/CAS

106-99-0

Name of the chemical

1,3-Butadien

Concentration

>=0,1-<=1 450-8

EC/CAS

77-73-6

Name of the chemical

3a,4,7,7a-tetrahydro-4,7-methanoindene

Concentration

>=1-<=20

Listed in

EC/CAS

100-42-5

Name of the chemical

Styrene ( Vinyl benzene )

Concentration

>=1-<=8 851-5

EC/CAS

100-41-4

Name of the chemical

Ethylbenzene

Concentration

>=0-<=3 849-4

Listed in

EC/CAS

78-79-5

Name of the chemical

Isopren; Methyl-1,3-butadien

Concentration

>=5-<=10

EC/CAS

1330-20-7

Name of the chemical

Xylene

Concentration

>=0-<=7 535-7

Listed in

EC/CAS

109-66-0

Name of the chemical

pentane

Concentration

>=5-<=10 692-4

EC/CAS

78-78-4

Name of the chemical

isopentane

Concentration

>=2-<=7

General Information

Version

5.1

Revision date

2025-07-11

Product name

Pygas (benzene <10%)

1.2.1 Relevant identified uses

Intermediate Refinery Stream Please refer to section 16 and/or the annexes for the regis- tered uses under REACH

Emergency telephone

+44 (0) 20 7934 7778, +31(0)88 755

Icons in SDS

GHS02 GHS07 GHS08 GHS09

Company Information

company name

Shell Trading Rotterdam B.V

e-mail address of the competent person responsible for the Safety Data Sheet

TRsds@shell.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H224, H302, H304, H315, H319, H335, H340, H350, H361, H372, H411

Hazard statements

Code

Statements

H224

Extremely flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

Danger

Physical hazards

H224 Extremely flammable liquid and vapour

Health hazards

H302 Harmful if swallowed H304 May be fatal if swallowed and enters airways H315 Causes skin irritation H319 Causes serious eye irritation H340 May cause genetic defects H350 May cause cancer H361 Suspected of damaging fertility or the unborn child H335 May cause respiratory irritation H372 Causes damage to organs (Blood forming organs, Central nervous system) through prolonged or repeated expo- sure

Environmental hazards

H411 Toxic to aquatic life with long lasting effects

Supplemental label elements

EUH066 Repeated exposure may cause skin dryness or cracking.

Prevention

P201 Obtain special instructions before use. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 Wear protective gloves/ protective clothing/ eye protec- tion/ face protection.

Response

P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other hazards

The substance does not fulfill all screening criteria for persistence, bioaccumulation and toxicity and hence is not considered to be PBT or vPvB

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regu- lation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. This material is a static accumulator. Even with proper grounding and bonding, this material can still accumulate an electrostatic charge. If sufficient charge is allowed to accumulate, electrostatic discharge and ignition of flammable air- vapour mixtures can occur. The vapour is heavier than air, spreads along the ground and distant ignition is possible. Will float and can be reignited on surface water.

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008) Flammable liquids, Category 1 H224: Extremely flammable liquid and vapour. Acute toxicity, Category 4, Oral H302: Harmful if swallowed. Supplemental Hazard Statements EUH066: Repeated exposure may cause skin dry- ness or cracking. Skin irritation, Category 2 H315: Causes skin irritation. Eye irritation, Category 2 H319: Causes serious eye irritation. Aspiration hazard, Category 1 H304: May be fatal if swallowed and enters air- ways. Germ cell mutagenicity, Category 1B H340: May cause genetic defects. Carcinogenicity, Category 1A H350: May cause cancer. Reproductive toxicity, Category 2 H361: Suspected of damaging fertility or the un- born child. Specific target organ toxicity - single ex- H335: May cause respiratory irritation. posure, Category 3 Specific target organ toxicity - repeated H372: Causes damage to organs through pro- exposure, Category 1, Blood-forming longed or repeated exposure. organs , Central nervous system Long-term (chronic) aquatic hazard, Cat- H411: Toxic to aquatic life with long lasting effects. egory 2

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