Piperylene 75%

Hazard statements (CLP)

H225, H302, H304, H312, H315, H319, H335, H336, H341, H350, H401, H411

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

GHS Classification Emergency Overview Appearance Liquid. Colour Colourless to light coloured Odour strong

Health hazards

Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. May be fatal if swallowed and enters airways. May cause heritable genetic damage May cause cancer. May cause respiratory irritation. May cause drowsiness and dizziness. Safety Hazards Highly flammable liquid and vapour. H302 Harmful if swallowed. H312 Harmful in contact with skin. H315 Causes skin irritation. H319 Causes serious eye irritation. H304 May be fatal if swallowed and enters airways. H341 Suspected of causing genetic defects. H350 May cause cancer. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. Inhalation: May cause respiratory tract irritation. May cause drowsiness and dizziness. Skin: Harmful in contact with skin. Causes skin irritation. Eyes: Causes serious eye irritation. Ingestion: Harmful if swallowed. May be fatal if swallowed and enters airways.

Environmental hazards

Toxic to aquatic life with long lasting effects. GHS Classification Flammable liquids Category 2 Acute toxicity (Oral) Category 4 Acute toxicity (Dermal) Category 4 Skin irritation Category 2 Eye irritation Category 2 H401 Toxic to aquatic life. H411 Toxic to aquatic life with long lasting effects. Toxic to aquatic life with long lasting effects.

Aspiration hazard

Category 1 Germ cell mutagenicity Category 2 Carcinogenicity Category 1B Specific target organ toxicity - Category 3 single exposure Short-term (acute) aquatic Category 2 hazard Long-term (chronic) aquatic Category 2 hazard

Signal word

Danger

Physical hazards

H225 Highly flammable liquid and vapour.

Prevention

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash hands thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response

P301 + P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. P302 + P352 IF ON SKIN: Wash with plenty of water and soap. P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P312 Call a POISON CENTER or doctor/ physician if you feel unwell. P330 Rinse mouth. P332 + P313 If skin irritation occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ attention. P362 + P364 Take off contaminated clothing and wash it before reuse. P370 + P378 In case of fire: Use appropriate media to extinguish. P391 Collect spillage.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P235 Keep cool. P405 Store locked up.

Disposal

P501 Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations.

Other hazards which do not result in classification

Highly flammable.This material is a static accumulator.Even with proper grounding and bonding, this material can still accumulate an electrostatic charge.If sufficient charge is allowed to accumulate, electrostatic discharge and ignition of flammable air-vapour mixtures can occur.Highly reactive.May form explosive peroxides.Will float and can be reignited on surface water.Vapours are heavier than air. Vapours may travel across the ground and reach remote ignition sources causing a flashback fire danger.May form flammable/explosive vapour-air mixture.

Other physicochemical hazards

Highly flammable liquid and vapour.

2.1 Classification of the substance or mixture

Flammable liquids : Category 2 Acute toxicity (Oral) : Category 4 Acute toxicity (Dermal) : Category 4 Skin irritation : Category 2 Eye irritation : Category 2 Aspiration hazard : Category 1 Germ cell mutagenicity : Category 2 Carcinogenicity : Category 1B Specific target organ toxicity - : Category 3 single exposure Short-term (acute) aquatic : Category 2 hazard Long-term (chronic) aquatic : Category 2 hazard