Note: Ingredients listed on restricted chemical lists
EC/CAS
200-679-5/68-12-2
Name of the chemical
Dimethyl formamide; N,N-dimethylformamide (DMFa)
Concentration
>=99,5-<=100
EC/CAS
67-56-1
Name of the chemical
Methanol
Concentration
>=0-<=0
General Information
Version
1.1
Revision date
2023-04-05
Product name
Spent N,N-dimethylformamide
1.2.1 Relevant identified uses
Please refer to section 16 and/or the annexes for the regis tered uses under REACH
Emergency telephone
+44 (0) 1235 239 670, +31(0)88 755 8000
Icons in SDS
Company Information
company name
Shell Chemicals Europe B.V
e-mail address of the competent person responsible for the Safety Data Sheet
sccmsds@shell.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H226, H312, H319, H332, H360
Hazard statements
Code
Statements
H226
Flammable liquid and vapour
Section 2
SECTION 2: Hazards identification
Regulation (EC) No. 1272/2008 Classification of the substance or mixture
Signal word
Danger
Physical hazards
H226 Flammable liquid and vapour
Health hazards
H312 Harmful in contact with skin H319 Causes serious eye irritation H332 Harmful if inhaled H360 May damage fertility or the unborn child
Environmental hazards
Not classified as environmental hazard according to CLP criteria
Prevention
P201 Obtain special instructions before use. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P280 Wear protective gloves/ protective clothing/ eye protec- tion/ face protection.
Response
P303 + P361 + P353 IF ON SKIN (or hair): Take off immedi- ately all contaminated clothing. Rinse skin with water or show- er. P305 + P351 + P338 IF IN EYES: Rinse cautiously with wa- ter for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention. P308 + P311 IF exposed or concerned: Call a POISON CENTER/ doctor.
Storage
P403 + P235 Store in a well-ventilated place. Keep cool.
Disposal
P501 Dispose of contents/ container to an approved waste disposal plant.
ECOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regu- lation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
TOXICOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. In use, may form flammable/explosive vapour-air mixture. Even with proper grounding and bonding, this material can still accumulate an electrostatic charge. If sufficient charge is allowed to accumulate, electrostatic discharge and ignition of flammable air- vapour mixtures can occur. Vapours are heavier than air. Vapours may travel across the ground and reach remote ignition sources causing a flashback fire danger. Repeated exposure may cause skin dryness or cracking. Slightly irritating to respiratory system.
2.1 Classification of the substance or mixture
Classification (REGULATION (EC) No 1272/2008) Flammable liquids, Category 3 H226: Flammable liquid and vapour. Acute toxicity, Category 4, Dermal H312: Harmful in contact with skin. Eye irritation, Category 2 H319: Causes serious eye irritation. Acute toxicity, Category 4, Inhalation H332: Harmful if inhaled. Reproductive toxicity, Category 1B H360: May damage fertility or the unborn child.
