Note: Ingredients listed on restricted chemical lists
EC/CAS
270-726-2/68477-35-0
Name of the chemical
Distillates (petroleum), C3-6, piperylene-rich
Concentration
<=100
EC/CAS
201-052-9/77-73-6
Name of the chemical
3a,4,7,7a-tetrahydro-4,7-methanoindene
Concentration
0,1-<1
EC/CAS
201-143-3/78-79-5
Name of the chemical
Isopren; Methyl-1,3-butadien
Concentration
0,1-<1 1-5
EC/CAS
200-753-7/71-43-2
Name of the chemical
Benzol
Concentration
0-<=0
General Information
Revision date
2021-11-02
Product name
Piperylene 75%
CAS No.
68477-35-0
REACH No
01-2119480194-38-0000
1.2.1 Relevant identified uses
Base chemical., Raw material for use in the chemical industry Please refer to section 16 and/or the annexes for the regis- tered uses under REACH
Emergency telephone
+44 (0) 1235 239 670
Icons in SDS
Company Information
company name
Shell Chemicals Europe B.V
e-mail address of the competent person responsible for the Safety Data Sheet
sccmsds@shell.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H225, H302, H304, H312, H315, H319, H335, H336, H341, H350, H411
Hazard statements
Code
Statements
H225
Highly Flammable liquid and vapour
Section 2
CLP CLASSIFICATION
Flammable liquids, Category 2 H225: Highly flammable liquid and vapour. Acute toxicity, Category 4, Oral H302: Harmful if swallowed. Acute toxicity, Category 4, Dermal H312: Harmful in contact with skin. Skin irritation, Category 2 H315: Causes skin irritation. Eye irritation, Category 2 H319: Causes serious eye irritation. Aspiration hazard, Category 1 H304: May be fatal if swallowed and enters air- ways. Germ cell mutagenicity, Category 2 H341: Suspected of causing genetic defects. Carcinogenicity, Category 1B H350: May cause cancer. Specific target organ toxicity - single ex- H335: May cause respiratory irritation. posure, Category 3 H336: May cause drowsiness or dizziness. Long-term (chronic) aquatic hazard, Cat- H411: Toxic to aquatic life with long lasting effects. egory 2
2.2 Label elements
REGULATION (EC) No 1272/2008)
Signal word
Danger
Physical hazards
H225 Highly flammable liquid and vapour.
Health hazards
H302 Harmful if swallowed. H312 Harmful in contact with skin. H315 Causes skin irritation. H319 Causes serious eye irritation. H304 May be fatal if swallowed and enters airways. H341 Suspected of causing genetic defects. H350 May cause cancer. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness.
Environmental hazards
H411 Toxic to aquatic life with long lasting effects.
Prevention
P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P243 Take action to prevent static discharges. P273 Avoid release to the environment.
Response
P303 + P361 + P353 IF ON SKIN (or hair): Take off immedi- ately all contaminated clothing. Rinse skin with water or show- er. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor.
Storage
No precautionary phrases.
Disposal
No precautionary phrases.
2.3 Other hazards
The substance does not fulfill all screening criteria for persistence, bioaccumulation and toxicity and hence is not considered to be PBT or vPvB. Highly flammable. This material is a static accumulator. Even with proper grounding and bonding, this material can still accumulate an electrostatic charge. If sufficient charge is allowed to accumulate, electrostatic discharge and ignition of flammable air- vapour mixtures can occur. Highly reactive. May form explosive peroxides. Will float and can be reignited on surface water. Vapours are heavier than air. Vapours may travel across the ground and reach remote ignition sources causing a flashback fire danger. May form flammable/explosive vapour-air mixture.
