Note: Ingredients listed on restricted chemical lists
EC/CAS
247-722-4/26471-62-5
Name of the chemical
m-Tolylidendiisocyanat
Concentration
<= 100
EC/CAS
584-84-9
Name of the chemical
2,4-Diisocyanattoluol
Concentration
>=80
EC/CAS
91-08-7
Name of the chemical
2,6-Diisocyanattoluol
Concentration
<=20
General Information
Revision date
2021-11-05
Product name
CARADATE 80 (TDI)
Product Synonyms
Methyl phenylene diisocyanate, TDI 80:20, Toluene 2,4- and 2,6-diisocyanate mixture
CAS No.
26471-62-5
1.2.1 Relevant identified uses
Use for the manufacture of polyurethane products
Emergency telephone
+44 (0) 1235 239 670 (This telephone number is available 24
Icons in SDS
Company Information
company name
Shell Chemicals Europe B.V
e-mail address of the competent person responsible for the Safety Data Sheet
sccmsds@shell.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H330, H334, H335, H351, H412
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
2.1 Classification of the substance or mixture
T.R. SEA No 28848 Skin irritation, Category 2 H315: Causes skin irritation. Skin sensitisation, Category 1 H317: May cause an allergic skin reaction. Eye irritation, Category 2 H319: Causes serious eye irritation. Acute toxicity, Category 1 H330: Fatal if inhaled. Respiratory sensitisation, Category 1 H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. Specific target organ toxicity - single ex- H335: May cause respiratory irritation. posure, Category 3, Respiratory system Carcinogenicity, Category 2 H351: Suspected of causing cancer. Long-term (chronic) aquatic hazard, Cat- H412: Harmful to aquatic life with long lasting ef- egory 3 fects.
2.2 Label elements
T.R. SEA No 28848
Signal word
Danger
Physical hazards
Not classified as a physical hazard under GHS criteria.
Health hazards
H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H330 Fatal if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer.
Environmental hazards
H412 Harmful to aquatic life with long lasting ef- fects.
Prevention
P260 Do not breathe dust/ fume/ gas/ mist/ va- pours/ spray. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P273 Avoid release to the environment.
Response
P302 + P352 IF ON SKIN: Wash with plenty of water and soap. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Im- mediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with wa- ter for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical ad- vice/ attention.
Storage
No precautionary phrases.
Disposal
P501 Dispose of contents/ container to an ap- proved waste disposal plant.
2.3 Other hazards
This material reacts with water to produce a violent chemical reaction. This material is a static accumulator. Even with proper grounding and bonding, this material can still accumulate an electrostatic charge. If sufficient charge is allowed to accumulate, electrostatic discharge and ignition of flammable air- vapour mixtures can occur.
