Note: Ingredients listed on restricted chemical lists
EC/CAS
247-722-4/26471-62-5
Name of the chemical
m-Tolylidendiisocyanat
Concentration
<=100
EC/CAS
209-544-5/584-84-9
Name of the chemical
2,4-Diisocyanattoluol
Concentration
>=80
EC/CAS
202-039-0/91-08-7
Name of the chemical
2,6-Diisocyanattoluol
Concentration
<=20
General Information
Version
3.2
Revision date
2023-11-08
Product name
CARADATE 80 (TDI)
Product Synonyms
Methyl phenylene diisocyanate, TDI 80:20, Toluene 2,4- and 2,6-diisocyanate mixture
CAS No.
26471-62-5
REACH No
01-2119454791-34
1.2.1 Relevant identified uses
Use for the manufacture of polyurethane products Please refer to section 16 and/or the annexes for the regis- tered uses under REACH
Emergency telephone
+30 210 409 1601
Icons in SDS
Company Information
company name
Shell Chemicals Europe B.V
e-mail address of the competent person responsible for the Safety Data Sheet
sccmsds@shell.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H330, H334, H335, H351, H412
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
SECTION 2: Hazards identification
Regulation (EC) No. 1272/2008 Classification of the substance or mixture
Signal word
Danger
Physical hazards
Not classified as a physical hazard according to CLP criteria
Health hazards
H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H330 Fatal if inhaled H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled H335 May cause respiratory irritation H351 Suspected of causing cancer
Environmental hazards
H412 Harmful to aquatic life with long lasting effects
Prevention
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. P280 Wear protective gloves/ protective clothing/ eye protec- tion/ face protection. P273 Avoid release to the environment.
Response
P302 + P352 IF ON SKIN: Wash with plenty of water and soap. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with wa- ter for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention.
Storage
No precautionary phrases.
Disposal
P501 Dispose of contents/ container to an approved waste disposal plant.
ECOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regu- lation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
TOXICOLOGICAL INFORMATION
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. This material reacts with water to produce a violent chemical reaction. This material is a static accumulator. Even with proper grounding and bonding, this material can still accumulate an electrostatic charge. If sufficient charge is allowed to accumulate, electrostatic discharge and ignition of flammable air- vapour mixtures can occur.
2.1 Classification of the substance or mixture
Classification (REGULATION (EC) No 1272/2008) Skin irritation, Category 2 H315: Causes skin irritation. Skin sensitisation, Category 1 H317: May cause an allergic skin reaction. Eye irritation, Category 2 H319: Causes serious eye irritation. Acute toxicity, Category 1, Inhalation H330: Fatal if inhaled. Respiratory sensitisation, Category 1 H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. Specific target organ toxicity - single ex- H335: May cause respiratory irritation. posure, Category 3, Respiratory system Carcinogenicity, Category 2 H351: Suspected of causing cancer. Long-term (chronic) aquatic hazard, Cat- H412: Harmful to aquatic life with long lasting ef- egory 3 fects.
