Refinery Heavy Reformate

Hazard statements (CLP)

H226, H302, H304, H312, H315, H319, H332, H335, H336, H373, H411

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Flammable liquids : Category 3 Acute toxicity (Oral) : Category 4 Aspiration hazard : Category 1 Acute toxicity (Dermal) : Category 4 Skin irritation : Category 2 Eye irritation : Category 2A Acute toxicity (Inhalation) : Category 4 Specific target organ toxicity : Category 3 (Respiratory system) - single exposure Specific target organ toxicity : Category 3 (Narcotic effects) - single exposure Specific target organ toxicity : Category 2 (Auditory system) - repeated exposure Long-term (chronic) aquatic : Category 2 hazard

Aspiration hazard

Category 1 Acute toxicity (Dermal) Category 4 Skin irritation Category 2 Eye irritation Category 2A Acute toxicity (Inhalation) Category 4 Specific target organ toxicity - single exposure Category 3 (Respiratory system) Specific target organ toxicity - single exposure Category 3 (Narcotic effects) Specific target organ toxicity Category 2 (Auditory system) repeated exposure Long-term (chronic) aquatic Category 2 hazard

Signal word

Danger

Physical hazards

H226 Flammable liquid and vapour

Health hazards

H302 Harmful if swallowed H304 May be fatal if swallowed and enters airways H312 Harmful in contact with skin H315 Causes skin irritation H319 Causes serious eye irritation H332 Harmful if inhaled H335 May cause respiratory irritation H336 May cause drowsiness or dizziness H373 May cause damage to organs through prolonged or re- peated exposure

Environmental hazards

H411 Toxic to aquatic life with long lasting effects

Prevention

P201 Obtain special instructions before use. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof electrical, ventilating and lighting equipment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. P261 Avoid breathing dust, fume, gas, mist, vapours or spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response

P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doc- tor if you feel unwell. P302 + P352 IF ON SKIN: Wash with plenty of water and soap. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 Call a POISON CENTER/ doctor/ .? if you feel unwell. P314 Get medical advice/ attention if you feel unwell. P321 Specific treatment (see supplemental first aid instructions on this label). P330 Rinse mouth. P331 Do NOT induce vomiting. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ atten- tion. P362 + P364 Take off contaminated clothing and wash it before reuse. P370 + P378 In case of fire: Use appropriate media to extin- guish. P391 Collect spillage.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up.

Disposal

P501 Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regula- tions. P501 Dispose of contents and container to an approved waste disposal plant.

Other hazards which do not result in classification

Moderately irritating to eyes. Slightly irritating to respiratory system. Liquid evaporates quickly and can ignite leading to a flash fire, or an explosion in a confined space. This material is a static accumulator. Even with proper grounding and bonding, this material can still accumulate an electrostatic charge. If sufficient charge is allowed to accumulate, electrostatic discharge and ignition of flammable air- vapour mixtures can occur. This product is intended for use in closed systems only.