Shell Polymers Monaca Pyrolysis Fuel Oil (PFO)

Hazard statements (CLP)

H225, H301, H304, H311, H315, H319, H331, H335, H336, H340, H350, H361, H372, H400, H410

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

Aspiration hazard

Category 1 Acute toxicity Category 3 Skin irritation Category 2 Eye irritation Category 2A Acute toxicity Category 3 Specific target organ toxicity - single exposure Category 3 Specific target organ toxicity - single exposure Category 3 Germ cell mutagenicity Category 1 Carcinogenicity Category 1B Reproductive toxicity Category 2 Specific target organ toxicity Category 1 repeated exposure Short-term (acute) aquatic Category 1 hazard Long-term (chronic) aquatic Category 1 hazard

Signal word

Danger

Physical hazards

H225 Highly flammable liquid and vapour

Health hazards

H301 Toxic if swallowed H304 May be fatal if swallowed and enters airways H311 Toxic in contact with skin H315 Causes skin irritation H319 Causes serious eye irritation H331 Toxic if inhaled H335 May cause respiratory irritation H336 May cause drowsiness or dizziness H340 May cause genetic defects H350 May cause cancer H361 Suspected of damaging fertility or the unborn child H372 Causes damage to organs through prolonged or repeated exposure

Environmental hazards

H400 Very toxic to aquatic life H410 Very toxic to aquatic life with long lasting effects

Prevention

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, sparks, open flame and hot surfac- es. No smoking. P233 Keep container tightly closed. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting equip- ment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. P261 Avoid breathing dust, fume, gas, mist, vapours or spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response

P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P302 + P352 IF ON SKIN: Wash with plenty of water and soap. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P312 Call a POISON CENTER/ doctor/ .? if you feel unwell. P314 Get medical advice/ attention if you feel unwell. P321 Specific treatment (see .? on this label). P322 Specific measures (see .? on this label). P330 Rinse mouth. P331 Do NOT induce vomiting. P332 + P313 If skin irritation occurs: Get medical advice/ atten- tion. P337 + P313 If eye irritation persists: Get medical advice/ atten- P361 Take off immediately all contaminated clothing. P363 Wash contaminated clothing before reuse. P370 + P378 In case of fire: Use appropriate media to extin- guish. P391 Collect spillage.

Storage

P235 Keep cool. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.

Disposal

P501 Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regula- tions.

Other hazards which do not result in classification

This material is a static accumulator. Even with proper grounding and bonding, this material can still accumulate an electrostatic charge. If sufficient charge is allowed to accumulate, electrostatic discharge and ignition of flammable air- vapour mixtures can occur. Highly reactive. Maintain dissolved oxygen and inhibitor at proper levels to prevent runaway polymerisation.

2.1 Classification of the substance or mixture

1910.1200) Flammable liquids : Category 2 Acute toxicity (Oral) : Category 3 Aspiration hazard : Category 1 Acute toxicity : Category 3 Skin irritation : Category 2 Eye irritation : Category 2A Acute toxicity : Category 3 Specific target organ toxicity : Category 3 - single exposure Specific target organ toxicity : Category 3 - single exposure Germ cell mutagenicity : Category 1 Carcinogenicity : Category 1B Reproductive toxicity : Category 2 Specific target organ toxicity : Category 1 - repeated exposure Short-term (acute) aquatic : Category 1 hazard Long-term (chronic) aquatic : Category 1 hazard