Shell Polymers Monaca De-ethanizer Bottoms

Hazard statements (CLP)

H220, H280, H304, H315, H319, H340, H350, H372

Code

Statements

H220

Extremely flammable gas

SECTION 2: Hazards identification

OSHA HCS 2012 GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR 1910.1200) Flammable gases Category 1 Gases under pressure Liquefied gas

Aspiration hazard

Category 1 Skin irritation Category 2 Eye irritation Category 2A Germ cell mutagenicity Category 1B Carcinogenicity Category 1 Specific target organ toxicity Category 1 - repeated exposure

Signal word

Danger

Physical hazards

H220 Extremely flammable gas. H280 Contains gas under pressure; may explode if heated. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H319 Causes serious eye irritation. H340 May cause genetic defects. H350 May cause cancer. H372 Causes damage to organs through prolonged or repeated exposure.

Prevention

P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P264 Wash skin thoroughly after handling. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. P270 Do not eat, drink or smoke when using this product.

Response

P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely. P381 Eliminate all ignition sources if safe to do so. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. P331 Do NOT induce vomiting. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P332 + P313 If skin irritation occurs: Get medical advice/ atten- tion. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ atten- tion. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P314 Get medical advice/ attention if you feel unwell.

Storage

P410 + P403 Protect from sunlight. Store in a well-ventilated place. P405 Store locked up.

Disposal

P501 Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regula- tions.

Other hazards which do not result in classification

Vapours may cause drowsiness and dizziness. Slightly irritating to respiratory system. Exposure to rapidly expanding gases may cause frost burns to eyes and/or skin. Vapours may be irritating to the eye. Possibility of organ or organ system damage from prolonged exposure; see Section 11 for details. Target organ(s): Blood forming organs Reproductive system. This material is a static accumulator. Even with proper grounding and bonding, this material can still accumulate an electrostatic charge. If sufficient charge is allowed to accumulate, electrostatic discharge and ignition of flammable air- vapour mixtures can occur. Highly reactive. May form explosive peroxides. The vapour is heavier than air, spreads along the ground and distant ignition is possible. May form flammable/explosive vapour-air mixture. The classification of this material is based on OSHA HCS 2012 criteria.