Piperylene 75%

Shell Chemical LP

Revision date : 2020-04-06

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GHS02 GHS07 GHS08 GHS09
Health risk rating 5
Safety risk rating 3
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

68477-35-0

Name of the chemical

Distillates (petroleum), C3-6, piperylene-rich

Concentration

N/A

EC/CAS

77-73-6

Name of the chemical

3a,4,7,7a-tetrahydro-4,7-methanoindene

Concentration

N/A

Listed in

EC/CAS

78-79-5

Name of the chemical

Isopren; Methyl-1,3-butadien

Concentration

N/A

General Information

Revision date

2020-04-06

Product name

Piperylene 75%

CAS No.

68477-35-0

Icons in SDS

Company Information

company name

Shell Chemical LP

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H302, H304, H312, H315, H319, H335, H336, H341, H350, H411

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

OSHA HCS Classification

Flammable liquids Category 2 Acute toxicity (Oral) Category 4 Acute toxicity (Dermal) Category 4 Skin irritation Category 2 Eye irritation Category 2

Aspiration hazard

Category 1 Germ cell mutagenicity Category 2 Carcinogenicity Category 1B Specific target organ toxicity Category 3 (Respiratory system., Narcotic effects.) - single exposure Long-term (chronic) aquatic Category 2

Signal word

Danger

Physical hazards

H225 Highly flammable liquid and vapour.

Health hazards

H302 Harmful if swallowed. H312 Harmful in contact with skin. H315 Causes skin irritation. H319 Causes serious eye irritation. H304 May be fatal if swallowed and enters airways. H341 Suspected of causing genetic defects. H350 May cause cancer. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness.

Environmental hazards

H411 Toxic to aquatic life with long lasting effects.

Prevention

P210 Keep away from open flames/ hot surfaces. - No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting equip- ment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P264 Wash hands thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment.

Response

P370+P378 In case of fire: Use appropriate media for extinction. P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. P312 Call a POISON CENTER/ doctor if you feel unwell. P332 + P313 If skin irritation occurs: Get medical advice/ atten- tion. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P330 Rinse mouth. P331 Do NOT induce vomiting. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ atten- tion. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P391 Collect spillage.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P235 Keep cool. P405 Store locked up.

Disposal

P501 Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regula- tions.

Other hazards which do not result in classification

Highly flammable. This material is a static accumulator. Even with proper grounding and bonding, this material can still accumulate an electrostatic charge. If sufficient charge is allowed to accumulate, electrostatic discharge and ignition of flammable air- vapour mixtures can occur. Highly reactive. May form explosive peroxides. Will float and can be reignited on surface water. Vapours are heavier than air. Vapours may travel across the ground and reach remote ignition sources causing a flashback fire danger. May form flammable/explosive vapour-air mixture. The classification of this material is based on OSHA HCS 2012 criteria.

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