Piperylene 75%

Hazard statements (CLP)

H225, H302, H304, H312, H315, H319, H335, H336, H341, H350, H411

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

Aspiration hazard

Category 1 Germ cell mutagenicity Category 2 Carcinogenicity Category 1B Specific target organ toxicity - single exposure Category 3 (Respiratory system, Narcotic effects) Long-term (chronic) aquatic Category 2 hazard

Signal word

Danger

Physical hazards

H225 Highly flammable liquid and vapour

Health hazards

H302 Harmful if swallowed H304 May be fatal if swallowed and enters airways H312 Harmful in contact with skin H315 Causes skin irritation H319 Causes serious eye irritation H335 May cause respiratory irritation H336 May cause drowsiness or dizziness H341 Suspected of causing genetic defects H350 May cause cancer

Environmental hazards

H411 Toxic to aquatic life with long lasting effects

Prevention

P201 Obtain special instructions before use. P233 Keep container tightly closed. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting equip- ment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash hands thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.

Response

P301 + P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. P302 + P352 IF ON SKIN: Wash with plenty of water. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P321 Specific treatment (see supplemental first aid instructions on this label). P330 Rinse mouth. P331 Do NOT induce vomiting. P332 + P313 If skin irritation occurs: Get medical attention. P337 + P313 If eye irritation persists: Get medical advice/ atten- tion. P362 + P364 Take off contaminated clothing and wash it before reuse. P370 + P378 In case of fire: Use appropriate media to extin- guish. P391 Collect spillage.

Storage

P235 Keep cool. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.

Disposal

P501 Dispose of contents and container to an approved waste disposal plant.

Other hazards which do not result in classification

Highly flammable. This material is a static accumulator. Even with proper grounding and bonding, this material can still accumulate an electrostatic charge. If sufficient charge is allowed to accumulate, electrostatic discharge and ignition of flammable air- vapour mixtures can occur. Highly reactive. May form explosive peroxides. Will float and can be reignited on surface water. Vapours are heavier than air. Vapours may travel across the ground and reach remote ignition sources causing a flashback fire danger. May form flammable/explosive vapour-air mixture.

2.1 Classification of the substance or mixture

1910.1200) Flammable liquids : Category 2 Acute toxicity (Oral) : Category 4 Acute toxicity (Dermal) : Category 4 Skin irritation : Category 2 Eye irritation : Category 2 Aspiration hazard : Category 1 Germ cell mutagenicity : Category 2 Carcinogenicity : Category 1B Specific target organ toxicity : Category 3 (Respiratory system, Narcotic effects) - single exposure Long-term (chronic) aquatic : Category 2 hazard