iPA-USP

Hazard statements (CLP)

H225

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

GHS Classification GHS Classification Flammable liquids Category 2 Eye irritation Category 2A Specific target organ foxicity Category 3 (Narcotic effects) single exposure {Inhalation, Oral)

Signal word

B Daner

Hazard statements

©

Physical hazards

H225 Highly flammable figuid and vapour.

Health hazards

H319 Causes serious eye irritation. 336 May cause drowsiness or dizziness

Environmental hazards

iy B £00001011069 Synonyms © Dimethy! carbincl-USP, IPA-USP, Isopropanol-USP, Propa- nol-USP, sec-, Propyl alcohol-USP, sec- Hazardous components Chemical Name Synonyms CAS-No. Concentration (%) Isopropyi atcohot propan-2-of 67-63-0 100 <= SECTION 4. FIRST-AID MEASURES General advice ¢ In general no reatment is necessary, however, obtain medical advice. finhaled © Remove to fresh air. If rapid recovery does not ocour, transport to nearest medical facility for additional treatment. In case of skin contact Remove contaminated clothing. Flush exposed area with wa- ter and fotlow by washing with soap if available. If persistent irritation cccurs, obtain medical attention. in case of eye contact Immediately flush eyes with large amounts of water for at least 15 minutes while holding eyelids open. Transport to the near- est medical facility for additional treatment. if swallowed If swallowed, do not induce vomiting: transport to nearest medical facility for additional treatment. If vomiting occurs spontaneously, keep head below hips to prevent aspiration. If any of the following delayed signs and symptems appear within the next 6 hours, transport to the nearest medical faciii- ty: fever greater than 101° F (38.3°C), shortness of breath, chest cengestion or continued coughing or wheezing. Maost important symptoms. . If material enters tungs, signs and symptoms may include and effects, both acute and coughing, choking, wheezing, difficulty in breathing, chest delayed congestior, shoriness of breath, andfor fever. Eye irritation signs and symptoms may include a burning sen- sation, redness, swelling, and/or blurred vision Protection of first-aiders © When administering first aid, ensure that you are wearing the appropriate personal protective equipment according to the incident, injury and surroundings. Immediate medical attention, Potential for chemicai pneumonitis. special treatment Call a doctor or poison controf center for guidance. SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Alcchol-resistant foam, water spray or fog. Dry chemical pow- der, carbon dioxide, sand or earth may be used for small fires only. Unsultable extinguishing None media BT 800601011069 appropriate absorbent material and dispose of safely Remove contaminated soil and dispose of safely. Additional advice . For guidance on selection of personal protective equipment see Chapter § of this Safety Data Sheet, For guidance on disposal of spilled material see Chapter 13 of this Safety Data Sheet. U.S. regulations may require reporting refeases of this materi- al to the environment which exceed the reportable quantity {refer to Chapter 15) to the Nationai Response Center at {800} 424-8802. SECTION 7. HANDLING AND STORAGE Technical measures Avoid breathing of or direct contact with material. Cnly use in well ventilated areas. Wash thoroughly after handling. For guidance on selection of personal protective equipment see Chapter 8 of this Safety Data Sheet. Use the information in this data sheet as input to a risk as- sessment of local circumstances to help determite appropri- ate controls for safe handling, storage and disposal of this material Ensure that all local regulations regarding handling and stor- age facilities are followed. Precautions for safe handiing Avoid contact with gkin, eyes and clothing. Use local exhaust ventilation if there is risk of inhatation of vapours, mists or aeresols. Avoidance of contact © Strong oxidising agents. Advice on protection against Bulk storage tanks should be diked (bunded). Extinguish any fire and explosion naked flames. Do not smoke. Remove ignition sources. Avoid sparks. Electrostatic discharge may cause fire. Ensure electri- cal centinuity by bonding and grounding {earthing) all equip- ment to reduce the risk. The vapours in the head space of the storage vessel may lie in the flammable/explesive range and hence may be flammable. Properly dispose of any contami- nated rags or cleaning materials in order to prevant fires. Do NOT use compressed air for filling, discharging, or handiing operations. Product Transfer Refer to guidance under Handling section. Storage Conditions for safe storage, The vapour is heavier than air. Beware of accumulation in pits including any incompatibili- and confined spaces. tes Refer to section 15 for any additional specific legisiation cov- ering the packaging and storage of this product, 5717 §600615171066~ http:fivaww . hse.gov. uk/ Institut fir Arbeitsschutz Deutschen Gesetziichen Unfaifversicherung (IFA) , Germany http:/www.dguv.definhalt/index.jsp L'institut National de Recherche et de Securité. (INRS), France httpi/iwww.inrs friaccueil Engineering measures The level of protection and types of controls necessary will vary depending upon potential exposure condifions. Select controls based on a risk assessment of local circumstances, Appropriate measures include: Use sealed systems as far as possible. Adequate explosion-proof ventilation to control airborne con- centrations below the exposure guidelines/limits. Local exhaust ventilation is recommended. Firewater monitors and deluge systems are recommended. Eye washes and showers for emergency use. Where materia! is heated, sprayed or mist formed, there is. greater potential for airborne concentrations to be generated. General Information: Always observe good personal hygiene measures, such as washing hands after handling the material and before eating, drinking, and/or smoking. Routinely wash work c'othing and protective equipment to remove contaminants. Discard con- taminated clothing and foctwear that cannot be cleaned. Practice good housekeeping, Define procedures for safe handling and maintenance of controls. Educate and train workers in the hazards and control measures relevant to normal activities associated with this product. Ensure appropriate selection, testing and maintenance of equipment used to control exposure, e.y. personal protective equipment, local exhaust ventiiation. Drain down system prior to equipment break-in or mainte- nance. Retain drain downs in sealed storage pending disposal or subsequent recycle. Personal protective equipment Respiratory protection If engineering controls do not maintain airborne concentra- tions to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the spe- cific conditions of use and meeting relevant legistation. Check with respiratory protective equipment suppliers. Where air-fiitering respirators are unsuitable {e.g. aircorne concentrations are high, risk of oxygen deficiency, confined space} use appropriate positive pressure breathing appa- ratus, Where air-filtering respirators are suitable, select an appro- priate combination of mask and filter. If air-filtering respirators are suitable for conditions of use: Select a filter suitable for organic gases and vapours [boifing point »65 °C (149 °F)}. Respirator selection, use and maintenance should be in ac- 800001011069 ronmental legistation. Information on accidental release measures are to be found in SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Liquid. Colour clear Odour 1 characteristic Odour Threshoid Data not available pH

2.1 Classification of the substance or mixture

Flammable liquids © Category 2 Eye irritation . Category 2A Specific target organ foxicity : Category 3 (Narcotic effects) - single exposure {Inhalation, Oral)