Heavy Olefin Feed

Hazard statements (CLP)

H227, H304, H332, H350, H361, H373, H400, H410

Code

Statements

H227

Combustible liquid

SECTION 2: Hazards identification

OSHA HCS 2012 GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR 1910.1200) Flammable liquids Category 4 Acute toxicity (Inhalation) Category 4

Aspiration hazard

Category 1 Reproductive toxicity Category 2 Carcinogenicity Category 1B Specific target organ toxicity Category 2 (Blood, Liver, thymus) - repeated exposure Short-term (acute) aquatic Category 1 Long-term (chronic) aquatic Category 1

Signal word

Danger

Physical hazards

H227 Combustible liquid.

Health hazards

H332 Harmful if inhaled. H304 May be fatal if swallowed and enters airways. H361 Suspected of damaging fertility or the unborn child. H350 May cause cancer. H373 May cause damage to organs (Blood, Liver, thymus) through prolonged or repeated exposure.

Environmental hazards

H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects.

Prevention

P201 Obtain special instructions before use. P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from open flames/ hot surfaces. - No smoking. P271 Use only outdoors or in a well-ventilated area. P281 Use personal protective equipment as required.

Response

P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. P331 Do NOT induce vomiting. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P314 Get medical advice/ attention if you feel unwell. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P370 + P378 In case of fire: Use alcohol-resistant foam, carbon dioxide or water mist for extinction. P391 Collect spillage.

Storage

P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up.

Disposal

P501 Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regula- tions.

Other hazards which do not result in classification

Hydrogen sulphide is highly toxic and may be fatal if inhaled. Hydrogen sulphide (H2S), an extremely flammable and toxic gas, and other hazardous vapours may evolve and collect in the headspace of storage tanks, transport vessels and other enclosed containers. May dull the sense of smell, so do not rely on odour as an indication of hazard. May ignite on surfaces at temperatures above auto-ignition temperature. This material is a static accumulator. Even with proper grounding and bonding, this material can still accumulate an electrostatic charge. If sufficient charge is allowed to accumulate, electrostatic discharge and ignition of flammable air- vapour mixtures can occur. Not classified as flammable but will burn. Flammable vapours may be present even at temperatures below the flash point. Therefore it should be treated as a potentially flammable liquid. Contact with hot material can cause thermal burns which may result in permanent skin damage. Repeated exposure may cause skin dryness or cracking. The classification of this material is based on OSHA HCS 2012 criteria. Hydrogen sulphide (H2S), an extremely flammable and toxic gas, and other hazardous vapours may evolve and collect in the headspace of storage tanks, transport vessels and other enclosed containers.