Dicyclopentadiene (DCPD) - 75%

Shell Chemical LP

Revision date : 2018-06-22

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GHS02 GHS06 GHS07 GHS08 GHS09
Health risk rating 5
Safety risk rating 3
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

201-052-9/77-73-6

Name of the chemical

3a,4,7,7a-tetrahydro-4,7-methanoindene

Concentration

>= 60 - <= 70

Listed in

General Information

Version

2.0

Revision date

2018-06-22

Product name

Dicyclopentadiene (DCPD) - 75%

CAS No.

68477-54-3

1.2.1 Relevant identified uses

Base chemical., Use only as a chemical intermediate

Emergency telephone

+52 (55) 5559 1588, +1 (703) 527- 3887

Icons in SDS

GHS02 GHS06 GHS07 GHS08 GHS09

Company Information

company name

Shell Chemical LP

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H302, H304, H315, H319, H330, H336, H340, H350, H361d, H373, H400, H411

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

GHS Classification GHS Classification Flammable liquids Category 2 Acute toxicity Category 4 Acute toxicity Category 2 Skin corrosion/irritation Category 2 Serious eye damage/eye Category 2A irritation Germ cell mutagenicity Category 1B Carcinogenicity Category 1A Reproductive toxicity Category 2 STOT SE: Specific target Category 3 (Respiratory system., Narcotic effects.) organ toxicity - single expo- sure Specific target organ toxicity Category 2 (Blood, Blood-forming organs., Peripheral nervous repeated exposure system., Auditory system, Immune system, Respiratory system., Visual system, Central nervous system (CNS).)

Aspiration hazard

Category 1 Acute aquatic toxicity Category 1 Chronic aquatic toxicity Category 2 GHS label elements Hazard pictograms

Signal word

Danger Hazard statements

Physical hazards

H225 Highly flammable liquid and vapour

Health hazards

H302 Harmful if swallowed H304 May be fatal if swallowed and enters airways H315 Causes skin irritation H319 Causes serious eye irritation H330 Fatal if inhaled H336 May cause drowsiness or dizziness H340 May cause genetic defects H350 May cause cancer H361d Suspected of damaging the unborn child H373 May cause damage to organs through prolonged or re- peated exposure

Environmental hazards

H400 Very toxic to aquatic life H411 Toxic to aquatic life with long lasting effects

Prevention

P201 + P202 Obtain special instructions before use. Do not handle until all safety precautions have been read and under- stood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting equip- ment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash hands thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P281 Use personal protective equipment as required. P284 [In case of inadequate ventilation] wear respiratory protec- tion.

Response

P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P310 Immediately call a POISON CENTER/doctor. P320 Specific treatment is urgent (see supplemental first aid instructions on this label). P330 Rinse mouth. P331 Do NOT induce vomiting. P332 + P313 If skin irritation occurs: Get medical advice/ atten- tion. P337 + P313 If eye irritation persists: Get medical advice/ atten- tion. P362 Take off contaminated clothing. P370 + P378 In case of fire: Use appropriate media to extin- guish. P391 Collect spillage.

Storage

P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up.

Disposal

P501 Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regula- tions.

Other hazards which do not result in classification

May form explosive peroxides. Will float and can be reignited on surface water. Vapours are heavier than air. Vapours may travel across the ground and reach remote ignition sources causing a flashback fire danger. May form flammable/explosive vapour-air mixture. This material is a static accumulator. Even with proper grounding and bonding, this material can still accumulate an electrostatic charge. If sufficient charge is allowed to accumulate, electrostatic discharge and ignition of flammable air- vapour mixtures can occur.

2.1 Classification of the substance or mixture

Flammable liquids : Category 2 Acute toxicity : Category 4 Acute toxicity : Category 2 Skin corrosion/irritation : Category 2 Serious eye damage/eye : Category 2A irritation Germ cell mutagenicity : Category 1B Carcinogenicity : Category 1A Reproductive toxicity : Category 2 STOT SE: Specific target : Category 3 (Respiratory system., Narcotic effects.) organ toxicity - single expo- sure Specific target organ toxicity : Category 2 (Blood, Blood-forming organs., Peripheral nervous - repeated exposure system., Auditory system, Immune system, Respiratory system., Visual system, Central nervous system (CNS).) Aspiration hazard : Category 1 Acute aquatic toxicity : Category 1 Chronic aquatic toxicity

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