Note: Ingredients listed on restricted chemical lists
EC/CAS
68955-28-2
Name of the chemical
Gases (petroleum), light steam-cracked, butadiene conc
Concentration
N/A
EC/CAS
106-99-0
Name of the chemical
1,3-Butadien
Concentration
N/A
General Information
Revision date
2021-08-19
Product name
Crude C4
CAS No.
68955-28-2
Emergency telephone
(24
Icons in SDS
Company Information
company name
Shell Chemical LP
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H220, H280, H340, H350
Hazard statements
Code
Statements
H220
Extremely flammable gas
Section 2
SECTION 2: Hazards identification
OSHA HCS 2012 GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR 1910.1200) Flammable gases Category 1 Gases under pressure Liquefied gas Germ cell mutagenicity Category 1B Carcinogenicity Category 1A
Signal word
Danger
Physical hazards
H220 Extremely flammable gas. H280 Contains gas under pressure; may explode if heated.
Health hazards
H340 May cause genetic defects. H350 May cause cancer.
Environmental hazards
Not classified as an environmental hazard under GHS criteria.
Prevention
P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P243 Take precautionary measures against static discharge. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
Response
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely. P381 Eliminate all ignition sources if safe to do so. P308 + P313 IF exposed or concerned: Get medical advice/ attention.
Storage
P410 + P403 Protect from sunlight. Store in a well-ventilated place. P405 Store locked up.
Disposal
P501 Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regula- tions.
Other hazards which do not result in classification
Vapours may cause drowsiness and dizziness. Slightly irritating to respiratory system. Exposure to rapidly expanding gases may cause frost burns to eyes and/or skin. Vapours may be irritating to the eye. Possibility of organ or organ system damage from prolonged exposure; see Section 11 for details. Target organ(s): Blood forming organs Reproductive system. This material is a static accumulator. Even with proper grounding and bonding, this material can still accumulate an electrostatic charge. If sufficient charge is allowed to accumulate, electrostatic discharge and ignition of flammable air- vapour mixtures can occur. Highly reactive. May form explosive peroxides. The vapour is heavier than air, spreads along the ground and distant ignition is possible. May form flammable/explosive vapour-air mixture. The classification of this material is based on OSHA HCS 2012 criteria.
