Renewable Methyl Ethyl Ketone

Hazard statements (CLP)

H225, H303, H305, H319, H336

Code

Statements

H225

Highly Flammable liquid and vapour

2.1 Classification of the substance or mixture

Flammable liquids : Category 2 Acute toxicity (Oral) : Category 5

Aspiration hazard

Category 2 Eye irritation : Category 2A Specific target organ toxicity - : Category 3 (Central nervous system, Narcotic effects) single exposure

Signal word

Danger

Physical hazards

H225 Highly flammable liquid and vapour.

Health hazards

H303 May be harmful if swallowed. H305 May be harmful if swallowed and enters airways. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness.

Environmental hazards

Not classified as an environmental hazard under GHS criteria.

Prevention

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting equip- ment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash hands thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ protective clothing/ eye protec- tion/ face protection.

Response

P303 + P361 + P353 IF ON SKIN (or hair): Take off immediate- ly all contaminated clothing. Rinse skin with water or shower. P370 + P378 In case of fire: Use appropriate media to extin- guish. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P331 Do NOT induce vomiting. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ at- tention. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P312 Call a POISON CENTER/ doctor if you feel unwell.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P235 Keep cool. P405 Store locked up.

Disposal

P501 Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regula- tions.

Other hazards which do not result in classification

Vapours are heavier than air. Vapours may travel across the ground and reach remote ignition sources causing a flashback fire danger. Even with proper grounding and bonding, this material can still accumulate an electrostatic charge. If sufficient charge is allowed to accumulate, electrostatic discharge and ignition of flammable air- vapour mixtures can occur. Exposure may enhance the toxicity of other materials. See Chapter 11 for details. Repeated exposure may cause skin dryness or cracking.