SASE Flo-Mender 2 “A”

SASE Company Inc

Revision date : 2017-05-26

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GHS07 GHS08
Health risk rating 4
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

N/A

EC/CAS

9016-87-9

Name of the chemical

4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)

Concentration

N/A

EC/CAS

91-20-3

Name of the chemical

Naphthalene,3

Concentration

N/A

General Information

Revision date

2017-05-26

Product name

SASE Flo-Mender 2 “A”

1.2.1 Relevant identified uses

Polyurea component industrial chemicals Suitable for use in industrial sector: Polymers industry; chemical industry

Icons in SDS

Company Information

company name

SASE Company Inc

GHS Information

Signal word

Warning

Hazard Codes

Hazard statements (CLP)

H315, H319, H320, H332, H335, H351, H373

Hazard statements

Code

Statements

H315

Causes skin irritation

Section 2

SECTION 2: Hazards identification

According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200

2.1 Classification of the substance or mixture

Acute Tox. 4 (Inhalation) Acute Toxicity Eye Dam./Irrit. 2A Serious eye damage/eye irritation Skin Corr./Irrit. 2 Skin corrosion/irritation STOT SE 3 Specific target organ toxicity — single exposure STOT RE 2 Specific target organ toxicity — repeated exposure Eye Dam./Irrit. 2B Serious eye damage/eye irritation Carc. 2 Carcinogenicity

Signal word

WARNING

Hazard statements

H332 Harmful if inhaled H373 May cause damage to organs through prolonged or repeated exposure. H319 Causes serious eye irritation H335 May cause respiratory irritation H315 - Causes skin irritation H315 Causes skin irritation H320 Causes eye irritation H351 Suspected of causing cancer.

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapors/spray. P264 Wash exposed skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P284 Wear respiratory protection. P271 Use only outdoors or in a well-ventilated area. P201 Obtain special instructions before use. P261 Avoid breathing dust/fume/gas/mist/vapors/spray. P202 Do not handle until all safety precautions have been read and understood. P272 Contaminated work clothing should not be allowed out of the workplace. P262 Do not get in eyes, on skin, or on clothing. P264 Wash exposed skin thoroughly after handling. (Disposal) P501 Dispose of contents/container to a licensed waste disposal facility

Response

P305+351+338 IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. P312 Call a POISON CENTER/doctor/…if you feel unwell. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P308 + P311 IF exposed or concerned: Call a POISON CENTER/doctor/... P314 Get medical advice/attention if you feel unwell. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P332 + P313 If skin irritation occurs: Get medical advice/attention. P337 + P313 If eye irritation persists: Get medical advice/attention.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.

Principle Routes of Exposure

Eyes; Ingestion; Inhalation; Skin; Target Organs: Respiratory system; Skin; Eyes; Inhalation: At room temperature, MDI vapors are minimal due to low vapor pressure. However, heating, spraying, foaming, or otherwise mechanically dispersing (drumming, venting or pumping) operations may generate vapor or aerosol concentrations sufficient to cause irritation or other adverse effects. Excessive exposure may cause irritation of the eyes, upper respiratory tract and lungs. Severe overexposure may lead to pulmonary edema. May cause respiratory sensitization with asthma-like symptoms in susceptible individuals. MDI concentrations below the exposure guidelines may cause allergic respiratory reactions in individuals already sensitized. Symptoms may include coughing, dryness of throat, headache, nausea, difficult breathing and a feeling of tightness in the chest. Effects may be delayed. Impaired lung function (decreased ventilator capacity) has been associated with overexposure to isocyanates Chronic: As a result of previous repeated overexposures or a single large dose, certain individuals develop isocyanate sensitization (chemical asthma) or tissue injury in the upper respiratory tract. Animal tests indicate skin contact alone may also lead to allergic respiratory reaction. These effects may be permanent. Any person developing asthmatic reaction or other sensitization should be removed from further exposure. Skin Contact: Product is a skin sensitizer. Causes irritation with symptoms of reddening, itching and swelling. Prolonged or repeated exposure can cause skin irritation, reddening, dermatitis, and in some individuals, sensitization. Skin contact may result in allergic skin reactions or respiratory sensitization, but is not expected to result in absorption of amounts sufficient to cause other adverse effects. May stain skin. Cured material is difficult to remove. Eye Contact: As a liquid, vapor, aerosol or dust, may cause irritation, inflammation, and/or damage to sensitive eye tissue. Symptoms include reddening, tearing, stinging and swelling. May cause corneal injury. Prolonged contact may cause conjunctivitis.

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