N° CAS TSCA

Hazard statements (CLP)

H226, H302, H304, H315, H317, H319, H331, H400, H410, H411, H412

Code

Statements

H226

Flammable liquid and vapour

2.1 Classification of the substance or mixture

RegulationCLP) Asp. Tox. 1 (RegulationCLP) Warning mention : Danger Asp. Tox. 1

Aspiration hazard

1 Aquatic Chronic 3 Hazardous to the aquatic environment, long-trem hazard 3 Flam. Liq. 3 Flammable Liquids 3 Skin Irrit. 2 Skin corrosion / irritation 2 Skin. Sens. 1 Sensitisation skin 1 H226 - Flammable liquid and vapour. H304 - May be fatal if swallowed and enters airways. H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H412 - Harmful to aquatic life with long lasting effects. 1 Aquatic Chronic 3 Hazardous to the aquatic environment, long-trem hazard 3 Flam. Liq. 3 Flammable Liquids 3 Skin Irrit. 2 Skin corrosion / irritation 2 Skin. Sens. 1 Sensitisation skin 1 H226 - Flammable liquid and vapour. H304 - May be fatal if swallowed and enters airways. H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H412 - Harmful to aquatic life with long lasting effects. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 - Keep container tightly closed. P240+P241 - Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/…/equipment. P242 - Use non-sparking tools. P243 - Take action to prevent static discharges. P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.

Contains

delta-3-Carene, Limonene, Myrcene, beta-Pinene, alpha-Terpinene, Terpinolene CMR (Reg. 1223/2009/EEC) : See certificate 3. SECTION 3 - COMPOSITION INFORMATION ON INGREDIENTS 3.1. Substances Material C.A.S EINECS

Classifications

Percent % Asp. Tox. 1, Flam. Liq. 3, Skin Irrit. 2, delta-3-Carene (Regist. : /) 13466-78-9 236-719-3 Skin. Sens. 1B - H226, H304, H315, > 50 % H317, H411 Aquatic Acute 1, Aquatic Chronic 3, Limonene (Regist. : N° INDEX 601-029-00-7) 5989-27-5 227-813-5 Flam. Liq. 3, Skin Irrit. 2, Skin. Sens. 1 - [ 1-5 ] H226, H315, H317, H400, H412 Asp. Tox. 1, Eye Irrit. 2, Flam. Liq. 3, Myrcene 123-35-3 204-622-5 [ 1-5 ] Skin Irrit. 2 - H226, H304, H315, H319 Asp. Tox. 1, Aquatic Acute 1, Aquatic Terpinolene (Regist. : /) 586-62-9 209-578-0 Chronic 1, Skin. Sens. 1B - H304, H317, [ 0-1 ] H400, H410 Asp. Tox. 1, Acute Tox. 4, Aquatic alpha-Terpinene (Regist. : /) 99-86-5 202-795-1 Chronic 2, Flam. Liq. 3, Skin. Sens. 1 - [ 0-1 ] H226, H302, H304, H317, H411 Asp. Tox. 1, Aquatic Acute 1, Aquatic Chronic 1, Flam. Liq. 3, Skin Irrit. 2, beta-Pinene (Regist. : /) 127-91-3 204-872-5 [ 0-1 ] Skin. Sens. 1B - H226, H304, H315, H317, H400, H410 Asp. Tox. 1, Acute Tox. 3, Aquatic p-Cymene Natural (Regist. : /) 99-87-6 202-796-7 Chronic 2, Flam. Liq. 3 - H226, H304, [ 0-1 ] H331, H411 Botanical name : Abies sp., Picea sp., Pinus sp. Description : Obtained by physical distillation of Turpentine oil collected from Fir (Abies sp.), Pruces (Picea sp.) And Pine (Pinus sp.).) 3.2. Mixtures NO CONCERNED 4. SECTION 4 - FIRST AID MEASURES 4.1. Description of first aid measures General notes : Please refer to the risk and safety statements (section 2) Following inhalation If inhaled If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Remove collar, belt, tie... Give artificial respiration if not breathing. Following ingestion If swallowed Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Following skin contact : If on skin (or hair) or clothing rinse immediately contaminated clothing and skin with plenty of water before removing clothes. If the symptom persists, consult a doctor. Following eye contact : Rinse cautiously with water for several minutes (15 minutes open eyelids). Remove contact lenses, if present and easy to do. Continue rinsing. In case of disorder, consult an ophtalmologist. Self-protection of the first aider : In lack of appropriate formation, none initiative should imply an individual risk. 4.2. Most important symptoms and effects, both acute and delayed See section 2 4.3. Indication of any immediate medical attention and special treatment needed See section 2 5. SECTION 5 - FIREFIGHTING MEASURES 5.1. Extinguishing media Suitable extinguishing media : Use an extinguishing agent suitable for the surrounding fire. CO2, powder, foam, specific liquid. Unsuitable extinguishing media : Never use a direct stream of water. 5.2. Special hazards arising from the substance or mixture Flammability : The product is not flammable.

Prevention

Keep away from heat/sparks/open flames/hot surfaces. - No smoking Particular risks linked to exposure : see section 2 Hazardous combustion products : Release of poison gases : Monoxide de carbone (CO), Dioxyde de carbon (CO2), Oxyde d'azotes (NOx), Dioxyde de soufre (SO2), Cyanures (CN) .... Auto-ignition temperature (°C) : 260°C (101.3 kPa) 5.3. Advice for firefighters Fire-fighting equipment : use an appropriate personal protective equipment with an approved positive-pressure self- contained breathing apparatus. 6. SECTION 6 - ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Call immediately the emergency personnel. Promote adequate ventilation in the area. For non-emergency personnel Keep them away from the area. Avoid all sources of ignition (spark of flame). Avoid skin/eye contact. Do not inhal vapours. For emergency responders Use personal protective equipment. In case of accidental spills, wear protective gloves during the handling. 6.2. Environmental precautions Avoid the dispersion and flow of the product. Keep away from drains, surface and ground water. Inform the competent authorities if the product enters in ground or surface waters. 6.3. Methods and material for containment and cleaning up For containment The spillage is contained with sand or inert powder. The chemical waste is placed in sealed containers. For cleaning up The soiled elements (rags, absorbent papiers, filters) are immediately soaked into water. The chemical waste are rapidly treated according to the local reglementation

Further information

Only qualified personnel is allowed to clean up. 6.4. Reference to other sections See section 8 for personal protective equipment and section 13 for waste treatment. 7. SECTION 7 - HANDLING AND STORAGE 7.1. Precautions for safe handling Protective measures: See section 2.2 Measures to prevent fire: Do not smoke. Do not expose to excessive heat or ignition sources (spark or flame). Measures to prevent aerosol and dust generation: Maintain adequate ventilation in the area. Measures to protect the environment: Avoid spreading product and keep it from spilling. Precautions or coming in contact with the ground, waterways, drains and vents. Advice on general occupational hygiene: Follow the general hygiene rules. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions: Store in its original packaging in a cool dry place, away from light. Technical measures: Close the container after use. In case of transferring, reproduce the labelling. Packaging materials: Preserve only in the container of origin. Respect the general rules of incompatibility. NO CONCERNED 10. SECTION 10 - STABILITY AND REACTIVITY 10.1. Reactivity Avoid powerful oxidizing agents 10.2. Chemical stability Stable under normal conditions. Shelf life : 12 months, according to storage conditions 10.3. Possibility of hazardous reactions No hazardous reactions when stored and handled according to instructions. 10.4. Conditions to avoid Avoid any potential source of heat. 10.5. Incompatible materials NO CONCERNED 10.6. Hazardous decomposition products Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Dangerous decomposition products: No dangerous decomposition products known. 11. SECTION 11 - TOXICOLOGICAL INFORMATION 11.1. Information on toxicological Toxicity data : No data LD50 oral (rat) : 4800 mg/kg LD50 Dermal (rabbit) : 5000 mg/kg 12. SECTION 12 - ECOLOGICAL INFORMATION 12.1. Toxicity Do not leave the product, even diluted or in great quantity, penetrate the ground water, water or the drains. LC50 Ecotoxicity : No data EC50 Ecology : No data 12.2. Persistence and degradability NO CONCERNED 12.3. Bioaccumulative potential NO CONCERNED 12.4. Mobility in soil PNEC sol

Storage

Store at 25°C max. in tightly sealed original container. Avoid prolonged exposure to light, heat and air. 7.3. Specific end use(s) Wash the hands and any other zone exposed with soap and water before eating, drinking, to smoke and before leaving work. 8. SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION 8.1. Control parameters Measures of technical order : Avoid contact with eyes, skin and closes. Do not ingest. Do not inhal vapors. Use proper personal protective equipment. Monitoring procedures : If the product contains ingredients presenting exposure limits, he can turn out necessary to make an examination followed by the persons, by the atmosphere in the workplace either bodies living to end the efficiency of the ventilation or the other control measures or estimate the need to use of the material of protection of respiratory tracts. It is important to put back you in the European standard EN 689 concerning the methods to estimate the exhibition by inhalation to the chemical agents and to the national general documents of politics relative to the methods to determine dangerous substances. 8.2. Exposure controls Appropriate technical controls : No special ventilation requirements. Good general ventilation should be sufficient to control worker exposure to airborne contaminants. If this product contains ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure. Personal protection measures : Personal protection : Protection des mains Protection non requise.-Protection des yeux Protection non requise -Protection respiratoire : En cas de ventilation insuffisante, porter un appareil respiratoire approprié. Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates that is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Filter apparatus (dust masks or half masks) Type of filters Type AX (Brown) : Organic compounds boiling point < 65°C Type A (Brown) : Organic compounds boiling point > 65°C Type B (Grey) : Inorganic gasses and fumes. Type P (White) : Particles, dusts and aerosols Hand protection : Impermeable and chemical resistant gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary >8 hours before piercing : vinyle disposable.

Remarks

Recommended impermeable goggles do not only depend of his matter. Other factors can have a signifiant effect on impermeability, like their thickness or specific use or temperature conditions. In all cases, matter certificates should be selected. Ask your supply if the goggles are appropriate to this use. Eyes protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Recommanded : Splash googles, safety glasses with side-shields. Skin protection :Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Body Recommanded lab coat (sarrau), general Type 3 : Liquid impermeability Type 4 : Aerosol impermeability Type 6 : Impermeability limited to liquid splashs Foot Recommanded neoprene Upper and sole resistant and impermeable (Hydrocarbure resistant). 9. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Solubility ethanol : Yes Appearance : Liquid Color : Colorless Refractive index n (20/D) : [1.472 ; 1.473] Optical rotation (°) : - Peroxides value mmol/kg : 160 Boiling point (°C) : 170 Flash point (°C) (close cup) : 47 Vapor pressure : - Peak #1 (%) : Delta 3 carene 93% min Peak #2 (%) : Dipentène 3% max Odour : Pine, Resinated, fruity sweet, citrus Melting point (°C) : < -80 Density at 20°C : [0.860 ; 0.870]

Other hazards

No data 13. SECTION 13 - DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Product : Does not have to be evacuated with the refuse. Not let it penetrate in the sewers. Not cleaned packing : Evacuation according to local reglementation. 14. SECTION 14 - TRANSPORT INFORMATION ADR: IMDG: IATA:

UN Number

ADR : 2319 ( Tunnel code (D/E) ) IMDG:2319 IATA :2319 14.2. UN proper shipping name ADR : TERPENE HYDROCARBONS, N.O.S.(Delta-3-Carene) IMDG:TERPENE HYDROCARBONS, N.O.S.(Delta-3-Carene) IATA :TERPENE HYDROCARBONS, N.O.S.(Delta-3-Carene) 14.3. Transport hazard class(es) ADR : 3 IMDG:3 IATA :3 14.4. Packing group ADR : III IMDG:III IATA :III

Environmental hazards

IMDG : 14.6. Special precautions for user NO CONCERNED 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code (Except particular case) IBC Liquid substances Metal (31A, 31B, 31N) Plastic (31H1, 31H2) GRV Solid substances Metal (11A, 11B, 21A, 21N) Plastic (11H1, 11H2, 21H1, 21H2) 15. SECTION 15 - REGULATORY INFORMATION 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Monographie (s) du RIFM n° : 288 Custom tariff : 2902 19 00 00 15.2. Chemical safety assessment 16. SECTION 16 - OTHER INFORMATIONS Full H sentenses text in point 3 : H226 Flammable liquid and vapour. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H331 Toxic if inhaled. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. -------------------------------------------------------------------------------------------------------------------------------------------------------- Key literature references and sources for data Sources for data : Information from supplier Literature references : ECHA Literature references EU : Reg. 1272/2008 -------------------------------------------------------------------------------------------------------------------------------------------------------- Safety data sheet according to REG. 1272/2008/CE and its amendings These indications are founded on the current state of our knowledge, but do not constitute a guarantee as for the properties of the product and do not give place to a contractual legal report. -------------------------------------------------------------------------------------------------------------------------------------------------------- Modified points : 9.1 04/07/2020 COMBI-BLOCKS HA-8770 1. Identification of the substance 1.1. Product identifiers: Product Name: Direct blue 6 Synonyms: Catalog number: HA-8770 CAS Number: 2602-46-2 1.2. Identified use: Laboratory chemicals, for scientific research and development only. 1.3. Supplier: Combi-Blocks, Inc., 7949 Silverton Ave # 915, San Diego, CA 92126, USA. Tel: 858- 635-8950. Email: sales@combi-blocks.com. 1.4. Emergency Contact: During normal business hours (Monday-Friday 8am-5pm PST), call 1-858-635-8950. Af- ter business hours, call Infotrac at 1-800-535-5053 (USA) or 1-352-323-3500 (interna- tional). 2. Hazards identification

OSHA HCS Classification

No data.

2.2 Label elements

No known hazard.