Note: Ingredients listed on restricted chemical lists
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
40-70%
EC/CAS
26447-40-5
Name of the chemical
Methylenediphenyl diisocyanate (see also specific isomers)
Concentration
1-10%
General Information
Revision date
2018-07-18
Product name
Structural Adhesive-Urethane (45 seconds) Part 1
Chemical name
Aromatic Isocyanate/Isocyanates aromatiques
1.2.1 Relevant identified uses
Urethane adhesive / sealant
Manufacturer Name
Saint-Gobain Abrasives, Inc
Emergency telephone
800-424-9300
Icons in SDS
Company Information
company name
Saint-Gobain Canada, Inc
GHS Information
Signal word
DANGER
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
SECTION 2: Hazards identification
OSHA HCS Classification
Page 2 of 13
Signal word
DANGER Emergency Overview Immediate Concerns: Extremely flammable liquid and vapor. Fumes and spray mist may be harmful. May irritate the eyes, skin and respiratory system. May cause sensitization by inhalation and skin contact. Vapours may cause drowsiness and dizziness. Product GHS Class
2.1 Classification of the substance or mixture
Health: Target Organ Toxicity (Repeated exposure), Category 2 Target Organ Toxicity (Single exposure), Category 3 Eye Irritation, Category 2 Skin Irritation, Category 2 Respiratory Sensitization, Category 1 Skin Sensitization, Category 1 Carcinogenicity, Category 2
Hazardous Ingredients
4,4'-Diphenylmethane diisocyanate
Health hazards
Exclamation mark
2.3 Other hazards
No data available that have been identified during the classification process
Hazard statements
H373 - May cause damage to organs (respiratory system) through prolonged or repeated exposure. H335 - May cause respiratory irritation. H319 - Causes serious eye irritation. H315 - Causes skin irritation. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 - May cause an allergic skin reaction. H351 - Suspected of causing cancer by inhalation.
Precautionary statements
P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P264 - Wash hands thoroughly after handling. P272 - Contaminated work clothing should not be allowed out of the workplace. P260 - Do not breathe mist, vapours or spray. P271 - Use only outdoors or in a well-ventilated area. P284 - Wear respiratory protection. P280 - Wear protective gloves and eye protection. P308+P313 - IF exposed or concerned: Get medical advice/attention. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 - If eye irritation persists: Get medical advice/attention. P302+P350 - IF ON SKIN: Gently wash with plenty of soap and water. P332+P313 - If skin irritation occurs: Get medical advice/attention. P362+P364 - Take off contaminated clothing and wash it before reuse. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P342+P311 - If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. P233 - Keep container tightly closed. P403+P235 - Store in a well-ventilated place. Keep cool. P405 - Store locked up. P501 - Dispose of contents/container in accordance with applicable local, regional and/or national regulations. Page 3 of 13