ArmaKleenTM 4 in 1 Cleaner - Cleaning Solution

SECTION 2: Hazards identification

Classification (GHS-US) Classification of the Substance or Mixture Classification (GHS‐US) Not classified

2.2 Label elements

GHS‐US Labeling No labeling applicable

2.3 Other hazards

Repeated exposure may cause skin, eye, and digestive tract irritation. May cause skin dryness or cracking. Product may be heated during use and could cause serious thermal burns. High concentrations of vapor or mist may irritate the respiratory tract.

Ingredient(s) with unknown acute toxicity

No additional information available

2.1 Classification of the substance or mixture

Classification (GHS‐US) Not classified Label Elements GHS‐US Labeling No labeling applicable Other Hazards Repeated exposure may cause skin, eye, and digestive tract irritation. May cause skin dryness or cracking. Product may be heated during use and could cause serious thermal burns. High concentrations of vapor or mist may irritate the respiratory tract. Unknown Acute Toxicity (GHS‐US) No additional information available SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Mixture Name Product Identifier % (w/w) Water (CAS No) 7732‐18‐5 60 ‐ 100 Contains no hazardous components above 1% or carcinogens above 0.1% SECTION 4: FIRST AID MEASURES Description of First Aid Measures General: Never give anything by mouth to an unconscious person. IF exposed or concerned: Get medical advice/attention. Inhalation: When symptoms occur: go into open air and ventilate suspected area. Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER/doctor/physician if you feel unwell. Skin Contact: Remove contaminated clothing and shoes. Flush with plenty of water. Seek medical advice if irritation develops or persists. Wash contaminated clothing before reuse. Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do so. Continue rinsing. Obtain medical attention if irritation persists. 04/27/2015 EN (English US) Ingestion: Rinse mouth. Do not induce vomiting. Get medical advice and attention. Most Important Symptoms and Effects Both Acute and Delayed General: None expected under normal conditions of use. Inhalation: May cause respiratory irritation. Skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Ingestion: May cause irritation to the digestive tract. Ingesting large amounts may cause systemic alkalosis. Chronic Symptoms: Repeated exposure may cause skin dryness or cracking. Indication of Any Immediate Medical Attention and Special Treatment Needed If medical advice is needed, have product container or label at hand. SECTION 5: FIRE‐FIGHTING MEASURES Extinguishing Media Suitable Extinguishing Media: Use extinguishing media appropriate for surrounding fire. Unsuitable Extinguishing Media: Use of heavy stream of water may spread fire. Special Hazards Arising From the Substance or Mixture Fire Hazard: Not flammable. Explosion Hazard: Product is not explosive. Containers may rupture when exposed to excessive heat. Reactivity: Hazardous reactions will not occur under normal conditions. May react vigorously with strong acids. Advice for Firefighters Precautionary Measures Fire: Exercise caution when fighting any chemical fire. Under fire conditions, hazardous fumes will be present. Firefighting Instructions: Use water spray or fog for cooling exposed containers. Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. Hazardous Combustion Products: Carbon oxides (CO, CO2). Nitrogen oxides. Reference to Other Sections Refer to section 9 for flammability properties. Refer to section 16 for NFPA information. SECTION 6: ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Do not get in eyes, on skin, or on clothing. Do not breathe vapor, mist or spray. Spilled material may present a slipping hazard. For Non‐Emergency Personnel Protective Equipment: Use appropriate personal protection equipment (PPE). Emergency Procedures: Evacuate unnecessary personnel. For Emergency Personnel Protective Equipment: Equip cleanup crew with proper protection. Emergency Procedures: Upon arrival at the scene, a first responder is expected to recognize the presence of dangerous goods, protect oneself and the public, secure the area, and call for the assistance of trained personnel as soon as conditions permit. Environmental Precautions Prevent entry to sewers and public waters. Contact competent authorities after a spill. Methods and Material for Containment and Cleaning Up For Containment: Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams. Methods for Cleaning Up: Clean up spills immediately and dispose of waste safely. Keep in suitable, closed containers for disposal. Reference to Other Sections See Section 8, Exposure Controls and Personal Protection. See Section 13, Disposal Considerations. SECTION 7: HANDLING AND STORAGE Precautions for Safe Handling Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas with mild soap and water before eating, drinking, or smoking and again when leaving work. Do not eat, drink or smoke when using this product. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Container remains hazardous when empty. Continue to observe all precautions. Storage Conditions: Store in a dry, cool and well‐ventilated place. Keep container tightly closed. Incompatible Materials: Acids. Oxidizers. Reducing agents. 04/27/2015 EN (English US) Sheet 820070 Specific End Use(s) Aqueous cleaner. For professional use only. If this product is used in combination with other products, refer to the Safety Data Sheet for those products. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Control Parameters For substances listed in section 3 that are not listed here, there are no established Exposure limits from the manufacturer, supplier, importer, or the appropriate advisory agency including: ACGIH (TLV), NIOSH (REL), OSHA (PEL), Canadian provincial governments, or the Mexican government Exposure Controls Appropriate Engineering Controls: Not generally required. Site‐specific risk assessments should be conducted to determine the appropriate exposure control measures. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Materials for Protective Clothing: As required, chemically resistant materials and fabrics. Hand Protection: Wear chemically resistant protective gloves. Eye Protection: Safety glasses with side shields, or goggles, are recommended. Skin and Body Protection: Wash contaminated clothing before reuse. Respiratory Protection: None normally required. If irritation is experienced, approved respiratory protection should be worn. Other Information: When using, do not eat, drink or smoke. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Information on Basic Physical and Chemical Properties Physical State : Liquid Appearance : Amber Clear Odor : Mild detergent Odor Threshold : Not available pH : 2.5% Solution: 10.4 5% Solution: 10.5 10% Solution: 11.0 Evaporation Rate : < 1 (butyl acetate = 1) Melting Point : 0 °C (32 °F) Freezing Point : Not available Boiling Point : 100 °C (212 °F) Flash Point : > 100 °C (212 °F) Auto‐ignition Temperature : Not available Decomposition Temperature : Not available Flammability (solid, gas) : Not available Lower Flammable Limit : Not available Upper Flammable Limit : Not available Vapor Pressure : 17.5 mm Hg at 68°F (20°C) (approximately) Relative Vapor Density at 20 °C : < 1 (air = 1) Specific Gravity : 1.005 Solubility : Complete in water Partition Coefficient: N‐Octanol/Water : Not available Viscosity : Not available Explosion Data – Sensitivity to Mechanical Impact : Not expected to present an explosion hazard due to mechanical impact. Explosion Data – Sensitivity to Static Discharge : Not expected to present an explosion hazard due to static discharge. SECTION 10: STABILITY AND REACTIVITY Reactivity: Hazardous reactions will not occur under normal conditions. May react vigorously with strong acids. Chemical Stability: The product is stable at normal handling and storage conditions. Possibility of Hazardous Reactions: Hazardous polymerization will not occur. Conditions to Avoid: Extremely high or low temperatures. Incompatible materials. Incompatible Materials: Acids. Oxidizers. Reducing agents. Hazardous Decomposition Products: Thermal decomposition generates: Carbon oxides (CO, CO2). Nitrogen oxides. 04/27/2015 EN (English US) Sheet 820070 SECTION 11: TOXICOLOGICAL INFORMATION Information on Toxicological Effects ‐ Product Acute Toxicity: Not classified LD50 and LC50 Data: Not available Skin Corrosion/Irritation: Not classified Serious Eye Damage/Irritation: Not classified Respiratory or Skin Sensitization: Not classified Germ Cell Mutagenicity: Not classified Teratogenicity: Not classified Carcinogenicity: Not classified Specific Target Organ Toxicity (Repeated Exposure): Not classified Reproductive Toxicity: Not classified Specific Target Organ Toxicity (Single Exposure): Not classified Aspiration Hazard: Not classified Symptoms/Injuries After Inhalation: May cause respiratory irritation. Symptoms/Injuries After Skin Contact: May cause skin irritation. Symptoms/Injuries After Eye Contact: May cause eye irritation. Symptoms/Injuries After Ingestion: May cause irritation to the digestive tract. Ingesting large amounts may cause systemic alkalosis. Chronic Symptoms: Repeated exposure may cause skin dryness or cracking. Information on Toxicological Effects ‐ Ingredient(s) LD50 and LC50 Data: Not available SECTION 12: ECOLOGICAL INFORMATION Toxicity Ecology ‐ General: Toxic to aquatic life with long lasting effects. Persistence and Degradability Not established Bioaccumulative Potential Not established Mobility in Soil Not available Other Adverse Effects Other Information: Avoid release to the environment. SECTION 13: DISPOSAL CONSIDERATIONS Sewage Disposal Recommendations: Do not empty into drains; dispose of this material and its container in a safe way. Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, national, provincial, territorial and international regulations. Additional Information: This product, if discarded, would not be a hazardous waste by listing and is not expected to be a characteristic hazardous waste. Processing, use, or contamination by the user may change the waste code(s) applicable to the disposal of this product. SECTION 14: TRANSPORT INFORMATION In Accordance with DOT Not regulated for transport In Accordance with IMDG Not regulated for transport In Accordance with IATA Not regulated for transport In Accordance with TDG Not regulated for transport SECTION 15: REGULATORY INFORMATION US Federal and International Regulations ArmaKleenTM 4 in 1 Cleaner – Cleaning Solution SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Water (7732‐18‐5) Listed on the Canadian DSL (Domestic Substances List) Listed on the United States TSCA (Toxic Substances Control Act) inventory 04/27/2015 EN (English US) Sheet 820070 VOLATILE ORGANIC COMPOUNDS (AS REGULATED) 2.5% Solution 0.51 WT%; 0.044 LB/US gal; 5.25 g/L; As per 40 CFR Part 51.100(s) Product Vapor Pressure @20°C = 17.5 mmHg Product does not contain photochemically reactive solvents 5.0% Solution 1.02 WT%; 0.088 LB/US gal; 10.5 g/L; As per 40 CFR Part 51.100(s) Product Vapor Pressure @20°C = 17.5 mmHg VOC Vapor Pressure @38°C = 0.644 mmHg Product does not contain photochemically reactive solvents 10% Solution 2.04 WT%; 0.175 LB/US gal; 21g/L; As per 40 CFR Part 51.100(s) Product Vapor Pressure @20°C = 17.5 mmHg VOC Vapor Pressure @38°C = 0.734 mmHg Product does not contain photochemically reactive solvents US State Regulations No additional information available Canadian Regulations ArmaKleenTM 4 in 1 Cleaner – Cleaning Solution WHMIS Classification Class E ‐ Corrosive Material Water (7732‐18‐5) Listed on the Canadian DSL (Domestic Substances List) WHMIS Classification Uncontrolled product according to WHMIS classification criteria This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all of the information required by CPR. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision Date : 04/27/2015 Other Information : This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200. NFPA Health Hazard : 1 ‐ Exposure could cause irritation but only minor residual injury even if no treatment is given. NFPA Fire Hazard : 0 ‐ Materials that will not burn. NFPA Reactivity : 0 ‐ Normally stable, even under fire exposure conditions, and are not reactive with water. Party Responsible for the Preparation of This Document Church & Dwight 500 Charles Ewing Blvd Ewing Township, NJ 08628 T 1‐800‐332‐5424 This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. Church&Dwight NA GHS SDS 04/27/2015 EN (English US) Sheet 820070