NAF S III

Hazard statements (CLP)

H226, H280, H304, H315, H317, H410, H420

Code

Statements

H226

Flammable liquid and vapour

2.1 Classification of the substance or mixture

The mixture is classified hazardous to the environment (ozone layer). Annex 6, Components CAS No. 1272/2008/EEC Chlorodifluoromethane 75-45-6 Not classified (HCFC-22) Chlorotetrafluoroethane 2837-89-0 Not classified (HCFC-124) Dichlorotrifluoroethane 306-83-2 Not classified (HCFC-123) Isopropenyl-metyl-ciclohexene (D-Limonene) 5989-27-5 Classified Reg. no. 1272/2008/EC Chlorotetrafluoroethane (HCFC-124) Reg. no. 1272/2008/EC Isopropenyl-metyl-ciclohexene (D-Limonene) GHS02: Flame GHS07: (exclamation mark) Warning

Classifications

Reg. no. 1272/2008/EC Chlorodifluoromethane (HCFC-22)

Hazard pictograms

GHS04: Gas cylinder GHS07: (exclamation mark) Warning EUH059: Hazardous to the ozone layer GHS04: Gas cylinder GHS07: (exclamation mark) Warning EUH059: Hazardous to the ozone layer GHS04: Gas cylinder GHS07: (exclamation mark) Warning EUH059: Hazardous to the ozone layer GHS08: Health hazard GHS09: Environment Flammable liquid and vapour, category 3

Hazard categories

Gases under pressure – Liquefied gas H280: Contains gas under pressure; may explode if heated. Gases under pressure – Liquefied gas H280: Contains gas under pressure; may explode if heated. Gases under pressure – Liquefied gas H280: Contains gas under pressure; may explode if heated. Skin irritant, category 2 H226: Flammable liquid and vapour. H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation - d-limonene is currently classified for skin irritation according

Hazard statements

H420: Harms public health and the environment by destroying ozone in the upper atmosphere P273: Avoid release to the environment H420: Harms public health and the environment by destroying ozone in the upper atmosphere P273: Avoid release to the environment H420: Harms public health and the environment by destroying ozone in the upper atmosphere P261 – Avoid breathing dust/fume/ gas/mist/vapors/spray to Annex VI of

Precautionary statements

P410+P403: Protect from sunlight. Store in a well-ventilated place. P501: Dispose of contents/container to controlled disposal (continues) P410+P403: Protect from sunlight. Store in a well-ventilated place. P501: Dispose of contents/container to controlled disposal Dichlorotrifluoroethane (HCFC-123) P302+P352 – If on skin, wash with plenty of soap and water. P333+P313 – If skin irritation or rash, get medical advice/attention. (continues) P280: Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 IF SWALLOWED Immediately call a POISON CENTER or doctor/physician P331: Do NOT induce vomiting. P302+P352 IF ON SKIN Wash with plenty of soap and water P333+P313 If skin irritation or rash occurs Get medical advice/attention P501: Dispose of contents/container to controlled disposal.

2.3 Other hazards

Dermal contact with rapidly evaporating liquid could result in freezing of the tissues or frostbite. High vapor concentrations can cause headaches, dizziness, drowsiness, and nausea, and may lead to unconsciousness. In case of thermal decomposition, it releases Hydrogen Fluoride (HF) and Hydrogen Chloride (HCl).