Sabakem Triclopyr 600EC Herbicide

Hazard statements (CLP)

H302, H315, H320, H335, H410

Code

Statements

H302

Harmful if swallowed

Hazard statements

This product is classified as: Xi, Irritating. Xn, Harmful. N, Dangerous to the environment. Hazardous according to the criteria of SWA. Not a Dangerous Good according to Australian Dangerous Goods (ADG) Code, IATA and IMDG/IMSBC criteria. However, this is a C1 Combustible Liquid so must be stored and handled as specified in AS 1940 “The storage and handling of flammable and combustible liquids.” H302: Harmful if swallowed. H315: Causes skin irritation. H320: Causes eye irritation. H335: May cause respiratory irritation. H410: Very toxic to aquatic life with long lasting effects.

SUSMP Classification

S6

ADG classification

None allocated. Not a Dangerous Good under the ADG Code

UN Number

None allocated

Signal word

WARNING Acute Toxicity Oral Category 4 Skin Irritation Category 2 Eye irritation Category 2B Specific Target Organ Toxicity - Single Exposure Category 3 Hazardous to aquatic environment Short term/Chronic Category 1

Prevention

P261: Avoid breathing fumes, mists, vapours or spray. P264: Wash contacted areas thoroughly after handling. P272: Contaminated work clothing should not be allowed out of the workplace. P280: Wear protective gloves, protective clothing and eye or face protection.

Response

P362: Take off contaminated clothing and wash before reuse. P363: Wash contaminated clothing before reuse. P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P302+P352 IF ON SKIN Wash with plenty of soap and water P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332+P313 If skin irritation occurs Get medical advice P337+P313 If eye irritation persists Get medical advice P391: Collect spillage. P370+P378: Not combustible. Preferred extinguishing media are carbon dioxide, dry chemical, foam, water fog.

Storage

P402+P404: Store in a dry place. Store in a closed container. P403+P235: Store in a well-ventilated place. Keep cool.

Disposal

P501: Dispose of contents and containers to landfill. Emergency Overview Physical Description & colour: Amber liquid. Odour: Characteristic odour.

Health hazards

The oral LD50 of Triclopyr in rats ranges from 630 to 729 mg/kg , and is over 2000 mg/kg for various amine and ester formulated products. The dermal LD50 for the technical material in rabbits is greater than 2000 mg/kg, and greater than 4000 mg/kg for the formulations. Inhalation of Triclopyr did not affect rats, but inhalation of some of the formulations did cause nasal irritation. These data indicate Triclopyr is harmful. Product is believed to be harmful if swallowed.