Sabakem Tri-Allate 500EC Herbicide

Hazard statements (CLP)

H227, H302, H304, H317, H336, H373, H410

Code

Statements

H227

Combustible liquid

Hazard statements

This product is classified as: Xi, Irritating. T, Toxic. N, Dangerous to the environment. Hazardous according to the criteria of SWA. Not subject to the ADG Code when transported in Australia by Road or Rail (refer to SP AU01). However if transported by Air or Sea, this provision does not apply. Then the product is classed as Dangerous (Class 9 Environmentally Hazardous) by IATA and IMDG respectively. See details below and in Section 14 of this SDS. H227: Combustible liquid. AUH066: Repeated exposure may cause skin dryness or cracking. H302: Harmful if swallowed. H304: May be fatal if swallowed and enters airways. H317: May cause an allergic skin reaction. H336: May cause drowsiness or dizziness. H373: May cause damage to organs through prolonged or repeated exposure. H410: Very toxic to aquatic life with long lasting effects.

SUSMP Classification

S5

ADG classification

Class 9 Miscellaneous dangerous goods

UN Number

3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S

Signal word

DANGER Flammable liquids Category 4 Acute Toxicity Oral Category 4

Aspiration hazard

Category 1 Skin Sensitisation Category 1 Specific Target Organ Toxicity - Single Exposure Category 3 Specific Target Organ toxicity - repeated exposure Category 2 Hazardous to aquatic environment Short term/Chronic Category 1

Prevention

P210: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. P260: Do not breathe fumes, mists, vapours or spray. P264: Wash contacted areas thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P280: Wear protective gloves, protective clothing and eye or face protection. P283: Wear fire or flame resistant/retardant clothing.

Response

P312: Call a POISON CENTER or doctor if you feel unwell. P314: Get medical advice or attention if you feel unwell. P330: Rinse mouth. P331: Do NOT induce vomiting. P363: Wash contaminated clothing before reuse. P301+P310 IF SWALLOWED Immediately call a POISON CENTER or doctor P301+P312 IF SWALLOWED Call a POISON CENTER or doctor if you feel unwell P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P302+P352 IF ON SKIN Wash with plenty of soap and water P303+P361+P353 IF ON SKIN (or hair) Remove immediately all contaminated clothing. Rinse skin with water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P333+P313 If skin irritation or rash occurs Get medical advice P391: Collect spillage. P370+P378: In case of fire, use carbon dioxide, dry chemical, foam, water fog.

Storage

P405: Store locked up. P403+P233: Store in a well-ventilated place. Keep container tightly closed. P403+P235: Store in a well-ventilated place. Keep cool.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & Colour: Amber to brown liquid. Odour: Characteristic solvent odour.

Health hazards

Technical Triallate is harmful by ingestion and practically nontoxic via dermal exposure or inhalation. Inhalation exposure to large amounts of thiocarbamates may cause itching, scratchy throat, sneezing, and coughing. Triallate is moderately irritating to the skin and is a mild eye irritant. This product, if exposed, may be harmful if swallowed, possible skin sensitiser, if aspirated, may cause lung damage, repeated exposure may cause skin dryness or cracking, vapours may cause drowsiness and dizziness.