SABAKEM QUIZALOFOP 200EC SELECTIVE HERBICIDE

Hazard statements (CLP)

H227, H304, H315, H320, H331, H335, H410

Code

Statements

H227

Combustible liquid

Hazard statements

This product is classified as: Xn, Harmful. Xi, Irritating. N, Dangerous to the environment. Hazardous according to the criteria of SWA. Not subject to the ADG Code when transported in Australia by Road or Rail in packages 500kg(L) or less; or IBCs (refer to SP AU01). However if transported by Air or Sea, this provision does not apply. Then the product is classed as Dangerous (Class 9 Environmentally Hazardous) by IATA and IMDG respectively. See details below and in Section 14 of this SDS. R65, R36/38, R50/53. Harmful May cause lung damage if swallowed. Irritating to eyes and skin Very toxic to aquatic organisms, may cause long-term adverse effects to the aquatic environment. H227: Combustible liquid. H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation. H320: Causes eye irritation. H331: Toxic if inhaled. H335: May cause respiratory irritation. H410: Very toxic to aquatic life with long lasting effects.

Precautionary statements

S23, S26, S28, S46, S60, S61, S24/25, S36/39. Do not breathe vapours or mists. In case of contact with eyes, rinse immediately with plenty of water and contact a doctor or Poisons Information Centre. After contact with skin, wash immediately with plenty of soap and water. If swallowed, contact a doctor or Poisons Information Centre immediately and show this SDS or label. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/Safety Data Sheets. Avoid contact with skin and eyes. Wear suitable protective clothing and eye/face protection.

SUSMP Classification

S6

ADG classification

Class 9 Miscellaneous Dangerous Goods

UN Number

3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S

Signal word

DANGER

Prevention

P210: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. P264: Wash contacted areas thoroughly after handling. P280: Wear protective gloves, protective clothing and eye or face protection.

Response

P331: Do NOT induce vomiting. P362: Take off contaminated clothing and wash before reuse. P301+P310 IF SWALLOWED Immediately call a POISON CENTER or doctor P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P302+P352 IF ON SKIN Wash with plenty of soap and water P303+P361+P353 IF ON SKIN (or hair) Remove immediately all contaminated clothing. Rinse skin with water P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332+P313 If skin irritation occurs Get medical advice P337+P313 If eye irritation persists Get medical advice P391: Collect spillage. P370+P378: In case of fire, use carbon dioxide, dry chemical, foam, water fog. Alcohol resistant foam is the preferred firefighting medium but, if it is not available, normal foam can be used.

Storage

P405: Store locked up. P403+P235: Store in a well-ventilated place. Keep cool.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & Colour: Dark amber liquid. Odour: Faint paint-like odour.

Health hazards

Pure Quizalofop-p-ethyl is harmful by oral exposure. The reported oral LD50 values of the compound are 1210 to 1670 mg/kg in male rats, and 1182 to 1480 mg/kg in female rats. Mice are only slightly less susceptible to the compound. Quizalofop-p-ethyl has reported LD50 values of 1753 to 2350 mg/kg in male mice and 1805 to 2360 mg/kg in female mice. irritating to eyes and skin, if aspirated, may cause lung damage.

Potential health effects

Inhalation: Short Term Exposure: Available data indicates that this product is not harmful. However product may be mildly irritating, although unlikely to cause anything more than mild transient discomfort. Long Term Exposure: No data for health effects associated with long term inhalation. Skin Contact: Short Term Exposure: Available data indicates that this product is a skin irritant. Symptoms may include itchiness and reddening of contacted skin. Other symptoms may also become evident, but all should disappear once exposure has ceased. Long Term Exposure: No data for health effects associated with long term skin exposure. Eye Contact: Short Term Exposure: This product is an eye irritant. Symptoms may include stinging and reddening of eyes and watering which may become copious. Other symptoms may also become evident. If exposure is brief, symptoms should disappear once exposure has ceased. However, lengthy exposure or delayed treatment may cause permanent damage. Long Term Exposure: No data for health effects associated with long term eye exposure. Ingestion: Short Term Exposure: Significant oral exposure is considered to be unlikely. Because of the low viscosity of this product, it may directly enter the lungs if swallowed, or if subsequently vomited. Once in the lungs, it is very difficult to remove and can cause severe injury or death. However, this product is an oral irritant. Symptoms may include burning sensation and reddening of skin in mouth and throat. Other symptoms may also become evident, but all should disappear once exposure has ceased. Long Term Exposure: No data for health effects associated with long term ingestion. Carcinogen Status: SWA: No significant ingredient is classified as carcinogenic by SWA. NTP: No significant ingredient is classified as carcinogenic by NTP. IARC: No significant ingredient is classified as carcinogenic by IARC.