Sabakem Haloxyfop 520EC Herbicide

Hazard statements (CLP)

H302, H315, H320, H332, H410

Code

Statements

H302

Harmful if swallowed

Hazard statements

This product is classified as: Xi, Irritating. Xn, Harmful. N, Dangerous to the environment. Hazardous according to the criteria of SWA. Not a Dangerous Good according to Australian Dangerous Goods (ADG) Code, IATA and IMDG/IMSBC criteria. However, this is a C1 Combustible Liquid so must be stored and handled as specified in AS 1940 “The storage and handling of flammable and combustible liquids.” H302: Harmful if swallowed. H315: Causes skin irritation. H320: Causes eye irritation. H332: Harmful if inhaled. H410: Very toxic to aquatic life with long lasting effects.

SUSMP Classification

S6

ADG classification

None allocated. Not a Dangerous Good under the ADG Code

UN Number

None allocated

Signal word

WARNING

Prevention

P261: Avoid breathing fumes, mists, vapours or spray. P264: Wash contacted areas thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well ventilated area. P280: Wear protective gloves, protective clothing and eye or face protection.

Response

P312: Call a POISON CENTRE or doctor if you feel unwell. P337 If eye irritation persists seek medical attention P362: Take off contaminated clothing and wash before reuse. P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P302+P352 IF ON SKIN Wash with plenty of soap and water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332+P313 If skin irritation occurs Get medical advice P337+P313 If eye irritation persists Get medical advice P391: Collect spillage. P370+P378 In case of fire Suitable extinguishing media are carbon dioxide, dry chemical, foam, water fog Alcohol resistant foam is the preferred firefighting medium but, if it is not available, normal foam can be used.

Storage

P402+P404: Store in a dry place. Store in a closed container. P403+P235: Store in a well-ventilated place. Keep cool.

Disposal

P501: Dispose of contents and containers to landfill. Emergency Overview Physical Description & colour: Clear brown liquid. Odour: Characteristic solvent odour.

Health hazards

For Haloxyfop-methyl the oral LD50 is 393 mg/kg for rats. The LD50 is greater than 5,000 mg/kg for rabbits whose skin is exposed to Haloxyfop-methyl. Haloxyfop-ethoxyethyl has an oral LD50 of 518-531 mg/kg for rats. The dermal LD50 is greater than 2000 mg/kg for rats and greater than 5,000 mg/kg for rabbits. Both Haloxyfop forms are non-irritating to skin and do not cause skin sensitization. They are mild eye irritants. The symptoms of toxicity in rats are reduced food intake and reduced food consumption. They may also cause liver and kidney damage. irritating to eyes and skin, harmful if swallowed.