Sabakem 2,4-D LVE 680 Herbicide

Hazard statements (CLP)

H227, H302, H317, H318, H411

Code

Statements

H227

Combustible liquid

Hazard statements

This product is classified as: Xn, Harmful. Xi, Irritating. Hazardous according to the criteria of SWA. Not subject to the ADG Code when transported in Australia by Road or Rail in packages 500kg(L) or less; or IBCs (refer to SP AU01). However if transported by Air or Sea, this provision does not apply. Then the product is classed as Dangerous (Class 9 Environmentally Hazardous) by IATA and IMDG/IMSBC respectively. See details below and in Section 14 of this SDS. H227: Combustible liquid. H302: Harmful if swallowed. H317: May cause an allergic skin reaction. H318: Causes serious eye damage. H411: Toxic to aquatic life with long lasting effects.

SUSMP Classification

S6

ADG classification

Class 9 Miscellaneous dangerous goods

UN Number

3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S

Signal word

DANGER

Prevention

P261: Avoid breathing fumes, mists, vapours or spray. P264: Wash contacted areas thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well ventilated area. P280: Wear protective gloves, protective clothing and eye or face protection.

Response

P312: Call a POISON CENTRE or doctor if you feel unwell. P363: Wash contaminated clothing before reuse. P301+P312 IF SWALLOWED Call a POISON CENTRE or doctor if you feel unwell P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P302+P352 IF ON SKIN Wash with plenty of soap and water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P332+P313 If skin irritation occurs Get medical advice P337+P313 If eye irritation persists Get medical advice P391: Collect spillage. P370+P378: In case of fire, alcohol resistant foam is the preferred firefighting medium but, if it is not available, normal foam can be used.

Storage

P402+P404: Store in a dry place. Store in a closed container. P403+P233: Store in a well-ventilated place. Keep container tightly closed.

Disposal

P501: Dispose of contents and containers to landfill. Emergency Overview Physical Description & Colour: Amber to brown liquid. Odour: Characteristic solvent odour.

Health hazards

The oral LD50 of 2,4-D ranges from 375 to 666 mg/kg in the rat, 370 mg/kg in mice, and from less than 320 to 1000 mg/kg in guinea pigs. The dermal LD50 values are 1500 mg/kg in rats and 1400 mg/kg in rabbits, respectively. In humans, prolonged breathing of 2,4-D causes coughing, burning, dizziness, and temporary loss of muscle coordination. Other symptoms of poisoning can be fatigue and weakness with possible nausea. On rare occasions following high levels of exposure, there can be inflammation of the nerve endings with muscular effects. Harmful if swallowed, eye irritant, possible skin sensitiser.