Reckon-B 275EC Herbicide

Hazard statements (CLP)

H227, H304, H315, H317, H320, H335, H361, H410

Code

Statements

H227

Combustible liquid

Hazard statements

This product is classified as: Xi, Irritating. T, Toxic. N, Dangerous to the environment. Hazardous according to the criteria of SWA. Not subject to the ADG Code when transported in Australia by Road or Rail in packages 500kg(L) or less; or IBCs (refer to SP AU01). However if transported by Air or Sea, this provision does not apply. Then the product is classed as Dangerous (Class 9 Environmentally Hazardous) by IATA and IMSBC respectively. See details below and in Section 14 of this SDS. R23, R43, R61, R63, R65, R21/22, R36/38, R36/37/38, R50/53. Toxic by inhalation. May cause sensitisation by skin contact. May cause harm to the unborn child. Possible risk of harm to the unborn child. Harmful: May cause lung damage if swallowed. Harmful in contact with skin and if swallowed. Irritating to eyes and skin. Irritating to eyes, respiratory system and skin. Very toxic to aquatic organisms, may cause long-term adverse effects to the aquatic environment. H227: Combustible liquid. H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H320: Causes eye irritation. H335: May cause respiratory irritation. H361: Suspected of damaging fertility or the unborn child. H410: Very toxic to aquatic life with long lasting effects.

Precautionary statements

S20, S23, S26, S28, S38, S46, S60, S61, S24/25, S36/37/39. When using, do not eat or drink. Do not breathe vapours or mists. In case of contact with eyes, rinse immediately with plenty of water and contact a doctor or Poisons Information Centre. After contact with skin, wash immediately with plenty of soap and water. In case of insufficient ventilation, wear suitable respiratory equipment. If swallowed, contact a doctor or Poisons Information Centre immediately and show this SDS or label. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/Safety Data Sheets. Avoid contact with skin and eyes. Wear suitable protective clothing, gloves and eye/face protection.

SUSMP Classification

S6

ADG classification

Class 9 Miscellaneous Dangerous Goods

UN Number

3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S

Signal word

DANGER

Prevention

P102: Keep out of reach of children. P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P210: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. P261: Avoid breathing fumes, mists, vapours or spray. P262: Do not get in eyes, on skin, or on clothing. P264: Wash contacted areas thoroughly after handling. P271: Use only outdoors or in a well ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P273: Avoid release to the environment. P280: Wear protective gloves, protective clothing and eye or face protection.

Response

P363: Wash contaminated clothing before reuse. P301+P310 IF SWALLOWED Immediately call a POISON CENTRE or doctor P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P303+P361+P353 IF ON SKIN (or hair) Remove immediately all contaminated clothing. Rinse skin with water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 If exposed or concerned Get medical advice P332+P313 If skin irritation occurs Get medical advice P333+P313 If skin irritation or rash occurs Get medical advice P337+P313 If eye irritation persists Get medical advice P370+P378: In case of fire, use carbon dioxide, dry chemical, foam, water fog. Alcohol resistant foam is the preferred firefighting medium but, if it is not available, normal foam can be used.

Storage

P410: Protect from sunlight. P402+P404: Store in a dry place. Store in a closed container. P403+P235: Store in a well-ventilated place. Keep cool.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & Colour: Clear, light yellow to dark brown liquid. Odour: Aromatic odour.

Health hazards

toxic if inhaled, may cause harm to unborn children, harmful in contact with skin, and if swallowed, irritating to eyes and skin, irritating to eyes, respiratory system and skin, possible skin sensitiser, possible risk of harm to the unborn child, if aspirated, may cause lung damage.

Potential health effects

Persons sensitised to Bromoxynil should avoid contact with this product. Inhalation: Short Term Exposure: Available data shows that this product is toxic, but symptoms are not available. In addition product is an inhalation irritant. Symptoms may include headache, irritation of nose and throat and increased secretion of mucous in the nose and throat. Other symptoms may also become evident, but they should disappear after exposure has ceased. Long Term Exposure: No data for health effects associated with long term inhalation. Skin Contact: Short Term Exposure: Available data shows that this product is harmful, but symptoms are not available. In addition product is a skin irritant. Symptoms may include itchiness and reddening of contacted skin. Other symptoms may also become evident, but all should disappear once exposure has ceased. Long Term Exposure: No data for health effects associated with long term skin exposure. Eye Contact: Short Term Exposure: This product is an eye irritant. Symptoms may include stinging and reddening of eyes and watering which may become copious. Other symptoms may also become evident. If exposure is brief, symptoms should disappear once exposure has ceased. However, lengthy exposure or delayed treatment may cause permanent damage. Long Term Exposure: No data for health effects associated with long term eye exposure. Ingestion: Short Term Exposure: Significant oral exposure is considered to be unlikely. Because of the low viscosity of this product, it may directly enter the lungs if swallowed, or if subsequently vomited. Once in the lungs, it is very difficult to remove and can cause severe injury or death. However, this product is an oral irritant. Symptoms may include burning sensation and reddening of skin in mouth and throat. Other symptoms may also become evident, but all should disappear once exposure has ceased. Long Term Exposure: No data for health effects associated with long term ingestion. Carcinogen Status: SWA: No significant ingredient is classified as carcinogenic by SWA. NTP: No significant ingredient is classified as carcinogenic by NTP. IARC: No significant ingredient is classified as carcinogenic by IARC.