Note: Ingredients listed on restricted chemical lists
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
N/A
EC/CAS
202-966-0
Name of the chemical
4,4'-Methylendiphenyldiisocyanat 2,2'-Methylendiphenyldiisocyanat 2,4'-Methylendiphenyldiisocyanat Methylendiphenyldiisocyanat (790/2009)
Concentration
N/A
General Information
Revision date
2012-05-03
Product name
POLURENE LPI 34 NT
CAS No.
101-68-8
1.2.1 Relevant identified uses
Hardener for coating materials or adhesives for industrial and trade applications
1.2.2. Uses advised against
Not suitable for DIY use
Icons in SDS
Company Information
company name
S.A.P.I.C.I. Spa Via Bergamo, 2
e-mail address of the competent person responsible for the Safety Data Sheet
HSE@sapici.it
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
2.1 Classification of the substance or mixture
Directive criteria, 67/548/CE, 99/45/EC and following amendments thereof: Properties / Symbols: Carcinogenic category 3 Xn Harmful Xi Irritant Limited evidence of a carcinogenic effect. Harmful: danger of serious damage to health by prolonged exposure through inhalation. Irritating to eyes, respiratory system and skin. May cause sensitization by inhalation and skin contact. EC regulation criteria 1272/2008 (CLP): Warning, Skin Irrit. 2, Causes skin irritation. Warning, Eye Irrit. 2, Causes serious eye irritation. Danger, Resp. Sens. 1, May cause allergy or asthma symptoms or breathing difficulties if inhaled. Warning, Skin Sens. 1, May cause an allergic skin reaction. Warning, Carc. 2, Suspected of causing cancer. Warning, STOT SE 3, May cause respiratory irritation. Warning, STOT RE 2, May cause damage to organs through prolonged or repeated exposure.
Adverse physicochemical, human health and environmental effects
No other hazards
2.2 Label elements
67/548/CEE, 1999/45/CE) (1272/2008/CE)
Hazard pictograms
Xn Harmful Danger
R-phrase(s)
R36/37/38 Irritating to eyes, respiratory system and skin. R40 Limited evidence of a carcinogenic effect. R42/43 May cause sensitization by inhalation and skin contact. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
S-phrase(s)
S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer). S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37 Wear suitable protective clothing and gloves. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
Contains
4,4'-methylenediphenyl diisocyanate; diphenylmethane-4,4'-diisocyanate; 4,4'-methylenediphenyl diisocyanate; diphenylmethane-4,4'-diisocyanate;
Special Provisions
Contains isocyanates. See information supplied by the manufacturer. EUH204 Contains isocyanates. May produce an allergic reaction.
Hazard statements
H315 Causes skin irritation. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
P201 Obtain special instructions before use. P280 Wear protective gloves/protective clothing/eye protection/face protection. P281 Use personal protective equipment as required. P308+P313 IF exposed or concerned: Get medical advice/attention. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention.
vPvB Substances
None
PBT Substances
None
