SCRUBS In-A-Bucket

2.2 Label elements

None WPS-ITW-002 - SCRUBS® In-A-Bucket Date: 15-May-2017

Hazard statements

None Physical and Health Hazards Not Otherwise Classified Not applicable.

Prevention

* None General Advice » None

Storage

None Keep container closed when not in use. Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Do not contaminate food or feed stuffs. Keep out of the reach of children. Incompatible Products Strong oxidizing agents. Strong acids. Control parameters Exposure Guidelines This product does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Appropriate engineering controls WPS-ITW-002 - SCRUBS® In-A-Bucket Date: 15-May-2017 Engineering Measures Eyewash stations. Individual protection measures, such as personal protective equipment Eye/Face Protection None required under normal usage. Risk of contact, wear: Goggles. Skin and Body Protection None required under normal usage. Repeated or prolonged contact: Wear protective gloves/clothing. Respiratory Protection None required under normal usage. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Information on basic physical and chemical properties Physical State Liquid.

Disposal

* None

Further information

Toxic to aquatic life. Harmful to aquatic life with long lasting effects. 0% of the mixture consists of ingredient(s) of unknown toxicity. Chemical Name CAS-No Weight % Hazardous Materia! Date: HMIRA fited and Information Review Act|date exemption granted registry number (HMIRA| (if applicable) registry #) Orange Terpenes §989-27-5 2 > Alcohols, C12-15, ethoxylated 68131-39-5 1.94 ” - lsoparaffinic Hydrocarbon 64742-47-8 4.4 - Dimethyl adipate 627-93-0 1.14 - Diethylhexyl sodium sulfosuccinate 577-11-7 1.03 > Description of necessary first-aid measures Eye Contact Rinse thoroughly with plenty of water, also under the eyelids. Get medical attention if symptoms occur. Skin Contact None normally required. Material is designed for skin cleansing. In the case of skin irritation or allergic reactions see a physician. Inhalation Move to fresh air. Get medical attention if symptoms occur. Ingestion Not an expected route of exposure. If large quantities of this material are swallowed, call a physician immediately. Most important symptoms/effects, acute and delayed Most Important Symptoms/Effects No information available. Indication of immediate medical attention and special treatment needed, if necessary Notes to Physician Treat symptomatically. WPS-ITW-002 - SCRUBS® In-A-Bucket Date: 15-May-2017 Suitable Extinguishing Media Dry chemical. Carbon dioxide (CO 2 ). Foam. Water spray or fog. Unsuitable Extinguishing Media None Specific Hazards Arising fromthe. None in particular Chemical Hazardous Combustion Carbon dioxide (CO ). Carbon monoxide. Hydrocarbons. Hydrogen sulfide. Sulfur dioxide. Products Soot. Explosion Data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective Equipment and Use water spray to cool surrounding containers. Precautions for Firefighters Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment. Avoid contact with eyes. Environmental Precautions Prevent entry into waterways, sewers, basements or confined areas. Avoid release to the environment. See Section 12 for additional Ecological Information. Methods and materials for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up Small spillage Wipe up with absorbent material (e.g. cloth, fleece). Large spillage Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Precautions for safe handling Handling Avoid contact with eyes. Do not smoke. Handle in accordance with good industrial hygiene and safety practice. Conditions for safe storage, including any incompatibilities VOC Content (%) 0% Reactivity Not reactive under normal conditions. Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions. None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur. Conditions to avoid Incompatible products. Incompatible materials Strong oxidizing agents. Strong acids. WPS-ITW-002 - SCRUBS® In-A-Bucket Date: 15-May-2017 Hazardous decomposition products Carbon dioxide (COz), Carbon monoxide (CO). Hydrocarbons. Hydrogen sulfide. Sulfur dioxide. Soot. Information on likely routes of exposure Product Information Inhalation Not an expected route of exposure. Eye Contact Non-irritating. (rabbit) Skin Contact May cause mild skin irritation. Ingestion Not an expected route of exposure, Numerical measures of toxicity - Product. Unknown acute toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity. The following values are calculated based on chapter 3.1 of the GHS document: LD56 Oral 35696 mg/kg; Acute toxicity estimate LD50 Dermal 113740 mg/kg; Acute toxicity estimate Orange Terpenes §200 mg/kg { Rat > 5 g/kg ( Rabbit ) (Rat) Dimethyl adipate > 5000 mg/kg (Rat) > 5000 mg/kg ( Rabbit } Diethylhexyl sodium sulfosuccinate = 1900 mg/kg ( Rat} > 10000 mg/kg { Rabbit } - Symptoms related to the physical, chemical and toxicological characteristics Symptoms No information availabie. Delayed and immediate effects and also chronic effects from short and long term exposure Respiratory or Skin Sensitization The results of testing on guinea pigs showed this material to be non-sensitizing. OECD Test Guideline 406 Germ Celt Mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Orange Terpenes IARC: (International Agency for Research on Cancer) Group 3 - Not Classifiable as to its Carcinogenicity to Humans OSHA: (Occupational Safety & Health Administration) X - Present Reproductive Toxicity This praduct does not contain any known or suspected reproductive hazards. STOT - single exposure None of the ingredients are known to cause specific target organ effects from a single exposure. STOT - repeated exposure None of the ingredients are known to cause specific target organ effects through prolonged or repeated exposure. Aspiration Hazard Not applicable. Ecotoxicity Harmful to aquatic life with long lasting effects. Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to Daphnia Magna (Water Microorganisms Flea) WPS-ITW-002 - SCRUBS® [n-A-Bucket Revision Date 15-May-2017 Orange Terpenes LC50 96 h: 0.619 - 0.796 5989-27-5 mg/L flow-through (Pimephales promelas) LC50 96 h: = 35 mg/L (Oncorhynchus mykiss) lsoparaffinic Hydrocarbon LC50 96 h: = 2.2 mog/L static LC50 96 h: = 4720 mg/L 64742-47-8 (Lepomis macrochirus) LC50| ({Den-dronereides 96 h: = 2.4 mg/L static heteropada) (Oncorhynchus mykiss) LO50 96 h: = 45 mg/L flow-through (Pimephales promelas} Diethylhexyl sodium LC50 96 h: 20 - 40 mg/L EC50 48 h: = 36 mg/L sulfosuccinate semi-static (Oncorhynchus (Daphnia magna) 577-11-7 mykiss) LC5O 96 h: < 24 mg/L static (Oncorhynchus mykiss) LC50 96 h: = 37 mg/L. static (Lepomis macrochirus) Persistence and Degradability No information available. Bioaccumulation No information available. Mobility No information available. Other Adverse Effects No information available. Waste Disposal Methods Dispose of in accordance with local reguiations. Contaminated Packaging Do not re-use empty containers. This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Orange Terpenes Toxic Not regulated IATA Not regulated IMDG/IMO Not regulated international Regulations Ozone depleting substances Not applicable Persistent Organic Pollutants Not applicable Hazardous Waste Not applicable The Rotterdam Convention (Prior Not applicable Informed Consent} International Convention for the Not applicable Prevention of Pollution from Ships (MARPOL) WPS-ITW-002 - SCRUBS® in-A-Bucket Revision Date 15-May-2017 International Inventories TSCA Complies DSL All components are listed either on the DSL or NDSL. Legend TSCA - United States Toxic Substances Contro! Act Section 8(b) inventory DSLI/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List U.S. Federal Requlations Section 313 of Titfe Ill of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard No Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material.

Appearance/Odor

Colorless-blue/white. Citrus. Odor Threshold No information available. Property Values

Remarks

- Method pH None known Melting Point/Range No data available None known Boiling Point/Boiling Range 212 None known Flash Point No data available None known Evaporation rate No daia available None known Fiammability (solid, gas) No data available None known Flammability Limits in Air upper flammability limit No data available lower flammability limit No data availabie Vapor Pressure No data available None known Vapor Density None known Relative Density No data available None known Specific Gravity 0.995 None known Water Solubility Miscible with water None known Solubility in other solvents No data available None known Partition coefficient: n-octanol/waterNo data available None known Autoignition Temperature No data available None known Decomposition Temperature No data available None known Viscosity No data available None known Flammable Properties Not flammable Explosive Properties No data available Oxidizing Properties No data available