ZINSSR 1-GL 4 PK PAINT AND VARNISH

Hazard statements (CLP)

H224, H242, H302, H303, H305, H313, H315, H319, H320, H332, H335, H336, H351, H361, H370, H373

Code

Statements

H224

Extremely flammable liquid and vapour

SECTION 2: Hazards identification

EMERGENCY OVERVIEW: Danger! Poison, contains methyl alcohol. Vapor harmful. May be fatal or cause blindness if swallowed. Harmful if swallowed. Causes eye irritation. Causes nose and throat irritation. Harmful if inhaled. May affect the brain or nervous system causing dizziness, headache or nausea. Vapor Harmful. Causes Eye, Skin, Nose, and Throat Irritation. May cause eye, skin, or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN. Harmful if inhaled. Use ventilation necessary to keep exposures below recommended exposure limits, if any. Extremely flammable liquid and vapor. Vapors may cause flash fire or explosion. Classification Symbol(s) of Product

Signal word

Danger Possible Hazards 21% of the mixture consists of ingredient(s) of unknown acute toxicity GHS HAZARD STATEMENTS Acute Toxicity, Oral, category 5 H303 May be harmful if swallowed Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin Skin Irritation, category 2 H315 Causes skin irritation Eye Irritation, category 2 H319 Causes serious eye irritation Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled STOT, single exposure, category 3, RTI H335 May cause respiratory irritation STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness Organic Peroxide, categories C, D H242 Heating may cause a fire Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways Eye Irritation, category 2B H320 Causes eye irritation Flammable Liquid, category 1 H224 Extremely flammable liquid and vapour Carcinogenicity, category 2 H351 Suspected of causing cancer. Classified as Category 2 based on limited evidence on human and/or animal studies. Mixtures with concentrations of suspected carcinogens ingredients at concentration present between 0.1% and 1.0% labelling the SDS will be optional depending on authorities. If Category 2 carcinogenic present at a concentration of 1% or above labelling the SDS will be expected. Routes of exposure are dependant on ingredient form Reproductive Toxicity, category 2 H361 Suspected of damaging fertility or the unborn child. Classifed Category 2 suspected human reproductive toxicant irreversible effects such as structural malfunctions, embryo/foetal lethality, post natal functional deficiencies STOT, single exposure, category 1 H370 Causes damage to organs . Classified Category 1 Substances that produced significant toxicity in humans and evidence to produce significant toxicity with single exposure. Cell death, adverse change in biochemistry, haematology or urinalysis parameters, Central or peripheral nervous system and effects senses. multifocal or diffuse necrosis, fibrosis or granuloma formation in organs STOT, repeated exposure, category 2 H373 May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard> Acute Toxicity, Oral, category 4 H302 Harmful if swallowed

Precautionary statements

P102 Keep out of reach of children. P103 Read label before use. P234 Keep only in original container. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P262 Do not get in eyes, on skin, or on clothing. P264 Wash … thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P281 Use personal protective equipment as required. P285 In case of inadequate ventilation wear respiratory protection. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P350 Gently wash with plenty of soap and water. P374 Fight fire with normal precautions from a reasonable distance. P402 Store in a dry place. P211 Do not spray on an open flame or other ignition source. P375 Fight fire remotely due to the risk of explosion. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P362 Take off contaminated clothing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P403+P235 Store in a well-ventilated place. Keep cool. P201 Obtain special instructions before use. P308+P313 IF exposed or concerned: Get medical advice/attention. P307+P311 IF exposed: Call a POISON CENTER or doctor/physician.

2.1 Classification of the substance or mixture

Possible Hazards 21% of the mixture consists of ingredient(s) of unknown acute toxicity GHS HAZARD STATEMENTS Acute Toxicity, Oral, category 5 H303 May be harmful if swallowed. Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin. Skin Irritation, category 2 H315 Causes skin irritation. Eye Irritation, category 2 H319 Causes serious eye irritation. Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled. STOT, single exposure, category 3, RTI H335 May cause respiratory irritation. STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness. Organic Peroxide, categories C, D H242 Heating may cause a fire. Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways Eye Irritation, category 2B H320 Causes eye irritation Flammable Liquid, category 1 H224 Extremely flammable liquid and vapour. Carcinogenicity, category 2 H351 Suspected of causing cancer. Classified as Category 2 based on limited evidence on human and/or animal studies. Mixtures with concentrations of suspected carcinogens ingredients at concentration present between 0.1% and 1.0% labelling the SDS will be optional depending on authorities. If Category 2 carcinogenic present at a concentration of 1% or above labelling the SDS will be expected. Routes of exposure are dependant on ingredient form. Reproductive Toxicity, category 2 H361 Suspected of damaging fertility or the unborn child. Classifed Category 2 suspected human reproductive toxicant irreversible effects such as structural malfunctions, embryo/foetal lethality, post natal functional deficiencies. STOT, single exposure, category 1 H370 Causes damage to organs . Classified Category 1 Substances that produced significant toxicity in humans and evidence to produce significant toxicity with single exposure. Cell death, adverse change in biochemistry, haematology or urinalysis parameters, Central or peripheral nervous system and effects senses. multifocal or diffuse necrosis, fibrosis or granuloma formation in organs. STOT, repeated exposure, category 2 H373 May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. Acute Toxicity, Oral, category 4 H302 Harmful if swallowed. GHS LABEL PRECAUTIONARY STATEMENTS P102