5/6/2015

Hazard statements (CLP)

H222, H224, H280, H303, H305, H313, H315, H319, H320, H332, H335, H336, H340, H350, H373

Code

Statements

H222

Extremely flammable aerosol

SECTION 2: Hazards identification

EMERGENCY OVERVIEW: Harmful if swallowed. Extremely flammable liquid and vapor. Vapors may cause flash fire or explosion.

Contains

Under Pressure. Harmful if inhaled. May affect the brain or nervous system causing dizziness, headache or nausea. May cause eye, skin, or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN. Harmful if inhaled. Causes eye irritation. Use ventilation necessary to keep exposures below recommended exposure limits, if any. Vapor Harmful. Causes Eye, Skin, Nose, and Throat Irritation. Classification Symbol(s) of Product

Signal word

Danger Possible Hazards 60% of the mixture consists of ingredient(s) of unknown acute toxicity GHS HAZARD STATEMENTS Flammable Aerosol, category 1 H222 Extremely flammable aerosol Flammable Liquid, category 1 H224 Extremely flammable liquid and vapor Acute Toxicity, Oral, category 5 H303 May be harmful if swallowed Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin Skin Irritation, category 2 H315 Causes skin irritation Eye Irritation, category 2 H319 Causes serious eye irritation Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled STOT, single exposure, category 3, RTI H335 May cause respiratory irritation STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways Eye Irritation, category 2B H320 Causes eye irritation Flammable Aerosol, category 1 H280 Contains gas under pressure; may explode if heated Germ Cell Mutagenicity, category 1B H340 May cause genetic defects. Classified as mutagenic Category 1 if one ingredient is present at or above 0.1%. Applies to liquids, solids (w/w units) and gases (v/v). The substance may also have its own exposure limit Routes of exposure are dependent on ingredient form Carcinogenicity, category 1B H350 May cause cancer. Classified as carcinogenic Category 1 on the basis of epidemiological and/or animal data. Mixtures are classified as carcinogenic when at least 1 ingredient has been classified as carcinogenic and is present at 0.1% or above Routes of exposure are dependant on ingredient form STOT, repeated exposure, category 2 H373 May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>

Precautionary statements

P211 Do not spray on an open flame or other ignition source. P220 Keep/Store away from clothing/…/combustible materials. P235 Keep cool. P251 Pressurized container: Do not pierce or burn, even after use. P375 Fight fire remotely due to the risk of explosion. P102 Keep out of reach of children. P103 Read label before use. P202 Do not handle until all safety precautions have been read and understood. P234 Keep only in original container. P260 Do not breathe dust/fume/gas/mist/vapors/spray. P261 Avoid breathing dust/fume/gas/mist/vapors/spray. P262 Do not get in eyes, on skin, or on clothing. P264 Wash … thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P281 Use personal protective equipment as required. P285 In case of inadequate ventilation wear respiratory protection. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P351 Rinse cautiously with water for several minutes. P374 Fight fire with normal precautions from a reasonable distance. P402 Store in a dry place. P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking. P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50°C / 122°F. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting/…/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P370+P378 In case of fire: Use … for extinction. P403+P235 Store in a well-ventilated place. Keep cool. P501 Dispose of contents/container to … P321 Specific treatment (see … on this label). P352 Wash with plenty of soap and water. P362 Take off contaminated clothing and wash before reuse. P332+P313 If skin irritation occurs: Get medical advice/attention. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P405 Store locked up. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P201 Obtain special instructions before use. P308+P313 IF exposed or concerned: Get medical advice/attention. P314 Get medical advice/attention if you feel unwell. P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.

2.1 Classification of the substance or mixture

Possible Hazards 60% of the mixture consists of ingredient(s) of unknown acute toxicity GHS HAZARD STATEMENTS Flammable Aerosol, category 1 H222 Extremely flammable aerosol. Flammable Liquid, category 1 H224 Extremely flammable liquid and vapor. Acute Toxicity, Oral, category 5 H303 May be harmful if swallowed. Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin. Skin Irritation, category 2 H315 Causes skin irritation. Eye Irritation, category 2 H319 Causes serious eye irritation. Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled. STOT, single exposure, category 3, RTI H335 May cause respiratory irritation. STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness. Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways. Eye Irritation, category 2B H320 Causes eye irritation. Flammable Aerosol, category 1 H280 Contains gas under pressure; may explode if heated. Germ Cell Mutagenicity, category 1B H340 May cause genetic defects. Classified as mutagenic Category 1 if one ingredient is present at or above 0.1%. Applies to liquids, solids (w/w units) and gases (v/v). The substance may also have its own exposure limit. Routes of exposure are dependent on ingredient form. Carcinogenicity, category 1B H350 May cause cancer. Classified as carcinogenic Category 1 on the basis of epidemiological and/or animal data. Mixtures are classified as carcinogenic when at least 1 ingredient has been classified as carcinogenic and is present at 0.1% or above Routes of exposure are dependant on ingredient form. STOT, repeated exposure, category 2 H373 May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. GHS PRECAUTIONARY STATEMENTS P211 Do not spray on an open flame or other ignition source.