11/6/2014

Hazard statements (CLP)

H227, H242, H305, H313, H315, H320, H332, H335, H336, H340, H350, H373

Code

Statements

H227

Combustible liquid

SECTION 2: Hazards identification

EMERGENCY OVERVIEW: Harmful if swallowed. Causes eye irritation. Flammable liquid and vapor. Causes nose and throat irritation. Harmful if inhaled. May affect the brain or nervous system causing dizziness, headache or nausea. Vapor Harmful. Causes Eye, Skin, Nose, and Throat Irritation. May cause eye, skin, or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN. Harmful if inhaled. Combustible liquid and vapor. Use ventilation necessary to keep exposures below recommended exposure limits, if any. Classification Symbol(s) of Product

Signal word

Danger GHS HAZARD STATEMENTS Flammable liquid, category 4 H227 Combustible liquid Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin Skin Irritation, category 2 H315 Causes skin irritation Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled STOT, single exposure, category 3, RTI H335 May cause respiratory irritation STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness Organic Peroxide, categories C, D H242 Heating may cause a fire Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways Eye Irritation, category 2B H320 Causes eye irritation Germ Cell Mutagenicity, category 1B H340 May cause genetic defects. Classified as mutagenic Category 1 if one ingredient is present at or above 0.1%. Applies to liquids, solids (w/w units) and gases (v/v). The substance may also have its own exposure limit Routes of exposure are dependent on ingredient form Carcinogenicity, category 1B H350 May cause cancer. Classified as carcinogenic Category 1 on the basis of epidemiological and/or animal data. Mixtures are classified as carcinogenic when at least 1 ingredient has been classified as carcinogenic and is present at 0.1% or above Routes of exposure are dependant on ingredient form STOT, repeated exposure, category 2 H373 May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>

Precautionary statements

P102 Keep out of reach of children. P103 Read label before use. P202 Do not handle until all safety precautions have been read and understood. P234 Keep only in original container. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P262 Do not get in eyes, on skin, or on clothing. P264 Wash … thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P281 Use personal protective equipment as required. P285 In case of inadequate ventilation wear respiratory protection. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P351 Rinse cautiously with water for several minutes. P374 Fight fire with normal precautions from a reasonable distance. P402 Store in a dry place. P410+P412 Protect from sunlight. Do no expose to temperatures exceeding 50°C/ 122°F. P321 Specific treatment (see … on this label). P352 Wash with plenty of soap and water. P362 Take off contaminated clothing and wash before reuse. P332+P313 If skin irritation occurs: Get medical advice/attention. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P405 Store locked up. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P501 Dispose of contents/container to … P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking. P220 Keep/Store away from clothing/…/combustible materials. P420 Store away from other materials. P411+P235 Store at temperatures not exceeding …°C/…°F. Keep cool. P201 Obtain special instructions before use. P308+P313 IF exposed or concerned: Get medical advice/attention. P314 Get medical advice/attention if you feel unwell. P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.

2.1 Classification of the substance or mixture

GHS HAZARD STATEMENTS Flammable liquid, category 4 H227 Combustible liquid Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin. Skin Irritation, category 2 H315 Causes skin irritation. Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled. STOT, single exposure, category 3, RTI H335 May cause respiratory irritation. STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness. Organic Peroxide, categories C, D H242 Heating may cause a fire. Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways. Eye Irritation, category 2B H320 Causes eye irritation. Germ Cell Mutagenicity, category 1B H340 May cause genetic defects. Classified as mutagenic Category 1 if one ingredient is present at or above 0.1%. Applies to liquids, solids (w/w units) and gases (v/v). The substance may also have its own exposure limit. Routes of exposure are dependent on ingredient form. Carcinogenicity, category 1B H350 May cause cancer. Classified as carcinogenic Category 1 on the basis of epidemiological and/or animal data. Mixtures are classified as carcinogenic when at least 1 ingredient has been classified as carcinogenic and is present at 0.1% or above Routes of exposure are dependant on ingredient form. STOT, repeated exposure, category 2 H373 May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. GHS PRECAUTIONARY STATEMENTS P102 Keep out of reach of children.