Karma Pour-On Lousicide for Sheep

Hazard statements (CLP)

H315, H319, H335, H336, H360, H411

Code

Statements

H315

Causes skin irritation

Hazard statements

This product is classified as: Xi, Irritating. T, Toxic. N, Dangerous to the environment. Hazardous according to the criteria of SWA. Not subject to the ADG Code when transported in Australia by Road or Rail in packages 500kg(L) or less; or IBCs (refer to SP AU01). However if transported by Air or Sea, this provision does not apply. Then the product is classed as Dangerous (Class 9 Environmentally Hazardous) by IATA and IMDG/IMSBC respectively. See details below and in Section 14 of this SDS. H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation. H336: May cause drowsiness or dizziness. H360: May damage fertility or the unborn child. H411: Toxic to aquatic life with long lasting effects.

SUSMP Classification

S5

ADG classification

Class 9 Miscellaneous Dangerous Goods

UN Number

3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S

Signal word

DANGER Skin Irritation Category 2 Serious eye irritation Category 2/2A Specific Target Organ Toxicity - Single Exposure Category 3 Reproductive Toxicity Category 1 Hazardous to aquatic environment Short term/Chronic Category 2

Prevention

P261: Avoid breathing fumes, mists, vapours or spray. P262: Do not get in eyes, on skin, or on clothing. P264: Wash contacted areas thoroughly after handling. P271: Use only outdoors or in a well ventilated area. P273: Avoid release to the environment. P280: Wear protective gloves, protective clothing and eye or face protection.

Response

P362: Take off contaminated clothing and wash before reuse. P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P302+P352 IF ON SKIN Wash with plenty of soap and water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 If exposed or concerned Get medical advice P332+P313 If skin irritation occurs Get medical advice P337+P313 If eye irritation persists Get medical advice P391: Collect spillage. P370+P378: In case of fire, use carbon dioxide, dry chemical, foam, water fog. Alcohol resistant foam is the preferred firefighting medium but, if it is not available, normal foam can be used.

Storage

P410: Protect from sunlight. P402+P404: Store in a dry place. Store in a closed container. P403+P235: Store in a well-ventilated place. Keep cool.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & Colour: Clear blue liquid Odour: Mild ether odour.

Health hazards

Acute Toxicity Imidacloprid is harmful. The LD50 is 450 mg/kg body weight in rats, and 131 mg/kg in mice. The 24-hour dermal LD50 in rats is >5,000 mg/kg. It is considered non-irritating to eyes and skin (rabbits), and non-sensitizing to skin (guinea pigs). The LC50 is > 69 mg/m3 as an aerosol, and >5323 mg/m3 as a dust. Signs and Symptoms of Poisoning: Although no account of human poisoning was found in the literature, signs and symptoms of poisoning would be expected to be similar to nicotinic signs and symptoms, including fatigue, twitching, cramps, and muscle weakness including the muscles necessary for breathing. May cause serious damage to eyes, may cause harm to unborn children, irritating to respiratory system and skin, vapours may cause drowsiness and dizziness.