ACID DYE HOT FUCHSIA

Hazard statements (CLP)

H341

Code

Statements

H341

Suspected of causing genetic defects

SECTION 2: Hazards identification

OSHA GHS Classification: Health Category 2-Mutagen Pictogram

Signal word

Warning Hazard Statements: H341: Suspected of Causing Genetic Defects Precautionary Statements P264: Wash face, hands, and any exposed skin thoroughly after handling P280: Wear protective gloves/ protective clothing/eye protection/face protection P270: Do not eat, drink, or smoke when using this product P260: Do not breath dust/fume/gas/mist/vapors/spray P284: Wear Respiratory Protection P201: Obtain special instructions before use P273: Avoid release to the environment P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337 + P313 If eye irritation persists: Get medical advice/attention P302 + P352 IF ON SKIN: Wash with plenty of soap and water for 15 minutes P333 + P313 If skin irritation or rash occurs: Get medical advice/attention P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a comfortable position for breathing P342 + P311 If experiencing respiratory symptoms: Call a Poison Center or doctor/physician P308 + P313 IF exposed or concerned: get medical advice / attention COMPOSITION/INFORMATIONS ON INGREDIENTS Proprietary Acid Dye In vitro mutagen in animal tests The exact ingredient percentages and composition has been withheld as a trade secret FIRST-AID MEASURES GENERAL INFORMATION: IMMEDIATELY REMOVE ALL CONTAMINATED CLOTHING EYE CONTACT ............ Wash immediately with large amounts of water for 15 minutes, lifting the upper and lower lids until no evidence of product remain. Get medical attention immediately. Do not wear contact lenses while handling SKIN CONTACT ........... Remove all contaminated clothing immediately. Wash immediately with soap and plenty of water. If a temporary skin reaction occurs, it should be treated as allergic contact dermatitis. Launder contaminated clothing before reuse INGESTION ................... Dilute with water. Get medical attention. Never give fluids or induce vomiting if patient is unconscious or has convulsions INHALATION ............... If inhaled, remove to fresh air. If not breathing, give artificial respiration, preferably mouth to mouth. If breathing is difficult, give oxygen. Call a physician MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED The most significant symptoms and effects are described in the labelling (see section 2) and/or in section 11 INDICATION OF ANY SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED No data available FIREFIGHTING MEASURES FLASH POINT ................................... Not Applicable EXTINGUISHING MEDIA ............... CO2 Dry Chemical Foam Water Fog SPECIAL FIRE FIGHTING PROCEDURES/UNUSUAL FIRE OR EXPLOSION HAZARDS Firefighters should be equipped with protective clothing & self-contained breathing apparatus to protect against potentially toxic & irritating fumes. In case of fire or explosion, keep unnecessary people away. Isolate hazard area & any entry. Stay upwind, out of low areas, and ventilate closed spaces before entering ADDITIONAL INFORMATION ....... Avoid dusting conditions. May form explosive dust mixtures with air ACCIDENTAL RELEASE MEASURES IN CASE MATERIAL IS RELEASED/SPILLED Avoid formation and deposition of dust. Do not empty into drains or waters. Do not touch or walk through the spilled material: stop leak if you can do it without risk. Take up with sand or other non-combustible absorbent material or suitable vacuum and place into labeled sealable containers. For further disposal measures see HANDLING AND STORAGE PRECAUTIONS FOR SAFE HANDLING In accord with good industrial practice. Handle with care and avoid personal contact CONDTIONS FOR SAFE STORAGE,INCLUDING ANY INCOMPATIBLITIES Keep container protected from direct sunlight in a dry, cool and in a well-ventilated area Keep the container tightly sealed and away from any incompatible materials (see Section 10) EXPOSURE CONTROLS/PERSONAL PROTECTION APPROPRIATE ENGINEERING CONTROLS Handle with good industrial practices and industrial hygiene. Wash hands after use GENERAL PROTECTIVE MEASURES Do not breathe dust. Avoid contact with eyes and skin. Immediately remove all contaminated clothing EYE PROTECTION .......... Employees should wear protective eye-goggles with side protection shield SKIN PROTECTION ......... Employees should avoid skin contact by wearing protective clothing. Long sleeve shirts, pants, gloves e.g. of PVC or nitrile rubber, and boots are recommended Additional protections such as impervious suits are recommended when the potential for dermal contact is significant. Employees should wash their hands and face before eating and drinking and shower thoroughly before leaving work. Keep away from food and drink stuffs RESPIRATORY PROTECTION ............Inhalation of dust and aerosols must be absolutely prevented by the use of a NIOSH approved dust respirator VENTILATION ................. Use local ventilation OTHER ............................... Wear overalls, apron or other protective clothing PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE ........................ POWDER COLOR .................................... RED ODOR ....................................... NONE ODOR THRESHOLD…………NA SOLUBILITY IN WATER ...... 10 g/l at 30 deg C BULK DENSITY ...................... ND RELATIVE DENSITY………...NA VISCOSITY……………………NA pH ............................................. 6.5 – 8.0 @ 1.0 g/l MELTING POINT/FREEZING POINT……NA PARTITION COEFFICIENT: N-OCTANOL/WATER……..ND BOILING POINT…………………NA VAPOR PRESSURE…………….NA VAPOR DENSITY………………NA EVAPORATION RATE…………NA FLAMMABILITY………………NA FLASH POINT………………….NA AUTO-IGNITION TEMP ......... NA DECOMPOSITION TEMPERATURE….ND UEL…………………………….NA LEL……………………………..NA % VOLATILE VALUE: ND UNIT: % COMMENT STABILITY AND REACTIVITY THERMAL DECOMPOSITION: No thermal decomposition when stored and handled correctly POSSIBILITY OF HAZARDOUS REACTIONS In the case of dusty organic products the possibility of a dust explosion should always be considered CHEMICAL STABILITY………………………Stable INCOMPATABLE MATERIALS: None HAZARDOUS DECOMPOSITION PRODUCTS……CO2, CO, SULFUR OXIDES, NITROGEN OXIDES CONDITIONS TO AVOID…………Avoid dusting conditions and sparks/flame REACTIVITY….Will not occur TOXICOLOGICAL INFORMATION ANIMAL TOXICITY ORAL - LD50 (INGESTION) ......... > 5000 mg/kg (RAT) FISH, LC50 .......................................................................... 450 mg/l ( 48 hour, Rainbow trout) EYE EFFECTS ..................................................................... NON-IRRITANT (RABBIT EYE) SKIN EFFECTS .................................................................. NON-IRRITANT (RABBIT) SENSITIZATION ............................................................... NOT A SENSITIZER (RIPT- HUMANS) PRIMARY ROUTE OF EXPOSURE INHALATION YES SKIN ABSORPTION NO INGESTION: NO SKIN CONTACT YES EYE CONTACT YES CARCINOGEN STATUS IARC NO NTP: NO NONE NONE

Hazard pictograms

NONE NONE

Hazard statements

NONE NONE

Precautionary statements

P264: Wash face, hands, and any exposed skin thoroughly after handling. P280: Wear protective gloves/ protective clothing/eye protection/face protection P270: Do not eat, drink, or smoke when using this product. P260: Do not breath dust/fume/gas/mist/vapors/spray P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P302 + P352 IF ON SKIN: Wash with plenty of soap and water for 15 minutes . P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a comfortable position for breathing. Wash face, hands and any exposed skin thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Do not eat, drink, or smoke when using this product. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Call a POISON CENTER or doctor/physician if you feel unwell.

Principle Routes of Exposure

INHALATION: YES SKIN ABSORPTION: NO INGESTION: NO SKIN CONTACT: YES EYE CONTACT: YES CARCINOGEN STATUS IARC: NO NTP: NO

Medical Conditions Generally Aggravated by Exposure

Persons with any pre-existing skin, eye or respiratory condition may be more susceptible to the effects of this product.

Hazardous Ingredients

HAZARDOUS COMPONENTS: NONE The exact ingredient percentages and composition has been withheld as a trade secret. 4. EMERGENCY AND FIRST AID PROCEDURES GENERAL INFORMATION: IMMEDIATELY REMOVE ALL CONTAMINATED CLOTHING EYE CONTACT ................ Wash immediately with large amounts of water for 15 minutes, lifting the upper and lower lids until no evidence of product remain. Get medical attention immediately. Do not wear contact lenses while handling. SKIN CONTACT .............. Remove all contaminated clothing immediately. Wash immediately with soap and plenty of water. If a temporary skin reaction occurs, it should be treated as allergic contact dermatitis. Launder contaminated clothing before reuse. INGESTION ...................... Dilute with water. Get medical attention. Never give fluids or induce vomiting if patient is unconscious or has convulsions. INHALATION ................... If inhaled, remove to fresh air. If not breathing, give artificial respiration, preferably mouth to mouth. If breathing is difficult, give oxygen. Call a physician. 5. FIRE AND EXPLOSION DATA FLASH POINT ....................................... Not Applicable EXTINGUISHING MEDIA .................... C02 Dry Chemical Foam Water Fog SPECIAL FIRE FIGHTING PROCEDURES/UNUSUAL FIRE OR EXPLOSION HAZARDS: Firefighters should be equipped with protective clothing & self-contained breathing apparatus to protect against potentially toxic & irritating fumes. In case of fire or explosion, keep unnecessary people away. Isolate hazard area & any entry. Stay upwind, out of low areas, and ventilate closed spaces before entering. ADDITIONAL INFORMATION........Avoid dusting conditions. May form explosive dust mixtures with air. 6. SPILL OR LEAK PROCEDURES IN CASE MATERIAL IS RELEASED/SPILLED: Avoid formation and deposition of dust. Do not empty into drains or waters. Do not touch or walk through the spilled material: stop leak if you can do it without risk. Take up with sand or other non-combustible absorbent material or suitable vacuum and place into labeled sealable containers. For further disposal measures see section 13. 7. SPECIAL PRECAUTIONS AND STORAGE DATA SAFE HANDLING: In accord with good industrial practice. Handle with care and avoid personal contact. PRODUCT: JACQUARD ACID DYE #628 8. EMPLOYEE PROTECTION RECOMMENDATIONS GENERAL PROTECTNE MEASURES: Do not breathe dust. Avoid contact with eyes and skin. Immediately remove all contaminated clothing. EYE PROTECTION .......... Employees should wear protective eye-goggles with side protection shield. SKIN PROTECTION ........ Employees should avoid skin contact by wearing protective clothing. Long sleeve shirts, pants, gloves e.g. of PVC or nitrile rubber, and boots are recommended. Additional protections such as impervious suits are recommended when the potential for dermal contact is significant. Employees should wash their hands and face before eating and drinking and shower thoroughly before leaving work. Keep away from food and drink stuffs. RESPIRATORY PROTECTION .................Inhalation of dust and aerosols must be absolutely prevented by the use of a NIOSH approved dust respirator. VENTILATION ..................... Use local ventilation. OTHER .............................. Wear overalls, apron or other protective clothing. 9. PHYSICAL DATA APPEARANCE ............................. POWDER COLOR ..................................... DARK GREEN ODOR ........................................... NONE ODOR THRESHOLD ................. NA SOLUBILITY IN WATER ...... 35 - 40 g/1 @ 100 C BULK DENSITY ......................... ND VISCOSITY .................................. NA pH ............................................. 6 - 7 @ 10 g/1 at 20C MELTING POINT/FREEZING POINT ....... NA PARTITION COEFFICIENT: N-OCTANOL/WATER ................ ND BOILING POINT ................................NA VAPOR PRESSURE ........................ NA VAPOR DENSITY ........................... NA EVAPORATION RATE ................... NA FLAMMABILITY .......................... NA FLASH POINT ............................... NA INGINITION TEMP ....................... NA DECOMPOSITION TEMPERATURE ......... ND UEL................................................NA LEL ................................................ NA %VOLATILE: VALUE: 0.00 UNIT: % COMMENT: PRODUCT: JACQUARD ACID DYE #628 10. REACTIVITYDATA THERMAL DECOMPOSITION: No thermal decomposition when stored and handled correctly. HAZARDOUS REACTIONS: None expected CHEMICAL STABILITY .........................................Stable INCOMPATABLE MATERIALS: None HAZARDOUS DECOMPOSITION PRODUCTS ............. C02, CO, SULFUR OXIDES, NITROGEN OXIDES CONDITIONS TO AVOID................... Avoid dusting conditions and sparks/flame. HAZARDOUS POLYMERIZATION ......... Will not occur 11. TOXICOLOGICAL DATA ANIMAL TOXICITY ORAL - LD50 (INGESTION) ........ > 5000 mg/kg (Rat) FISH, LC50.......................................................................... 100-500 mg/1 (48 hour Rainbow Trout) EYE EFFECTS .................................................................... SLIGHT-IRRITANT (RABBIT EYE) SKIN EFFECTS ................................................................. NON-IRRITANT (RABBIT) SENSITIZATION ...................................................................... NOT EXPECTED 12. ECOLOGICAL DATA BIODEGRADABILITY: 25-50% (TOC) BACTERIA TOXICITY IC %: > 1000 mg/1 (activated sludge) 13. DISPOSAL CONSIDERATIONS PRODUCT:......... If utilization or recycling of the product is not possible, it should be disposed of in accordance with existing federal, state and local environmental regulations, e.g. by incineration in a suitable plant. UNCLEANED PACKAGING: Soiled, empty containers are to be treated in the same way as the contents. 14. SHIPPING DATA PROPER SHIPPING NAME: NON-HAZARDOUS INK MATERIAL D.O.T. HAZARD CLASSIFICATION: NOT REGULATED FRT. CLASS PACKAGE: 55 IATA (C,P): NON-REGULATED IMDG: NON-REGULATED PRODUCT: JACQUARD ACID DYE #628 15. REGULATORY DATA US REGULATIONS: TSCA: The components of this product are listed on the TSCA Inventory SARA 313: This product is not subject to SARA Title III Section 313 reporting requirements under 40 CFR 372. SARA 312: Immediate (acute) health hazard Yes Delayed (chronic) health hazard No Fire hazard No Sudden Release of Pressure No Reactivity No This product is not subject to the German Ordinance that bans certain azo dyes or the 19 th Amendment of the Council Directive 76/769/EEC.

Further information

Rupert, Gibbon & Spider, Inc. warrants that this product conforms to the chemical description on the label and is reasonably fit for the specific purposes referred to in its directions for use, subject to the inherent risks referred to in the material safety data sheet for this product. Rupert, Gibbon & Spider, Inc. makes no other expressed or implied warranty of fitness or merchantability or any other expressed or implied warranty. In no case shall Rupert, Gibbon & Spider, Inc. be liable for consequential, special, or indirect damages resulting from the use or handling of this product. PRODUCT: JACQUARD ACID DYE #628 01288-4220 SAFETY DATA SHEET Issue date 4/26/23 Revision Date: 3/11/24 1. PRODUCT IDENTIFICATION PRODUCT NAME: Jacquard Acid Dye Fluorescent Yellow PRODUCT CODE NUMBER: 640 CHEMICAL FAMILY: Aminoketone T.S.C.A. STATUS: Complies RECOMMENDED PRODUCT USE: Textile Dyeing MANUFACTURED BY: Jacquard Products Manufactured by Rupert, Gibbon & Spider, Inc. P.O. Box 425 | Healdsburg, CA 95448 800. 442.0455 | Fax: 707.433.4906 www.jacquardproducts.com EMERGENCY PHONE NUMBER: Chemtrec 1-800-424-9300

2.1 Classification of the substance or mixture

Pictogram: Signal Word: Warning Hazard Statements: H341: Suspected of Causing Genetic Defects