General Information
Version
0.53
Revision date
2023-09-12
Product name
RS Matt Black Spray Paint
1.2.1 Relevant identified uses
Paint
supplier name
RS Components Ltd
Emergency telephone
44 1235 239670, +44 (0) 1865 407333, +353 (0)1 809 2166
Icons in SDS
Company Information
company name
RS Components Ltd
e-mail address of the competent person responsible for the Safety Data Sheet
RCustomerServicesUK@rs-components.com, enquiries.ie@rs-components.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H220, H222, H225, H226, H229, H304, H312, H315, H319, H332, H335, H336, H373, H412
Hazard statements
Code
Statements
H220
Extremely flammable gas
Section 2
SECTION 2: Hazards identification
Regulation (EC) No. 1272/2008 [CLP]] Classification of the substance or mixture Classification according to
2.2 Label elements
;
Contains
Acetone, xylene, 1-Methoxy-2-propanol, butanone
Signal word
Danger
Hazard statements
H222 - Extremely flammable aerosol H229 - Pressurised container: May burst if heated H319 - Causes serious eye irritation H336 - May cause drowsiness or dizziness EUHO066 - Repeated exposure may cause skin dryness or cracking see section 16 Acute Toxicity Estimate ee Chesnical name. = ied wee mang Dermal.LD§0 _|° Inhalation LC50- 4 © ~ Inhalation LC50 - 4 Inhalation t LC50. 2 ‘f 718 28 mg/kg “28 |hour ~ dust/mist - mg/L.| hour = vapour = mg/L~| “ hour - gas = ppi Acetone “5800 15700 100.2 No data available 67-64-14 . xylene 3500 4350 No data available 1330-20-7 2-Methoxy-1-methylethyl 8532 5000 24 No data available acetate 108-65-6 butanone 2483 5000 No data available 34.5018 No data available 78-93-3 1-Methoxy-2-propanol 5000 13000 No data available 34.1234 No data available 107-98-2 This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No.
Precautionary statements
- EU (§28, 1272/2008) P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P211 - Do not spray on an open flame or other ignition source. - P251 - Do not pierce or burn, even after use. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P304.+ P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. ; P410 + P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. P501 - Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable.
2.3 Other hazards
This mixture contains no substance considered to be persistent, bioaccumulating or toxic (PBT). This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB). Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors. 3.1 Substances Not applicable 3.2 Mixtures "]weight-%| = “REACH registration | EC No (EU [Classification according] :** Specific ~ «| M-Factor. |’ _ Index No}, to Regulation (EC). No. “concentration ll 4272/2008 [CLP]: | limit (SCE). é Petroleum gases, | 30-60 | No data available | 270-704-2 | Flam, Gas 1A (H220) - aa liquefied 68476-85-7 Acetone 30-60 |01-2119471330-49-00| 200-662-2 | Eye Irrit. 2 (H319) - 67-64-1 00 STOT SE 3 (H336) Flam. Lig. 2 (H225) xylene 5-10 |01-2119488216-32-00| 215-535-7 | Aquatic Chronic 3 - 1330-20-7 00 _(H412) Asp. Tox. 1 (H304) Flam. Liq. 3 (H226) Acute Tox. 4 (H332) STOT RE 2 (H373) Eye Irrit. 2 (H319) Skin Irrit. 2 (H315) Acute Tox. 4 (H312) STOT SE 3 (H335) 2-Methoxy-1-methyl| 5-10 |01-2119475791-29-00| 203-603-9 | Flam. Lig. 3 (H226) - ethyl acetate 00 108-65-6 butanone 1-5 |01-2119457290-43-00| 201-159-0 | Eye Irrit. 2 (H319) - 78-93-3 00 STOT SE 3 (H336) Flam. Lig. 2 (H225) 1-Methoxy-2-propan| 1-5 |01-2119457435-35-00| 203-539-1 | Flam. Lig. 3 (H226) - . - ol 00 STOT SE 3 (H336) 107-98-2
Further information
Ventilate the area. Refer to protective measures listed in Sections 7 and 8. For emergency responders Use personal protection recommended in Section 8. 6.2. Environmental precautions Environmental precautions Refer to protective measures listed in Sections 7 and 8. Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. 6.3. Methods and material for containment and cleaning up Methods for containment Keep out of drains, sewers, ditches and waterways. Stop leak if you can do it without risk. A vapour suppressing foam may be used to reduce vapours, Dyke far ahead of spill to collect run-off water. Flood with water to complete polymerization and scrape off floor. Methods for cleaning up Take precautionary measures against static discharges. Dam up. Soak up with inert absorbent material. Pick up and transfer to properly labelled containers. ; Prevention of secondary hazards —_ Clean contaminated objects and areas thoroughly observing environmental regulations. 6.4. Reference to other sections Reference to other sections See section 8 for more information. See section 13 for more information. ISECTION 7 Handling and storage" 7.1, Precautions for safe handling Advice on safe handling Use personal protection equipment. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). Use spark-proof tools and explosion-proof equipment. Handle product only in closed system or provide appropriate exhaust ventilation. Keep in an area equipped with sprinklers, Do not puncture or incinerate cans. Contents under pressure. In case of rupture. Avoid breathing vapours or mists. Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product. In case of insufficient ventilation, wear suitable respiratory equipment. General hygiene considerations Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Regular cleaning of equipment, work area and clothing is recommended. Wash hands before breaks and immediately after handling the product. Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection. 7.2. Conditions for safe storage, including any incompatibilities
Storage
Conditions -Protect from sunlight. Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Keep in properly labelled containers. Do not store near combustible materials. Keep in an area equipped with sprinklers. Store in accordance with the particular national regulations. Store in accordance with local regulations. Store in a cool, dry area away from potential sources of heat, open flames, sunlight or other chemicals. Keep out of the reach of children. 7.3. Specific end use(s) Risk Management Methods (RMM) The information required is contained in this Safety Data Sheet. [SECTION 8: Exposure 'controls/personal protection 8.1. Control parameters Exposure Limits This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Chemical name ~ Bulgaria “European Union|: “.” Austria: | “Croatia Pale, <> |>" > Belgium? "| °° Acetone TWA: 500 ppm TWA: 246 ppm | STEL: 1400 mg/m$| TWA: 500 ppm 67-64-14 TWA 1210 mg/m3 | TWA 1200 mg/m’ | TWA 594 mg/m? | TWA: 600.mg/m? | TWA: 1210 mg/m STEL 2000 ppm STEL: 492 ppm STEL 4800 mg/m? | STEL: 1187 ma/m* Petroleum gases, - TWA: 1000 ppm - TWA: 1000 ppm - liquefied TWA: 1826 mg/ms TWA: 1750 mg/m’ 68476-85-7 STEL: 1250 ppm STEL: 2180 ma/ms 2-Methoxy-1-methylethy! TWA: 50 ppm STEL: 100 ppm TWA: 50 ppm acetate TWA: 275 mg/m? | TWA: 275 mg/m3 | TWA: 275 mg/m? |STEL: 550.0 mg/m?| TWA: 275 mg/m$ 108-65-6 ' STEL: 100 ppm STEL 100 ppm STEL: 100 ppm TWA: 50 ppm STEL: 100 ppm STEL: 550 mg/m? | STEL 550 mg/m? STEL 550 mg/m? | TWA 275.0 mg/m? | STEL 550 mg/mé * H* D* K* * xylene TWA: 50 ppm STEL: 100 ppm TWA: 50 ppm 1330-20-7 TWA; 221 mg/m? | TWA: 221 mg/m3 | TWA: 221 mg/m? | STEL: 442 mg/m? | TWA: 221 mg/m STEL: 100 ppm STEL 100 ppm STEL: 100 ppm TWA: 50 ppm STEL: 100 ppm STEL: 442 mg/m? | STEL 442 mg/m? STEL 442 mg/m® | TWA 221.0 mg/m | STEL 442 mg/m * D* K* * butanone TWA: 200 ppm TWA: 100 ppm TWA: 200 ppm | | STEL: 885 mg/m* TWA: 200 ppm 78-93-3 TWA: 600 mg/m? | TWA: 295 mg/m? | TWA: 600 mg/m? | TWA: 590 mg/m? | TWA: 600 mg/m? STEL: 300 ppm STEL 200 ppm STEL: 300 ppm STEL: 900 mg/m? | STEL 590 mg/m? | STEL: 900 mg/m? STEL: 900 mg/m? H* 4-Methoxy-2-propanol TWA: 100 ppm ' TWA: 50 ppm TWA: 50 ppm STEL: 150 ppm TWA: 100 ppm 107-98-2 TWA: 375 mg/m? | TWA: 187 mg/m? | TWA: 184 mg/m? |STEL: 568.0 mg/m’| TWA: 375 mg/m? STEL: 150 ppm STEL 50 ppm STEL;: 100 ppm TWA: 100 ppm STEL: 150 ppm STEL: 568 mg/m? | STEL 187 mg/m? | STEL: 369 mg/m? TWA 375.0 mg/m? | STEL 568 mg/m® id Ceiling: 50 ppm D* K* Ceiling: 187 mg/m? H* ; “2 Chemical name® = | =" "Cyprus: ©. ‘|** Czech Republic = |<" Denmark” |." Estonia’ | ° 0 Finland: 1 Page 6/21 Acetone * TWA: 800 mg/ms TWA: 250 ppm TWA: 500 ppm 67-64-1 TWA: 500 ppm Ceiling: 1500 mg/m? TWA: 600 mg/m? TWA: 1210 mg/m? TWA: 1200 mg/m’ TWA: 1210 mg/m? STEL: 500 ppm STEL: 630 ppm . STEL: 1200 ma/m3 STEL: 1500 mg/m? Petroleum gases, TWA: 1800 mg/m liquefied Ceiling: 4000 mg/m? 68476-85-7 2-Methoxy-1-methylethy! * TWA: 270 mg/m* “TWA: 50 ppm S+ TWA: 50 ppm acetate STEL: 100 ppm _ | Ceiling 550 mg/m? | TWA 275 mg/m TWA: 50 ppm TWA: 270 mg/m$ 108-65-6 STEL: 550 mg/m? D* H* TWA: 275 mg/m? STEL: 100 ppm TWA: 50 ppm STEL: 550 mg/m? | STEL: 100 ppm | STEL: 550 mg/m* TWA: 275 mg/m STEL: 100 ppm | STEL: 550 mg/m? ino* A xylene is TWA: 200 mg/ms TWA: 25 ppm TWA: 50 ppm 1330-20-7 STEL 100 ppm _| Ceiling 400 mg/m3 | TWA 109 mg/m? | TWA: 200 mg/m’ | TWA: 220 mg/m STEL: 442 mg/m D* H* STEL: 100 ppm TWA: 50 ppm STEL: 442 mg/m? STEL 450 mg/m? | STEL 440 mg/m? TWA: 221 mg/ms STEL: 100 ppm A* iho* butanone STEL: 300 ppm. | TWA: 600 mg/ms TWA: 50 ppm TWA: 200 ppm TWA: 20 ppm 78-93-3 STEL 900 mg/m? | Ceiling 900 mg/m | TWA 145 mg/m? | TWA 600 mg/m? TWA: 60 mg/m? TWA: 200 ppm H* STEL: 300 ppm STEL: 100 ppm TWA: 600 mg/m* STEL: 900 mg/m? STEL: 300 mg/m? STEL: 300 ppm iho* 1-Methoxy-2-propanol * TWA: 270 mg/m TWA: 50 ppm S+ TWA: 100 ppm 107-98-2 STEL 150 ppm __| Ceiling 550 mg/m* | TWA 185 mg/m? TWA: 100 ppm TWA: 370 mg/m? STEL: 568 mg/m? D* H* TWA: 375 mg/m? STEL: 150 ppm TWA: 100 ppm STEL 568 mg/m? | STEL 150 ppm | STEL: 560 mg/m TWA: 375 mg/m STEL: 150 ppm. | STEL: 568 mg/m? iho* A* “ea Chemical name: oe, Frances. | Germany: TRGS «|: Germany DFG. - |=... < Greece’ <2. |2. Hungary a0 Acetone TWA: 500 ppm TWA 500 ppm =| TWA 1780 mg/m TWA: 500 ppm 67-64-1 TWA 1210 rng/m? | TWA 1200 mg/m? | TWA 1200 mg/m? | STEL 3560 mg/m’ | TWA 1210 mg/m? STEL: 1000 ppm Peak: 1000 ppm STEL: 2420 mg/m> Peak: 2400 mg/m$ Petroleum gases, TWA: 1250 ppm liquefied TWA: 2250 mg/m* 68476-85-7 STEL: 1250 ppm STEL: 2250 mg/m? 2-Methoxy-1-methylethyt TWA: 50 ppm TWA: 275 mg/m acetate TWA: 275 mg/m? | TWA: 270 mg/m? | TWA: 275 mg/m> TWA: 50 ppm 108-65-6 STEL: 100 ppm Peak: 50 ppm STEL: 100 ppm STEL: 550 mg/m? Peak: 270 mg/m? STEL 550 mg/m? | STEL 100 ppm xylene. TWA: 50 ppm TWA: 100 ppm TWA: 221 mg/ms 1330-20-7 TWA: 221 mg/m? | TWA: 220 mg/m? | TWA: 435 mg/m TWA: 50 ppm STEL: 100 ppm H* Peak: 100 ppm STEL: 150 ppm STEL: 442 mg/m* STEL: 442 mg/m? Peak 440 mg/m? | STEL 650 mg/m? | STEL 100 ppm * i b* . butanone TWA: 200 ppm TWA: 200-ppm TWA: 200 ppm TWA: 600 mg/m? 78-93-3 TWA: 600 mg/m? | TWA: 600 mg/m? | TWA: 600 mg/m TWA: 200 ppm STEL: 300 ppm H* Peak: 200 ppm STEL: 300 ppm | STEL: 900 mg/m? STEL: 900 mg/m? Peak: 600 mg/m? STEL 900 mg/m? | STEL 300 ppm * . * b* 1-Methoxy-2-propanol |. TWA: 50 ppm TWA: 100 ppm TWA: 375 mg/m? 107-98-2 TWA: 188 mg/m? TWA: 370 mg/m TWA: 370 mg/m* TWA: 360 mg/m? TWA: 100 ppm STEL: 100 ppm Peak: 200 ppm STEL: 300 ppm. STEL: 568 mg/m? STEL: 375 mg/m Peak: 740 mg/m? STEL: 1080 mg/m? STEL: 150 ppm b* en Chemical name. as/ sate freland os hotttaly MDLPS «- - ce ttaly AIDH 2] # Lithuania ioe aay Page 7/21 Acetone > TWA: 500 ppm- TWA: 500 ppm TWA: 250 ppm TWA: 500 ppm STEL: 1000 ppm 67-64-1 TWA: 1210 mg/m? TWA: 1210 mg/m3 TWA: 594 mg/m? TWA: 1210 mg/m? STEL: 2420 mg/m® STEL: 1500 ppm STEL: 500 ppm TWA: 500 ppm STEL: 3630 ma/m? STEL: 1187 mg/m% TWA: 1210 mg/m? Petroleum gases, liquefied Simple asphyxiant 68476-85-7 2-Methoxy-1-methylethyl| TWA: 50 ppm ~ TWA: 50 ppm STEL: 75 ppm acetate TWA: 275 mg/m? | TWA: 275 mg/ms TWA: 275 mg/m? | STEL: 400 mg/m$ 108-65-6 STEL: 100 ppm TWA: 50 ppm STEL: 550 mg/m? | STEL: 550 mg/m? STEL: 550 mg/m? | TWA: 250 mg/m. Sk* cute* Ada* O* xylene TWA: 50 ppm TWA: 100 ppm TWA: 50 ppm STEL: 442 mg/m? 1330-20-7 TWA: 221 mg/m? | TWA: 221 mg/m? | TWA: 434 mg/m® | TWA: 221 mg/m STEL: 100 ppm STEL: 150 ppm STEL: 100 ppm TWA: 221 mg/m? STEL 442 mg/m? | STEL 442 mg/m’ STEL 651 mg/m? | STEL 442 mg/m TWA: 50 ppm Sk* cute* Ada* o* butanone TWA: 200 ppm TWA: 67 ppm ‘s 78-93-3 TWA: 600 mg/m? | TWA: 600 mg/m’ | TWA: 590 mg/m? | TWA: 200 mg/m? STEL: 300 ppm STEL: 900 mg/m? STEL: 885 mg/m? STEL: 900 mg/m? Skt 1-Methoxy-2-propanol TWA 100 ppm TWA: 100 ppm TWA: 50 ppm TWA: 100 ppm STEL: 300 mg/m* 107-98-2 TWA: 375 mg/m? | TWA: 375 mg/m? | TWA: 184 mg/m? | TWA: 375 mg/m STEL: 75 ppm STEL: 150 ppm STEL: 100 ppm STEL: 150 ppm. TWA: 190 mg/m? STEL 568 mg/m’ | STEL 568 mg/m’ | STEL 368 mg/m*® | STEL: 568 mg/m TWA: 50 ppm cute* Ada* O* Chemical. name: > Luxembourg |: Malta. | > Netherlands = Norway 8s. 2 Poland. Acetone TWA: 500 ppm TWA: 125 ppm | STEL: 1800 mg/m# 67-64-1 TWA .1210 mg/m? | TWA 1210 mg/m? | TWA 1210 mg/m? | TWA 295 mg/m? | TWA 600 mg/m STEL: 1 ppm STEL: 156.25 ppm STEL 2420 mg/m? |STEL 368.75 mg/m? 2-Methoxy-1-methylethyl| STEL: 100 ppm TWA: 100 ppm TWA: 50 ppm STEL: 520 mg/m? acetate STEL 550 mg/m3 | STEL 550 mg/m? | TWA 550 mg/m? TWA 270 mg/m*® | TWA 260 mg/m 108-65-6 TWA: 50 ppm skin* STEL: 75 ppm sk6ra* TWA: 275 mg/ms TWA: 50 ppm STEL: 337.5 mg/ms Peau* TWA: 275 mg/ms H* xylene STEL: 100 ppm TWA: 47.5 ppm TWA: 25 ppm STEL: 200 mg/mé 1330-20-7 STEL 442 mg/m | STEL 442 mg/m’ | TWA 210 mg/m? TWA 108 mg/m? | TWA 100 mg/m? TWA: 50 ppm skin* STEL: 100 ppm STEL: 37.5 ppm skéra* TWA: 221 mg/m’ TWA: 50 ppm STEL: 442 mg/m? | STEL: 135 mg/m? Peau* TWA: 221 mg/ms H* butanone STEL: 300 ppm TWA: 197 ppm TWA: 75 ppm STEL: 900 mg/ms 78-93-3 STEL: 900 mg/m? STEL 900 mg/m? | TWA 590 mg/m? | TWA: 220 mg/m? | TWA: 450 mg/m? TWA: 200 ppm STEL: 300 ppm STEL: 112.5 ppm ‘skora* TWA: 600.mg/m3 TWA: 600 mg/m? STEL: 900 mg/m? STEL: 275 mg/m? H* 1-Methoxy-2-propanol STEL: 150 ppm TWA: 100 ppm TWA: 50 ppm STEL: 360 mg/m* 107-98-2 STEL 568 mg/m? | STEL 568 mg/m? | TWA 375 mg/m? | TWA: 180 mg/m? | TWA: 180 mg/m TWA: 100 ppm skin* STEL: 150 ppm STEL: 75 ppm skora* TWA: 375 mg/m TWA: 100 ppm STEL 563 mg/m? | STEL 225 mg/m Peau* TWA: 375 mg/m’ H* Chemical name = Portugal]. Romania]. Slovakia 2... | Slovenia. |. Spain.) os. Acetone TWA: 500 ppm 67-64-1 TWA 1210 mg/m | TWA 1210 mg/m? | TWA 1210 mg/m? | TWA 1210 mg/m | TWA 1210 mg/m STEL: 750 ppm STEL: 2420 mg/m? STEL: 1000 ppm Petroleum gases, TWA: 1000 ppm “liquefied _. Page 8/21 68476-85-7 2-Methoxy-1-methylethyl| TWA: 50 ppm acetate TWA: 275 mg/m? | TWA: 275 mg/m? TWA 275 mg/m3 | TWA 275 mg/m? 108-65-6 STEL: 100 ppm K* STEL: 100 ppm STEL 550 mg/m? | STEL 550 mg/m? | Ceiling 550 mg/m? | STEL 550 mg/m? | STEL: 550 mg/m? Cutanea* P* K* via dérmica* xylene TWA: 50 ppm 1330-20-7 TWA: 221 mg/m? | TWA: 221. mg/m? | TWA: 221 mg/m? STEL: 100 ppm K* STEL: 100 ppm STEL: 442 mg/m? | STEL: 442 mg/m? Ceiling 442 mg/m? | STEL 442 mg/m* | STEL 442 mg/m Cutaénea* p* kK* via dérmica* butanone TWA: 200 ppm - 78-93-3 TWA: 600 mg/m? | TWA: 600 mg/m? TWA 600 mg/m? | TWA 600 mg/m? STEL: 300 ppm STEL 300 ppm | Ceiling 900 mg/m? | STEL 300 ppm STEL: 300 ppm STEL 900 mg/m? | STEL 900 mg/m? STEL 900 mg/m? | STEL 900 mg/m K* 1-Methoxy-2-propanol TWA: 100 ppm TWA; 100 ppm TWA: 100 ppm 107-98-2 TWA: 375 mg/m? | TWA: 375 mg/m? TWA 375 mg/m? | TWA 375 mg/m? STEL: 150 ppm K* STEL: 150 ppm STEL: 568 mg/m? STEL 568 mg/m? | Ceiling 568 mg/m? | STEL 568 mg/m? | STEL 568 mg/m? P* K* via dérmica* aca. Chemical name eos | Sweden --< cai ~_iv Switzerland. _United Kingdom." Acetone Vagledande KGV: 500 ppm TWA; 500 ppm TWA: 500 ppm 67-64-1 Vagledande KGV: 1200 mg/m* TWA: 1200 mg/ms TWA: 1210 mg/m? NGV: 250 ppm STEL: 1000 ppm STEL: 1500 ppm NGV: 600 mg/ms STEL: 2400 mg/m? STEL: 3620 ma/ms Petroleum gases, liquefied - TWA: 1000 ppm 68476-85-7 TWA: 1750 mg/m? STEL: 1250 ppm STEL: 2186 mg/m? 2-Methoxy-1-methylethy! acetate) | Bindande KGV: 100 ppm TWA: 50 ppm 108-65-6 Bindande KGV: 550 mg/m$ TWA: 275 mg/m? TWA: 274 mg/m3 NGV: 50 ppm STEL: 50 ppm STEL: 100 ppm NGV: 275 mg/m? STEL: 275 mg/ms STEL: 548 mg/m? H* . Sk* xylene Bindande KGV: 100 ppm TWA: 50 ppm 1330-20-7 Bindande KGV: 442 mg/m® TWA: 220 mg/m? NGV: 50 ppm STEL: 100 ppm NGV: 221 mg/mé STEL: 440 mg/m STEL: 441 mg/m3 H* . H* Sk* butanone Bindande KGV: 300 ppm TWA: 200 ppm 78-93-3 Bindande KGV: 900 mg/m$ TWA: 590 mg/m? TWA: 600 mg/m* NGV: 50 ppm STEL: 200 ppm STEL: 300 ppm NGV: 150 mg/m? STEL: 590 mg/m’ STEL: 899 mg/m? ‘ H* Sk* 1-Methoxy-2-propanol Bindande KGV: 150 ppm TWA: 100 ppm 107-98-2 Bindande KGV: 568 mg/m? TWA: 360 mg/ms TWA: 375 mg/m? NGV: 50 ppm STEL: 200 ppm STEL: 150 ppm NGV: 190 mg/m? STEL: 720 mg/m? STEL: 560 mg/m$ H* Sk* Biological occupational exposure This product, as supplied, does not contain any hazardous materials with biological limits limits established by the region specific regulatory bodies. Chemical name--..- ares Bulgaria. European Union oot. Austria cy: woos: Croatia 5: . Czech Republic: . bas Acetone - 80 mg/L - urine 20.0 mg/L - blood - 67-64-4 (Acetone) - atthe | (Acetone) - at the end of exposure or |end of the work shift end of work shift [20.0 mg/g Creatinine Page 9/21 - urine (Acetone) - al the end of the work shift ; xylene - 1.5 g/L (urine - 1.50 mg/L - blood 820 umol/mmol 1330-20-7 Methylhippuric acid (Xylene) - at the end| Creatinine (urine - after end of work of the work shift | Methyihippuric acid day, at the end of a 1.50 g/g Creatinine - end of shift) work week/end of urine (Methylhippuric 1400 mg/g the shift) acid) - at the end of| Creatinine (urine - the work shift Methylhippuric acid end of shift) butanone - - 2.6 mg/g Creatinine - - 78-93-3 urine (Ethyl methyl ketone} - at the end of the work shift * Chemical name = Denmark: _ Finland " 2oFrance.i« | Germany DFG: | Germany TRGS Acetone - 100 mg/L - urine 80 mo/L (urine - 80 mg/L (urine - 67-64-1 (Acetone) ~ end of [Acetone end of shift)|Acetone end of shift shift 50 mg/L - BAT (end of exposure or end of shift) urine 2.5 mg/L - BAR (end of exposure or end of shift) urine xylene - 5.0 mmol/L (urine - [1500 mg/g creatinine] 2000 mg/L (urine - | 2000 mg/L (urine - 1330-20-7 Methylhippuric acid - urine , Methythippuric(tolur-/Methylhippuric(tolur- after the shift) | |(Methythippuric acid)| )acid (all isomers) | Jacid (all isomers) ~ end of shift end of shift) 2000 mg/L - BAT (end of exposure or end of-.shift) urine butanone - 2 mg/L - urine 2 mg/L (urine - 78-93-3 (Methylethylketone) -| 2-Butanone end of | 2-Butanone end of end of shift shift) 2 mg/L - BAT (end of exposure or end of shift) urine 1-Methoxy-2-propanol - 15 mg/L (urine - 15 mo/L (urine - 107-98-2 ; 4-Methoxypropan-2-| 1-Methoxypropan-2- ol end of shift) 15 mg/L - BAT (end of exposure or end of shift) urine Chemical name Hungary “treland~. _ltaly MDLPS °° -. Italy AIDIT: <-> Acetone - 50 mg/L (urine - Acetone - 25 mg/L - urine (Acetone) 67-64~1 end of shift) - end of shift xylene 1500 mg/g Creatinine {1.5 g/g Creatinine (urine - - 1.5 g/g Creatinine - urine 1330-20-7 (urine - Methyl hippuric | Methylhippuric acids end (Methylhippuric acid) ~ acid end of shift) of shift) end of shift 860 pmol/mmol Creatinine (urine - Methyl hippuric acid end of shift) butanone - 70 pmol/L (urine - 2 mg/L - urine (MEK) - 78-93-3 Butan-2-one post shift) end of shift “8 Chemical name 2" |) este Latvia oF oc Luxembourg eatualecRomanias “ate | 3s cs Slovakia = Acetone - 50 mg/L. - urine (Acetone) 80 mg/L (urine - Aceton 67-64-1 - end of shift end of exposure or work shift) xylene - 3 g/L - urine 1.5 mg/L (blood - Xylene Page 10/21 1330-20-7 (Methylhippuric acid) - | end of exposure or work __ end of shift shift) 2000 mg/L (urine - Methylhippuric acid end of exposure or work shift) butanone ~ - 2 mg/L - urine - 78-93-3 (Methylethy!ketone) - end of shift Chemical name Slovenia Spain i ~ Switzerland... |_|. United Kingdom Acetone 80.0 mg/L - urine 50 mg/L (urine - Acetone | 50 mg/L (urine - Acetone - 67-64-1 (Acetone) - at the end of end of shift) the work shift 0.86 mmol/L (urine - Acetone end of shift) xylene 2 g/L - urine 1 g/g Creatinine (urine - 2 g/L (urine - 650 mmol/mol creatinine - 1330-20-7 (Methylhipuric acid (all | Methylhippuric acids end |Methylhippuric acid end off urine (Methyl hippuric | isomers)) - at the end of of shift) shift) acid) ~ post shift the work shift butanone 2 mg/L - urine 2 mg/L (urine - Methyl 2 mg/L (urine - . 70 pmoi/L - urine 78-93-3 (2-Butanone).- at the end| ethyl ketone end of shift) | 2-Butanone end of shift, | (Butan-2-one) - post shift of the work shift before subsequent shift or 16 hour) 27.7 umol/L (urine - 2-Butanone end of shift, before subsequent shift or 16 hour) 1-Methoxy-2-propanol 15 mg/L - urine - * 20 mg/L (urine - 107-98-2 (1-Methoxypropan-2-ol) - {-Methoxypropanol-2 end at the end of the work of shift) , shift 221.9 umol/L (urine - 1-Methoxypropanol-2 end of shift) Derived No Effect Level (DNEL) - Workers “tere "Ss Chemicalinames Pre | eee hee rakes foes Dermal. oe "Inhalation Acetone - 186 mg/kg bw/day [4] [6] 1210 mg/m’ [4] [6] 67-64-1 2420 mg/m? [5] [7] Petroleum gases, liquefied - 23.4 mg/kg bw/day [4] [6] - 68476-85-7 2-Methoxy-1-methylethy! acetate - 796 mg/kg bw/day [4] [6] 275 mg/m® [4] [6] 108-65-6 550 ma/ms [5] [7] xylene - 212 mg/kg bw/day [4] [6] 221 mg/m? [4] [6] 1330-20-7 442 mg/mé [4] [7] 221 mg/m? [5] [6] 442 ma/m3 [5] [7] butanone - 1161 mg/kg bw/day [4] [6] 600 mg/ms [4] [6] 78-93-3 1-Methoxy-2-propanol - 183 mg/kg bw/day [4] [6] 369 mg/m [4] [6] 107-98-2 553.5 mg/m [4] [7] 553.5 mg/m [5] [7] Derived No Effect Level (DNEL) - General Public . Chemical name» Semone ee Dermab Inhalation: . Acetone 62 mg/kg bw/day [4] [6] 200 mg/m [4] [6] 67-64-1 Page 11/21 ". Chemicalname =] “Oral == Dermal" To inhalation 2-Methoxy-1-methylethyl acetate 36 OnE pwiday 4] 73 7] - 33 mg/mé [4] [6] 108-65-6 33 mg/m? [5] [6] xylene 12.5 mg/kg bw/day {4] [6] - 65.3 mg/m [4] [6] 1330-20-7 260 mg/m? [4] [7] 65.3 mg/m? [5] [6] 260 maim? [5] [7] butanone 31 mg/kg bw/day [4] [6] - 106 mg/m? [4] [6] 78-93-3 1-Methoxy-2-propanol 33 mg/kg bw/day [4] [6] - 43.9 mg/m: [4] [6] 107-98-2 Predicted No Effect Concentration (PNEC) . Freshwater ; c {intermittent release)| 25° finterraitient release): Acetone 10.6 mg/L 21 mg/L 1.06 mg/L - 67-64-1 2-Methoxy-1-methylethyl 0.635 mg/L 6.35 mg/L 0.0635 mg/L - acetate 108-65-6 xylene 0.327 mg/L - 1330-20-7 butanone 55.8 mg/L 55.8 mo/L 55.8 mg/L - 78-93-3 _1-Methoxy-2-propanol 10 mg/L 100 mg/L 1 mg/L - 107-98-2 at yehetel cal name ab: blest eMaliys sediment . See treatment | eee “Food chain: « Sue we dees pio. sediment Ia 2 [es ap sranal Wee i ee Sacatane 30.4 mg/kg 3. 04 mak 100 mgt 29, 5 mak zane aw - 67-64-1 sediment dw 2-Methoxy-1-methylethyl 3.29 mg/kg 0.329 mg/kg 100 mg/L 0.29 mg/kg soil dw - acetate sediment dw 108-65-6 xylene 12.46 mg/kg 6.58 mg/L 2.31 mg/kg soil dw - 1330-20-7 sediment dw butanone 284.74 mg/kg 284.7 mg/kg 709 mg/L 22.5 mg/kg soil dw} 1000 mg/kg food 78-93-3 sediment dw 4{-Methoxy-2-propanol 52.3 mg/kg 5.2 mg/kg sediment 100 mg/L 4.59 mg/kg soil dw - 107-98-2 sediment dw dw 8.2. Exposure controls Engineering controls Ensure adequate ventilation, especially in confined areas. Personal protective equipment Eye/face protection Tight sealing safety goggles. Safety glasses with side shields are recommended for medical or industrial exposures. Hand protection impervious gloves. Wear suitable gloves. Page 12/21 Skin and body protection Wear suitable protective clothing. Long sleeved clothing. Chemical resistant apron. Antistatic boois. Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. General hygiene considerations Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Regular cleaning of equipment, work area and clothing is recommended. Wash hands before breaks and immediately after handling the product. Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection. Environmental exposure controls —_No information available. — SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Aerosol Appearance Aerosol Colour black Odour Solvent. Odour threshold No information available Property Values
Remarks
» Method Melting point / freezing point No daia available None known Initial boiling point and boiling range-41°C 143. °C None known Flammability No data available None known Flammability Limit in Air None known Upper flammability or explosive No data available limits Lower flammability or explosive No data available limits Flash point -40 °C None known Autoignition temperature 270 °C None known Decomposition temperature None known pH No data available None known pH (as aqueous solution) No data available None known Kinematic viscosity No data available None known Dynamic viscosity No data available None known Water solubility Insoluble in water None known Solubility(ies) No data available None known Partition coefficient No data available None known Vapour pressure No data available None known Relative density No data available None known Bulk density 0.728 kg/l Liquid Density No data available Relative vapour density No data available None known Particle characteristics Particle Size No information available Particle Size Distribution No information available 9.2, Other information 9.2.1. Information with regards to physical hazard classes Explosive properties Not considered to be explosive. Oxidising properties Does not meet the criteria for classification as oxidizing. Page 13/21 9.2.2. Other safety characteristics No information available ISECTION 10: Stability and reactivity 10.1. Reactivity Reactivity No information available. 410.2, Chemical stability Stability Stable under normal conditions. Explosion data Sensitivity to mechanical impact None. Sensitivity to static discharge Yes. 10.3. Possibility of hazardous reactions Possibility of hazardous reactions None under normal processing. 10.4. Conditions to avoid Conditions to avoid Heat, flames and sparks. Excessive heat. 10.5. Incompatible materials Incompatible materials None known based on information supplied. 10.6. Hazardous decomposition products Hazardous decomposition products None known based on information supplied. [SECTION 11: Toxicological information 11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008 Information on likely routes of exposure Product Information Inhalation intentional misuse by deliberately concentrating and inhaling contents may be harrnful or fatal. Specific test data for the substance or mixture is not available. May cause irritation of respiratory tract. May cause drowsiness or dizziness. Harmful by inhalation. (based on: components). Eye contact Specific test data for the substance or mixture is not available. Causes serious eye irritation. (based on components). May cause redness, itching, and pain. Skin contact Specific test data for the substance or mixture is not available. May cause irritation. Prolonged contact may cause redness and irritation. Causes mild skin irritation. Ingestion Specific test data for the substance or mixture is not available. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea. Symptoms related to the physical, chemical and toxicological characteristics Symptoms May cause redness and tearing of the eyes. Inhalation of high vapour concentrations may Page 14/21 cause symptoms like headache, dizziness, tiredness, nausea and vomiting. Prolonged contact may cause redness and irritation. Coughing and/ or wheezing. Acute toxicity Numerical measures of toxicity No information available The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 5,689.20 mg/kg ATEmix (dermal) 5,965.20 mg/kg ATEmix (inhalation-gas) 60,000.00 ppm ATEmix (inhalation-vapour) 146.6667 mg/l. ATEmix (inhalation-dust/mist) 20.00 mg/l é.Chemical name ™ =<. Oral LD50-3 [228 Dermal LD50 Fn fer inhalation LC50.6" 7" Acetone = 5800 mg/kg (Rat) > 15700 mg/kg ( Rabbit ) = 50100 mg/m? (Rat)8h xylene = 3500 mg/kg (Rat) > 4350 mg/kg ( Rabbit ) = 29.08 mg/L (Rat)4h SMathoxy-T-methylethyi acetate = 8532 mg/kg (Rat) >5 g/kg (Rabbit ) = 16000 mg/m? (Rat)6h butanone = 2483 mg/kg (Rat) = 5000 mg/kg ( Rabbit ) =11700 ppm (Rat)4h 1-Methoxy-2-propanol = 5000 mg/kg (Rat) = 13 g/kg (Rabbit ) > 7559 ppm (Rat)6h Delayed and immediate effects as well as chronic effects from short and long-term exposure Skin corrosion/irritation Classification based on data available for ingredients. Causes mild skin irritation. Serious eye damageleye irritation Classification based on data available for ingredients. Causes serious eye irritation. Respiratory or skin sensitisation Based on available data, the classification criteria are not met. Germ cell mutagenicity Based on available data, the classification criteria are not met. Carcinogenicity Based on available data, the classification criteria are not met. Reproductive toxicity Based on available data, the classification criteria are not met. STOT - single exposure May cause drowsiness or dizziness. STOT - repeated exposure Based on available data, the classification criteria are not met. Aspiration hazard Based on available data, the classification criteria are not met. 11.2. Information on other hazards Page 15/21 11.2.1. Endocrine disrupting properties Endocrine disrupting properties The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/6085 at levels of 0.1% or higher. 11.2.2. Other information Other adverse effects No information available. SECTION 12: Ecological information” 12.1. Toxicity Ecotoxicity Chemical name « ‘Algae/aquatic plants‘ + Toxicity to ® ee ae ee ee a 2 |e Se epee ee “microorganisms. ate Males ital Ie Acetone LC50: 4.74 - 6.33mL/L EC50: 10294 - (96h, Oncorhynchus 17704mg/L (48h, Daphnia mykiss) ~ magna) LC50: 6210 - 8120mg/L EC50: 12600 - (96h, Pimephales 12700mg/L (48h, Daphnial promelas) magna) LC50: =8300mg/L (96h, Lepomis macrochirus) xylene EC50: =11mg/L (72h, LC50: =13.4mg/L (96h, EC50: =3.82mg/L (48h, Pseudokirchneriella Pimephales promelas) . water flea) subcapitata) LC50: 2.661 - 4.093mg/L LC50: =0.6mg/L (48h, (96h, Oncorhynchus Gammarus lacustris) mykiss) LC50: 13.5 - 17.3mg/L (96h, Oncorhynchus - mykiss) LCS50: 13.1 - 16.5mg/L (96h, Lepomis macrochirus) LC50: =19mg/L (96h, Lepomis macrochirus) LC50: 7.711 - 9.591mg/L (96h, Lepomis macrochirus) LC50: 23.53 - 29.97mg/L (96h, Pimephales’ promelas) LC50: =780mg/L (96h, Cyprinus carpio) LC50: >780mg/L (96h, Cyprinus carpio) LC50: 30.26 - 40.75mg/L (96h, Poecilia reticulata) 2-Methoxy-1-methylethy! LC50: =161mg/L (96h, EC50: >500mg/L (48h, acetate Pimephales promelas) Daphnia magna) butanone LC50: 3130 - 3320mg/L EC50: >520mg/L (48h, (96h, Pimephales Daphnia magna) promelas) EC50; =5094mg/L (48h, Daphnia magna) EC50: 4025 - 6440mg/L (48h, Daphnia magna) Page 16/21 4-Methoxy-2-propanol - LC50: =20.8g/L (96h, - EC50: =23300mg/L (48h, Pimephales promelas) Daphnia magna) 12.2. Persistence and degradability Persistence and degradability No information available. 12.3. Bioaccumulative potential Bioaccumulation There is no data for this product. why nies 2 Chemical name -< i a ee “ce. Partition coefficient. ‘Petroleum gases, liquefied 2.8 Acetone -0.24 xylene 3.15 2-Methoxy-1-methylethyl acetate 1.2 ' butanone 0.3. 1-Methoxy-2-propanol 1 12.4. Mobility in soil Mobility in soil No information available. 12.5. Results of PBT and vPvB assessment PBT and vPvB assessment The product does not contain any substance(s) classified as PBT or vPvB above the threshold of declaration. = Chemical name Sec <meta Seg | ae PBT and VPvB assessment: 20: Petroleum gases, liquefied The substance is not PBT / vPvB Acetone The substance is not. PBT / vPvB xylene The substance is not PBT / vPvB 2-Methoxy-1-methylethyl acetate The substance is not PBT / vPvB butanone The substance is not PBT / vPvB 4-Methoxy-2-propanol The substance is not PBT / vPvB 12.6. Endocrine disrupting properties Endocrine disrupting properties The substance/mixture does not contain components considered to have endocrine disrupting properties according te REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/6085 at levels of 0.1% or higher. 12.7. Other adverse effects No information available. (SECTION 13: Disposal considerations: ° ] 13.1. Waste treatment methods Waste from residues/unused Should not be released into the environment. Dispose of in accordance with local products regulations. Dispose of waste in accordance with environmental legislation. Contaminated packaging aa containers pose a potential fire and explosion hazard. Do not cut, puncture or weld containers. Page 17/21 ISECTION.14: ‘Transport information IATA 14.1. UN number or ID number UN1950 é 14.2 UN proper shipping name AEROSOLS, FLAMMABLE 14.3 Transport hazard class(es) 2.1 14.4 Packing group None 14.5 Environmental hazards No 14.6 Special precautions for user Special Provisions None IMDG 14.1. UN number or ID number UN1950 14.2 UN proper shipping name AEROSOLS, FLAMMABLE 14.3 Transport hazard class(es) 14.4 Packing group 14.5 Environmental hazards 14.6 Special precautions for user Special Provisions None EmS-No F-D, S-U 14.7 Maritime transport in bulk No information available according to {MO instruments - RID 14.1. UN number or iD number UN1950 14.2 UN proper shipping name AEROSOLS, FLAMMABLE 14.3 Transport hazard class(es) 2.1 14.4 Packing group None 14.5 Environmental hazards No 14.6 Special precautions for user Special Provisions None ADR 14.1 UN number or ID number UN1950 14.2 UN proper shipping name AEROSOLS, FLAMMABLE 14.3 Transport hazard class(es) 2.1 14.4 Packing group None 14.5 Environmental hazards No 14.6 Special precautions for user Special Provisions None Tunnel restriction code (D) [SECTION 15; Regulatory information 15.1, Safety, health and environmental requlations/legislation specific for the substance or mixture ie i Oo <s Chemical name” beicryzs French RG number Ne ain ary Acetone - 67-64-1 RG 84 xylene - 1330-20-7 RG 4bis,RG 84 2-Methoxy-1-methylethy! acetate - 108-65-6 RG 84 butanone - 78-93-3 RG 84 4-Methoxy-2-propanol - 107-98-2 RG 84 Water hazard class (WGK) obviously hazardous to water (WGK 2) Page 18/21 Netherlands = List of ry Netherlands - List o 7 Netherlands - List of. ~ Carcinogens- Reproductive Toxins. _. Development Category 2 European Union Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work. Authorisations and/or restrictions on use: This product does not contain substances subject to authorisation (Regulation (EC) No. 1907/2006 (REACH), Annex XIV) This roduct does not contain substances subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVIL) “Chemical name « Restricted substance per REACH 3s bstance subject to authorisation per “REACH Annex XIV - Annex XVil ‘Petroleum gases, liquefied - 68476-85-7 Use restricted. See item 28. ) Use restricted. See item 29. Use restricted. See item 75. Acetone - 67-64-1 Use restricted. See item 75. xylene - 1330-20-7 Use restricted. See item 75. butanone - 78-93-3 Use restricted. See item 75. Persistent Organic Pollutants Not applicable oy oh Chemical name ‘Lower-tier. requirements (tons) Upper-tier requirements (tons). ~ Petroleum gases, liquefied - 68476-85-7 50 200 Ozone-depleting substances (ODS) regulation (EC) 1005/2009 Not applicable International inventories TSCA Contact supplier for inventory compliance status DSL/NDSL Contact supplier for inventory compliance status EINECS/ELINCS Contact supplier for inventory compliance status ENCS Contact supplier for inventory compliance status IECSC Contact supplier for inventory compliance status KECL Contact supplier for inventory compliance status PICCS Contact supplier for inventory compliance status AIC Contact supplier for inventory compliance status NZloC Contact supplier for inventory compliance status Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSLINDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL, - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AllC - Australian Inventory of Industrial Chemicals NZloC ~- New Zealand Inventory of Chemicais Page 19/21 15.2. Chemical safety assessment Chemical Safety Report No information available SECTION .16
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP] Aerosols Category 1 - (H222, H229) Serious eye damage/eye irritation Category 2. - (H319) Specific target organ toxicity —- single exposure Category 3 - (H336) |Category 3 Narcotic effects