Glutaraldehyde 25 % in water, for electromicro- scopy

Hazard statements (CLP)

H302, H314, H317, H318, H330, H334, H335, H400, H410, H411

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

According to Regulation (EC) No 1272/2008 [CLP Classification of the substance or mixture

Hazard categories

Cat- Hazard class and Hazard egory category statement 3.1O Acute toxicity (oral) Acute Tox. 4 H302 3.1I Acute toxicity (inhal.) Acute Tox. 2 H330 3.2 Skin corrosion/irritation 1B Skin Corr. 1B H314 3.3 Serious eye damage/eye irritation Eye Dam. 1 H318 3.4R Respiratory sensitisation Resp. Sens. 1 H334 3.4S Skin sensitisation Skin Sens. 1 H317 3.8R Specific target organ toxicity - single exposure (respir- STOT SE 3 H335 atory tract irritation) 4.1A Hazardous to the aquatic environment - acute hazard Aquatic Acute 1 H400 4.1C Hazardous to the aquatic environment - chronic hazard Aquatic Chronic 2 H411 Supplemental hazard information Code Supplemental hazard information EUH071 corrosive to the respiratory tract For full text of abbreviations: see SECTION 16

Most important adverse effects

Skin corrosion produces an irreversible damage to the skin; namely, visible necrosis through the epi- dermis and into the dermis. Spillage and fire water can cause pollution of watercourses

Signal word

Danger Danger Not required

Hazard pictograms

GHS05, GHS06, GHS08, GHS09 H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H330 Fatal if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. P260 Do not breathe mist/vapours. P280 Wear protective gloves/protective clothing/eye protection/face protection. P302+P352 IF ON SKIN: Wash with plenty of water. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER. EUH071 Corrosive to the respiratory tract.

Hazard statements

H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H317 May cause an allergic skin reaction H330 Fatal if inhaled H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled H410 Very toxic to aquatic life with long lasting effects Not required

Prevention

P260 Do not breathe mist/vapours P270 Do not eat, drink or smoke when using this product P280 Wear protective gloves/protective clothing/eye protection/face protection

Response

P302+P352 IF ON SKIN: Wash with plenty of water P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 Immediately call a POISON CENTER

Supplemental label elements

EUH071 Corrosive to the respiratory tract.

Hazardous Ingredients

Glutardialdehyde, Methanol Labelling of packages where the contents do not exceed 125 ml

Contains

Glutardialdehyde, Methanol Labelling of packages where the contents do not exceed 10 ml

Precautionary statements

Not required

Results of PBT and vPvB assessment

Does not contain a PBT-/vPvB-substance at a concentration of ≥ 0,1%. Endocrine disrupting properties Does not contain an endocrine disruptor (ED) at a concentration of ≥ 0,1%.

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 (CLP) Section Hazard class Cat- Hazard class and Hazard egory category statement 3.1O Acute toxicity (oral) 4 Acute Tox. 4 H302 3.1I Acute toxicity (inhal.) 2 Acute Tox. 2 H330 3.2 Skin corrosion/irritation 1B Skin Corr. 1B H314 3.3 Serious eye damage/eye irritation 1 Eye Dam. 1 H318 3.4R Respiratory sensitisation 1 Resp. Sens. 1 H334 3.4S Skin sensitisation 1 Skin Sens. 1 H317 3.8R Specific target organ toxicity - single exposure (respir- 3 STOT SE 3 H335 atory tract irritation) 4.1A Hazardous to the aquatic environment - acute hazard 1 Aquatic Acute 1 H400 4.1C Hazardous to the aquatic environment - chronic hazard 2 Aquatic Chronic 2 H411 Supplemental hazard information Code Supplemental hazard information EUH071 corrosive to the respiratory tract For full text of abbreviations: see SECTION 16 The most important adverse physicochemical, human health and environmental effects Skin corrosion produces an irreversible damage to the skin; namely, visible necrosis through the epi- dermis and into the dermis. Spillage and fire water can cause pollution of watercourses.