1,4-Dioxane ≥99,5 %, for synthesis, stabilized

ROTH AG

Revision date : 2025-10-13

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GHS02 GHS08 GHS07
Health risk rating 5
Safety risk rating 5
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

204-661-8/123-91-1

Name of the chemical

1,4-Dioxane

Concentration

N/A

EC/CAS

204-881-4/128-37-0

Name of the chemical

2,6-di-tert-butyl-p-cresol

Concentration

< 0,1

General Information

Version

2.0 en

Revision date

2025-10-13

Product name

1,4-Dioxane ≥99,5 %, for synthesis, stabilized

Product Synonyms

1,4-Diethylene dioxide

CAS No.

123-91-1

REACH No

01-2119462837-26-xxxx

1.2.2. Uses advised against

Do not use for products which come into contact with foodstuffs. Do not use for private purposes (household). Food, drink and animal feeding- stuffs

Emergency telephone

+41 61 7121160

Icons in SDS

F001 GHS02 GHS07 GHS08 M004 M009 M016 M017 M022 T013 W001

Company Information

company name

ROTH AG

e-mail address of the competent person responsible for the Safety Data Sheet

sicherheit@carlroth.de, info@carlroth.ch

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H319, H335, H350

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

According to Regulation (EC) No 1272/2008 [CLP Classification of the substance or mixture

Hazard categories

Cat- Hazard class and Hazard egory category statement 2.6 Flammable liquid Flam. Liq. 2 H225 3.3 Serious eye damage/eye irritation Eye Irrit. 2 H319 3.6 Carcinogenicity 1B Carc. 1B H350 3.8R Specific target organ toxicity - single exposure (respir- STOT SE 3 H335 atory tract irritation) Supplemental hazard information Code Supplemental hazard information EUH019 may form explosive peroxides EUH066 repeated exposure may cause skin dryness or cracking For full text of abbreviations: see SECTION 16

Most important adverse effects

The product is combustible and can be ignited by potential ignition sources

Signal word

Danger Danger Not required

Hazard pictograms

GHS02, GHS07, GHS08 H335 May cause respiratory irritation. H350 May cause cancer. P261 Avoid breathing mist/vapours/spray. P280 Wear protective gloves/eye protection/face protection. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P308+P313 IF exposed or concerned: Get medical advice/attention. EUH019 May form explosive peroxides. EUH066 Repeated exposure may cause skin dryness or cracking. Labelling of packages where the contents do not exceed 10 ml

Hazard statements

H225 Highly flammable liquid and vapour H319 Causes serious eye irritation H335 May cause respiratory irritation H350 May cause cancer Not required

Prevention

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P261 Avoid breathing mist/vapours/spray P280 Wear protective gloves/eye protection/face protection

Response

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P308+P313 IF exposed or concerned: Get medical advice/attention For professional users only

Supplemental label elements

EUH019 May form explosive peroxides. EUH066 Repeated exposure may cause skin dryness or cracking. Labelling of packages where the contents do not exceed 125 ml

Precautionary statements

Not required

Results of PBT and vPvB assessment

According to the results of its assessment, this substance is not a PBT or a vPvB. Endocrine disrupting properties Does not contain an endocrine disruptor (ED) at a concentration of ≥ 0,1%.

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 (CLP) Section Hazard class Cat- Hazard class and Hazard egory category statement 2.6 Flammable liquid 2 Flam. Liq. 2 H225 3.3 Serious eye damage/eye irritation 2 Eye Irrit. 2 H319 3.6 Carcinogenicity 1B Carc. 1B H350 3.8R Specific target organ toxicity - single exposure (respir- 3 STOT SE 3 H335 atory tract irritation) Supplemental hazard information Code Supplemental hazard information EUH019 may form explosive peroxides EUH066 repeated exposure may cause skin dryness or cracking For full text of abbreviations: see SECTION 16 The most important adverse physicochemical, human health and environmental effects The product is combustible and can be ignited by potential ignition sources.

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